Lonni Johnson --- Thermo-Electric Generator -- articles,
patent

![](0logo.gif)  
[rexresearch.com](../index.htm)

---

**Lonnie JOHNSON**

**JTEC Thermo-Electric Generator**

---

[**http://www.johnsonems.com/company.html**](http://www.johnsonems.com/company.html)

**Lonnie Johnson**

![](ljohnson.jpg)

Until now, thermodynamic engines that use compressible working
fluids have generally been mechanical devices. These devices
have inherent difficulties in achieving high compression ratios
and in achieving the near constant temperature compression and
expansion processes needed to approximate Carnot equivalent
cycles. Solid-state thermoelectric converters that utilize
semiconductor materials have only been able to achieve single
digit conversion efficiency. Extensive resources have been
applied toward Alkali Metal Thermoelectric Converters (AMTEC),
which operate on a modified Rankine cycle and on the Stirling
engine. However, because of inherent limitations, these systems
have not achieved envisioned performance levels.

The JTEC is an all solid-state engine that operates on the
Ericsson cycle. Equivalent to Carnot, the Ericsson cycle offers
the maximum theoretical efficiency available from an engine
operating between two temperatures. The JTEC system utilizes the
electro-chemical potential of hydrogen pressure applied across a
proton conductive membrane (PCM). The membrane and a pair of
electrodes form a Membrane Electrode Assembly (MEA) similar to
those used in fuel cells. On the high-pressure side of the MEA,
hydrogen gas is oxidized resulting in the creation of protons
and electrons. The pressure differential forces protons through
the membrane causing the electrodes to conduct electrons through
an external load. On the low-pressure side, the protons are
reduced with the electrons to reform hydrogen gas. This process
can also operate in reverse. If current is passed through the
MEA a low-pressure gas can be "pumped" to a higher pressure.

The JTEC uses two membrane electrode assembly (MEA) stacks. One
stack is coupled to a high temperature heat source and the other
to a low temperature heat sink. Hydrogen circulates within the
engine between the two MEA stacks via a counter flow
regenerative heat exchanger. The engine does not require oxygen
or a continuous fuel supply, only heat. Like a gas turbine
engine, the low temperature MEA stack is the compressor stage
and the high temperature MEA is the power stage. The MEA stacks
will be designed for sufficient heat transfer with the heat
source and sink to allow near constant temperature expansion and
compression processes. This feature coupled with the use of a
regenerative counter flow heat exchanger will allow the engine
to approximate the Ericsson cycle.

The engine is scaleable and has applications ranging from
supplying power for Micro Electro Mechanical Systems (MEMS) to
power for large-scale applications such as fixed power plants.
The technology is applicable to skid mounted, field generators,
land vehicles, air vehicles and spacecraft. The JTEC could
utilize heat from fuel combustion, solar, low grade industrial
waste heat or waste heat from other power generation systems
including fuel cells, internal combustion engines and combustion
turbines. As a heat pump, the JTEC system could be used as a
drop in replacement for existing HVAC equipment in residential,
commercial, or industrial settings.

---

**<http://www.physorg.com/news119107136.html>**

Nuclear Engineer Lonnie Johnson, best known for his invention
of the super soaker squirt gun, has recently designed a new type
of solar energy technology that he says can achieve a conversion
efficiency rate of more than 60 percent. Considering that the
best solar energy systems today have an efficiency of 30-40
percent, Johnson's method could cut the cost of solar energy
nearly in half.

A recent article in Popular Mechanics describes how Johnson's
system would work. Rather than use photovoltaic cells, where
silicon converts light into electricity, the new system works
like a heat engine. But instead of using heat to turn an axle,
it uses heat to force hydrogen ions through a
membrane-electrode, and create electricity.

The system, called the Johnson Thermoelectric Energy Converting
System (JTEC) consists of two stacks of electrodes --- a
high-temperature stack heated by the sun (and by concentrated
mirrors) and a low-temperature stack.

