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Chlorine Dioxide

Inventor: Richard Hamilton, et al.
Year: 2004
Device: Controlled Gas Delivery Apparatus
Folder: chlorinedioxide
Original: Open article
Confidence
0.90
Practicability
0.60
Evidence
0.30
Fringe Score
0.20
Risk
0.40
TRL
5

Goal

Provide on-site generation of high-purity chlorine dioxide gas with controlled rate and minimal toxic by-products for disinfection, deodorization, bleaching and sanitization.

Problem

Existing chlorine dioxide generation methods produce toxic chlorates/chlorites, require large generators, and lack precise control of gas release.

Concept Summary

The invention uses a multi-layered sachet/ membranevelope system containing reactants that generate chlorine dioxide when exposed to water (or water vapor). A proprietary membrane traps harmful by-products, releasing only pure ClO_2 gas. The design allows controlled rate, duration, and dosage of gas delivery for various applications.

Principles

  • Chemical oxidation reaction producing chlorine dioxide
  • Selective membrane trapping of toxic by-products
  • Multi-layer sachet structure for controlled reactant exposure
  • Water-vapor selective material to regulate initiation

Scientific Domains

Chemistry Chemical Engineering Materials Science Environmental Engineering

Materials

  • Hydrophobic membrane material
  • Water-vapor selective material
  • Sachet polymer (e.g., polyester)
  • Reactants (unspecified, typical chlorine dioxide precursors)

Mechanisms of Action

  • Reactants (e.g., sodium chlorite + acid) react with water to generate ClO_2 gas
  • Proprietary membrane allows ClO_2 to pass while retaining chlorates/chlorites
  • Barrier layers and sachet geometry control diffusion rate and gas release

Energy Sources

Water (as initiating agent)

Applications

  • Water disinfection
  • Food processing sanitation
  • Medical instrument sterilization
  • Odor elimination in confined spaces
  • Bleaching of flour, fats and textiles

Claimed Performance

99.9% pure chlorine dioxide solution; odor elimination in confined spaces >6,000 ft^2 to >10,000 ft^2 per unit with a treatment period of at least 4 hours.

Experimental Evidence

Fast-release products are reported to be widely used in laboratory and clinical settings; the CLO2BBERIZER odor eliminator is specified for spaces >6003 ft to 10003 ft per unit with a minimum 4-hour treatment period.

Replication Status

Patented (US2004022676) - no independent replication reported.

Limitations

  • Requires safe handling of reactive chemicals
  • Generation of chlorine dioxide must be on-site; not transportable as a concentrated gas
  • Potential residues if membrane fails

Keywords

chlorine dioxide gas delivery on-site generation membrane sachet deodorization disinfection purity

Related Technologies

Gas generators Disinfectant sprays Odor control systems Bleaching agents

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