Confidence
0.80
Practicability
0.70
Evidence
0.30
Fringe Score
0.20
Risk
0.20
TRL
7
Goal
Capture and permanently store carbon dioxide emissions from fossil-fuel combustion.
Problem
Atmospheric CO_2 buildup and greenhouse-gas emissions from power plants and industrial processes.
Concept Summary
A family of processes and apparatuses that capture CO_2 (and other gases) from flue streams, convert it into solid carbonates via mineral carbonation, plasma ionization, or chemical absorption, and store the solid product or compressed CO_2 underground. The technologies employ acid-base reactions, ionized water scrubbing, plasma arcs, and gas-separation membranes to achieve high-purity CO_2 capture and sequestration.
Principles
- Acid-base neutralization
- Mineral carbonation
- Plasma ionization
- Gas absorption and scrubbing
- Membrane gas separation
- Compression and condensation
Scientific Domains
Materials
- Magnesium-containing minerals (e.g., dolomite)
- Calcium silicate minerals
- Weak acids (e.g., dilute sulfuric acid)
- Bases (e.g., sodium hydroxide)
- Water
- Ionized water
- Catalysts for CO_2 conversion
- Gas diffusion membranes
Mechanisms of Action
- Dissolution of magnesium or calcium minerals in weak acid to form metal-rich solutions
- Addition of CO_2 and base to precipitate metal carbonates
- Ionization of flue gases in a plasma arc to produce elemental fragments
- Spray of ionized water in a tunnel to scrub toxic constituents
- Use of gas diffusion membranes to transfer CO_2 into a fluid medium
- Catalytic conversion of CO_2 to carbonic acid followed by carbonate precipitation
Energy Sources
Applications
- Power-plant emissions reduction
- Industrial gas cleaning
- Underground CO_2 storage
- Hydrogen production with CO_2 capture
Limitations
- High energy demand for heat, compression, and plasma generation
- Requirement for large quantities of suitable minerals
- Capital cost of retrofitting existing plants
- Potential scaling challenges for tunnel-based scrubbing systems