An electrical jolt triggers a voltage across the electrode
stacks, with the low-temperature stack pumping out hydrogen from
low to high pressure in order to maintain the pressure
differential. As the hydrogen passes through the
high-temperature stack of electrodes, it generates power. In a
sense, the system works similar to a fuel cell.

Johnson plans to build a system whose high temperature reaches
600 degrees centrigrade, within the current solar concentration
ability of parabolic mirrors, which can produce temperatures of
more than 800 degrees centigrade. At 600 degrees, the system
would have an efficiency of close to 60 percent. At higher
temperatures, the efficiency would increase even more.

The system should be able to produce several megawatts of
power, according to Johnson. It could also harvest waste heat
from internal combustion engines, turbines, and even the human
body.

Johnson, a former NASA employee, funds his work with the
millions of dollars he made from inventing the super soaker.

---

**<http://www.popularmechanics.com/science/earth/4243793.html>**

***Popular Mechanics* ( Jan. 8, 2008)**

**Super Soaker Inventor Aims to Cut Solar
Costs in Half**

**by**

**Logan Ward**

Solar energy technology is enjoying its day in the sun with the
advent of innovations from flexible photovoltaic (PV) materials
to thermal power plants that concentrate the suns heat to drive
turbines. But even the best system converts only about 30
percent of received solar energy into electricitymaking solar
more expensive than burning coal or oil. That will change if
Lonnie Johnsons invention works. The Atlanta-based independent
inventor of the Super Soaker squirt gun (a true technological
milestone) says he can achieve a conversion efficiency rate that
tops 60 percent with a new solid-state heat engine. It
represents a breakthrough new way to turn heat into power.

Johnson, a nuclear engineer who holds more than 100 patents,
calls his invention the Johnson Thermoelectric Energy Conversion
System, or JTEC for short. This is not PV technology, in which
semiconducting silicon converts light into electricity. And
unlike a Stirling engine, in which pistons are powered by the
expansion and compression of a contained gas, there are no
moving parts in the JTEC. Its sort of like a fuel cell: JTEC
circulates hydrogen between two membrane-electrode assemblies
(MEA). Unlike a fuel cell, however, JTEC is a closed system. No
external hydrogen source. No oxygen input. No wastewater output.
Other than a jolt of electricity that acts like the ignition
spark in an internal-combustion engine, the only input is heat.

Heres how it works: One MEA stack is coupled to a high-
temperature heat source (such as solar heat concentrated by
mirrors), and the other to a low-temperature heat sink (ambient
air). The low-temperature stack acts as the compressor stage
while the high-temperature stack functions as the power stage.
Once the cycle is started by the electrical jolt, the resulting
pressure differential produces voltage across each of the MEA
stacks. The higher voltage at the high-temperature stack forces
the low-temperature stack to pump hydrogen from low pressure to
high pressure, maintaining the pressure differential. Meanwhile
hydrogen passing through the high-temperature stack generates
power.

Its like a conventional heat engine, explains Paul Werbos,
program director at the National Science Foundation, which has
provided funding for JTEC. It still uses temperature
differences to create pressure gradients. Only instead of using
those pressure gradients to move an axle or wheel, hes using
them to force ions through a membrane. Its a totally new way of
generating electricity from heat.

The bigger the temperature differential, the higher the
efficiency. With the help of Heshmat Aglan, a professor of
mechanical engineering at Alabamas Tuskegee University, Johnson
hopes to have a low-temperature prototype (200-degree
centigrade) completed within a years time. The pair is
experimenting with high-temperature membranes made of a novel
ceramic material of micron-scale thickness. Johnson envisions a
first-generation system capable of handling temperatures up to
600 degrees. (Currently, solar concentration using parabolic
mirrors tops 800 degrees centigrade.) Based on the theoretical
Carnot thermodynamic cycle, at 600 degrees efficiency rates
approach 60 percent, twice those of todays solar Stirling
engines.

This engine, Johnson says, can operate on tiny scales, or
generate megawatts of power. If it proves feasible, drastically
reducing the cost of solar power would only be a start. JTEC
could potentially harvest waste heat from internal combustion
engines and combustion turbines, perhaps even the human body.
And no moving parts means no friction and fewer mechanical
failures.

As an engineer, Johnson says he has always been interested in
energy conversion. In fact, it was while working on an idea for
an environmentally friendly heat pump (one that would not
require Freon) that he came up with the Super Soaker, which
earned him millions of dollars in royalties. That money allowed
Johnson to quit NASAs Jet Propulsion Lab (where he worked on
the Galileo Mission, among other projects) and go independent.
His toy profits have funded his research in advanced battery
technology, specifically thin-film lithium-ion conductive
membranes. And that work sparked the idea for JTEC. Besides, he
jokes, All inventors have to have an engine. Its like a rite
of passage.

---

**National Science Foundation**   
[**http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=0646367**](http://www.nsf.gov/awardsearch/showAward.do?AwardNumber=0646367)

**Award Number:   0646367**

**Johnson ThermoElectrochemical Converter
(JTEC) Solar Powered Cell Tower Generator**

**ABSTRACT --- JTEC SOLAR POWERED CELL TOWER GENERATOR**

This project will attempt to resolve the key technical issues
and uncertainties regarding a breakthrough concept for low-cost
high-efficiency solar power. The proposed approach is based on a
conceptual system for providing independent power for cell
towers that will allow them to function even after emergencies
like hurricane Katrina. The solar engine is based on the Johnson
  
ThermoElectrochemical Converter (JTEC) concept for converting
heat to electricity invented by (Lonnie) Johnson, who will be
available to assist Tuskegee University in carrying out this
work. Except for the working fluid, JTEC is an all solid state
engine that does not have mechanical moving parts. Different
from conventional solid state thermoelectric devices, it does
not have inherent parasitic heat loss paths. JTEC uses Membrane
Electrode Assemblies (MEA) similar to those used in fuel cells;
however, it does not require oxygen or a special fuel, only
heat. The availability of a range of proton conductive membrane
materials that operate from room temperature up to and exceeding
1200 C suggests that JTEC could generate electricity from
practically any heat source, from very small, just a few
degrees, to very large temperature differences. JTEC
approximates the Ericsson thermodynamic cycle which is Carnot
equivalent. Research on this technology offers the potential for
achieving solar power efficiency of 50% in the short-term and
80% in the long-term, far beyond what is expected from
photovoltaics both in efficiency and in cost.

(1) Intellectual merit of the proposed activity

JTEC is a fundamentally new solid state engine concept.
Critical research is needed to enable a credible analysis of its
potential. Research is needed into the properties of proton
conductive materials needed to make a working system. The
materials are similar those being studied in fuel cell research,
but new material properties must be investigated in order to
optimize the choices for this application. Research is needed to
model, simulate and optimize an integrated systems design for
cost-effective recharge power for cell towers.

(2) Broader impacts resulting from the proposed activity:

Cell towers running out of battery power were a crucial problem
in the wake of Katrina and resulted unnecessary deaths and
destruction. This project, with follow-on research, could
provide un-interruptible, cost effective power for
communications in areas threatened by hurricanes and other
disasters that is not limited by battery life. The proposed
engine technology will have major impacts on the international
energy economy particularly with respect to the need for
economical, green, renewable energy. This research is consistent
with NSF goals for minority education and outreach. Tuskegee
University is a HBCU institution and Johnson Research is a
minority owned small business.

---

  
[**http://www.wikipedia.org**](http://www.wikipedia.org)

**Ericsson Cycle**

 

The Ericsson Cycle is named after inventor John Ericsson. John
Ericsson designed and built many unique heat engines based on
various thermodynamic   
cycles. He is credited with inventing two unique heat engine
cycles and developing practical engines based on these cycles.
His first cycle is very similar to what we now call the "Brayton
Cycle" except that it was external combustion. His second cycle
we now call the "Ericsson Cycle".

**Ideal Ericsson Cycle**

The following is a list of the four processes that occur
between the four stages of the ideal Ericsson cycle:

Process 1 -> 2: Isothermal Compression. The compression
space is assumed to be intercooled, so the gas undergoes
isothermal compression. The compressed air flows into a storage
tank at constant pressure. In the ideal cycle, there is no heat
transfer across the tank walls.

Process 2 -> 3: Isobaric Heat-addition. From the tank, the
compressed air flows through the regenerator and picks-up heat
at a high constant-pressure   
on the way to the heated power-cylinder.

Process 3 -> 4: Isothermal Expansion. The power-cylinder
expansion-space is heated externally, and the gas undergoes
isothermal expansion.

Process 4 -> 1: Isobaric Heat removal. Before the air is
released as exhaust, it is passed back through the regenerator,
thus cooling the gas at a low constant pressure, and heating the
regenerator for the next cycle.

**Comparison with Stirling, Carnot and Brayton cycles**

The Ericsson Cycle is often compared to the Stirling cycle,
since the engine designs based on these respective cycles are
both external combustion   
engines with regenerators. The Ericsson is perhaps most similar
to the so called "double-acting" type of Stirling engine, in
which the displacer piston also acts as the power piston.
Theoretically, both of these cycles have so called "ideal"
efficiency, which is the highest allowed by the Second law of
thermodynamics. The most well known ideal cycle is the Carnot
cycle, although ironically, a real Carnot Engine is not known to
have been invented.

**Comparison with the Brayton Cycle**

The first cycle Ericsson developed, is now called the "Brayton
Cycle", commonly applied to the rotary jet engines for
airplanes.

The second Ericsson cycle is the cycle most commonly referred
to as simply the "Ericsson cycle". The (second) Ericsson cycle
is also the limit of ideal gas-turbine Brayton cycle, operating
with multistage intercooled compression, and multistage
expansion with reheat and regeneration. Compared to the Brayton
cycle which uses adiabatic compression and expansion, the second
Ericsson cycle uses isothermal compression and expansion, thus
producing more net work per stroke. Also the use of regeneration
in the Ericsson cycle increases efficiency by reducing the
required heat input. For further comparisons of thermodynamic
cycles, see Heat engine.

**Ericsson Engine**

The Ericsson engine, (see figure), is based on the Ericsson
cycle, and is known as an "external combustion engine", because
it is externally heated. To improve efficiency, the engine has a
regenerator or recuperator between the compressor and the
expander. The engine can be run open-cycle or closed-cycle.
Expansion occurs simultaneously with compression, on opposite
sides of the piston.

**The Regenerator**

Ericsson coined the term "regenerator" for his independent
invention of the mixed-flow counter-current heat-exchanger.
However, Rev. Robert Stirling had invented the same device,
prior to Ericsson, so the invention is credited to Stirling.
Stirling called it an "economiser" or "economizer", because it
increased the fuel economy of various types of heat processes.
The invention was found to be useful, in many other devices and
systems, where it became more widely used, since other types of
engines became favored over the Stirling engine. Interestingly,
the term "regenerator" is now the name given to the component in
the Stirling Engine!

The term "recuperator" refers to a separated-flow,
counter-current heat exchanger. As if this weren't confusing
enough, a mixed-flow regenerator is sometimes used as a
quasi-separated-flow recuperator. This can be done through the
use of moving valves, or by a rotating regenerator with fixed
baffles, or by the use of other moving parts. When heat is
recovered from exhaust gases and used to preheat combustion air,
typically the term recuperator is used, because the two flows
are separate.

**History**

In 1791, before Ericsson, Barber proposed a similar engine. The
Barber engine used a bellows compressor and a turbine expander,
but it lacked a regenerator/recuperator. There are no records of
a working Barber engine. Ericsson invented and patented his
first engine using an external version of the Brayton Cycle in
1833 (number 6409/1833 British). This was 18 years before Joule
and 43 years before Brayton. Brayton engines were all piston
engines and for the most part, internal combustion versions of
the un-recuperated Ericsson engine. The "Brayton Cycle" is now
known as the gas turbine cycle, which differs from the original
"Brayton Cycle" in the use of a turbine compressor and expander.
The gas turbine cycle is used for all modern gas turbine and
turbojet engines, however simple cycle turbines are often
recuperated to improve efficiency and these recuperated turbines
more closely resemble Ericsson's work.

Ericsson eventually abandoned the open cycle in favor of the
traditional closed Stirling cycle.

The Ericsson Cycle Engine (The second of the two discussed
here) was used to power a 2000 ton ship, The Caloric Ship
Ericsson and the engine ran flawlessly for 73 hours. The
combination engine produced about 300 horsepower. It had a
combination of 4 dual-piston engines; the larger expansion
piston/cylinder, at 4.267 meters or 14 feet in diameter, was
perhaps the largest piston ever built. Rumor has it that tables
were placed on top of those pistons and dinner was served and
eaten, while the engine was running at full power. At 6.5 RPM
the pressure was limited to 8 psi. The one sea trial proved that
even though the engine ran well it was underpowered. ometime
after the trials the Ericsson sank. When it was raised the
Ericsson cycle engine was removed and a steam engine took its
place.

Ericsson designed and built a very great number of engines
running on various cycles including steam, Stirling, Brayton,
externally heated diesel air fluid cycle. He ran his engines on
a great variety of fuels including coal and solar heat.

Ericsson also was the inventor of the screw propeller for ship
propulsion, in the USS Princeton.

---

***The Atlanta Journal-Constitution***

**Inventor breaks through again -- Beyond Super Soaker** :   
*Atlantan's energy game-changer earns honors.*

Lonnie Johnson has some impressive hard science credentials.

He's worked for the Strategic Air Command and for NASA's Jet
Propulsion Laboratory, outfitting missions to Mars, Jupiter and
Saturn. He holds about 100 patents, many of them in that arcane
spot where chemistry, electricity and physics cross into the
marketplace. And his latest invention appears to do the
impossible: generating electricity with no fuel and no moving
parts.

But he's still known as Mr. Squirt Gun.

Even among the geniuses who gathered to honor him and his new
thermo-electrochemical converter at a  Breakthrough
Awards  banquet in Manhattan this month, the Atlanta
scientist's new invention was ignored when his most famous
device was revealed.

"What?" they cried. "You invented the Super Soaker?"

Johnson, 59, doesn't mind if he's better known for watery
mayhem than rocket science. Perhaps that's because $1 billion
worth of Super Soakers have sold since 1990. A billion dollars
could buy most of a Galileo mission.

Johnson's share (he licensed the Soaker's design to Larami,
later bought by Hasbro) won him the financial independence to
pursue his own ideas, which is how the Johnson
Thermo-electrochemical Converter system -- JTEC for short ---
was born.

Using heat to force ions out of a hydrogen cell, the JTEC "is
just a stunning insight," said Jerry Beilinson, deputy editor of
*Popular Mechanic*s magazine, which honors innovators in
its current issue and sponsors the Breakthrough Awards. "I kind
of thought we were finished; I didn't think there was a new
way."

Beilinson groups Johnson with other great synthesists of
science, including Henry Ford and Thomas Edison. He also points
out that Johnson, a native of Mobile, flourished in a somewhat
hostile environment.

**A whole new technology"**

In 1963 his governor stood up for segregation in Alabama,
standing in the schoolhouse door. Five years later, Johnson, a
high school senior, finished building a remote-controlled robot
with a reel-to-reel tape player for a brain and jukebox
solenoids controlling its pneumatic limbs. As a representative
of Williamson High School, Johnson took his robot (nicknamed
Linex) to a science fair at the University of Alabama.

The door wasn't exactly blocked, but no other black high
schools participated in the event. On the strength of Linex,
Williamson won. Teachers predicted Johnson would go far.

His robots went even farther. After graduating from Tuskegee
University, Johnson joined the Air Force, worked at the Air
Force Weapons Laboratory at Sandia, worked for NASA's Jet
Propulsion Lab on the Galileo mission to Jupiter and the Mars
Observer project, among others. He also helped design the
Cassini robot probe that flew 740 million miles to Saturn.

In 1990, just before the Super Soaker made him wealthy, Johnson
moved to Atlanta. In 2000, he began working in earnest on the
JTEC. In 2006 that work came to the attention of Paul Werbos at
the National Science Foundation, who recommended Johnson to
Popular Mechanics.

"This is a whole new family of technology," said the NSF's
Werbos. "It's like discovering a new continent. You don't know
what's there, but you sure want to explore it to find out."

Johnson's device can potentially work with even modest
temperature differentials -- say, between body heat and ambient
air -- to power implanted medical devices such as pacemakers. If
successful, at high heat it would generate Con Edison-scale
output. It also would run backward for refrigeration purposes:
put in electricity to generate heat loss for, say, wearable air
conditioning.

Paired with a parabolic solar array to generate heat, it would
create virtually limitless emission-free power.

Johnson, who projects earnings of $10 billion by 2013, claims a
potential 60 percent efficiency rating, which doubles the
efficiency of the current leader, the Stirling engine.

"It has a darn good chance," said Werbos, "of being the best
thing on Earth."

**Always an adventure"**

This energy game-changer comes from unlikely quarters: a
renovated factory on a formerly bleak stretch of Decatur Street.

With the help of a $3.9 million empowerment-zone loan from the
city, Johnson's company bought, renovated and outfitted three
adjacent buildings on the street. In addition to his workshop,
he hosts a high school robotics team sponsored by the 100 Black
Men of Atlanta and donates office space for the Georgia Alliance
for Children, of which he is the chairman.

On a recent weekday, Johnson, impeccable in head-to-toe khaki,
conducts a tour of the workshop, moving among shiny stainless
steel deposition chambers and glove boxes where scientists can
manipulate delicate materials isolated in a pure argon
atmosphere.

Here the two dozen employees of his privately owned concern
work on several projects at once, developing solid-state
batteries and lithium-air batteries.

At one station Bill Rauch is working on solid-state batteries.
"He's full of ideas,"  says Rauch, a Ph.D. in material
science from Georgia Tech. "It's always an adventure."

Rauch says every now and then Johnson has a get-together at his
Ansley Park home for the employees; they swim in the pool and
squirt each other with off-the-shelf Super Soakers. Then Johnson
comes out with a prototype water weapon not available to the
public. He crushes the opposition.

Johnson's interest in thermal engines and heat pumps led to
experiments using water vapor instead of Freon as a compressible
liquid, which led, oddly enough, to the birth of the Super
Soaker.

His work with batteries led to an interest in generating
electricity electrochemically, instead of mechanically, which
led to the JTEC. The JTEC completes the loop between heat pumps
and batteries.

It;s freshman chemistry, said Karl Littau, a material scientist
at Palo Alto Research Center, a California nursery for high-tech
innovation. "Millions of people learn about that every year, yet
he was the guy who put two and two together."

Most of his ideas are connected, said Johnson.

"Sometimes I think I'm still working on everything I ever
invented."

**HOW DOES IT WORK?**

Most electricity is generated using heat to power a mechanical
device, such as a piston or a turbine. The JTEC uses heat to
force ions through a special membrane. "It's a totally new way
of generating electricity from heat," Paul Werbos told Popular
Mechanics. The JTEC includes two closed hydrogen cells or
"stacks" attached to pairs of electrodes. One is a
low-temperature stack, the other is high-temperature. Current
compresses hydrogen in the low-temperature stack, ionizing the
hydrogen and forcing its protons through the membrane to the
high-temperature stack, where the hydrogen expands. Current is
generated as electrons are freed. The high-temperature end
generates more power than the low-temperature end uses --
creating an excess that can cool beer or run TVs and washing
machines. Hydrogen is neither burned nor added, and emissions
are zero.

**LONNIE JOHNSON**

> Born: Oct. 6, 1949, Mobile   
> Residence: Ansley Park   
> Family: Wife, Linda Moore, and four children   
> Education: Tuskegee University, with degrees in mechanical
engineering and nuclear engineering   
> Career: Research engineer with Oak Ridge National
Laboratories; engineer at NASAas Jet Propulsion Laboratory;
nuclear safety engineer with U.S. Air Force; officer with the
Strategic Air Command; flight test engineer Edwards Air Force
Base.   
> Businesses: Johnson Research and Development, Johnson
Electro-Mechanical Systems, Excellatron Solid State LLC

---

<http://www.johnsonems.com/>  
  

JTEC  
Johnson
Thermo-Electrochemical Converter System

  
Until now, thermodynamic engines that use compressible working
fluids have generally been mechanical devices. These devices have
inherent difficulties in achieving high compression ratios and in
achieving the near constant temperature compression and expansion
processes needed to approximate Carnot equivalent cycles.
Solid-state thermoelectric converters that utilize semiconductor
materials have only been able to achieve single digit conversion
efficiency. Extensive resources have been applied toward Alkali
Metal Thermoelectric Converters (AMTEC), which operate on a
modified Rankine cycle and on the Stirling engine. However,
because of inherent limitations, these systems have not achieved
envisioned performance levels.  
  
The JTEC is an all solid-state engine that operates on the
Ericsson cycle. Equivalent to Carnot, the Ericsson cycle offers
the maximum theoretical efficiency available from an engine
operating between two temperatures. The JTEC system utilizes the
electro-chemical potential of hydrogen pressure applied across a
proton conductive membrane (PCM). The membrane and a pair of
electrodes form a Membrane Electrode Assembly (MEA) similar to
those used in fuel cells. On the high-pressure side of the MEA,
hydrogen gas is oxidized resulting in the creation of protons and
electrons. The pressure differential forces protons through the
membrane causing the electrodes to conduct electrons through an
external load. On the low-pressure side, the protons are reduced
with the electrons to reform hydrogen gas. This process can also
operate in reverse. If current is passed through the MEA a
low-pressure gas can be "pumped" to a higher pressure.  
  
The JTEC uses two membrane electrode assembly (MEA) stacks. One
stack is coupled to a high temperature heat source and the other
to a low temperature heat sink. Hydrogen circulates within the
engine between the two MEA stacks via a counter flow regenerative
heat exchanger. The engine does not require oxygen or a continuous
fuel supply, only heat. Like a gas turbine engine, the low
temperature MEA stack is the compressor stage and the high
temperature MEA is the power stage. The MEA stacks will be
designed for sufficient heat transfer with the heat source and
sink to allow near constant temperature expansion and compression
processes. This feature coupled with the use of a regenerative
counter flow heat exchanger will allow the engine to approximate
the Ericsson cycle.  
  
The engine is scaleable and has applications ranging from
supplying power for Micro Electro Mechanical Systems (MEMS) to
power for large-scale applications such as fixed power plants. The
technology is applicable to skid mounted, field generators, land
vehicles, air vehicles and spacecraft. The JTEC could utilize heat
from fuel combustion, solar, low grade industrial waste heat or
waste heat from other power generation systems including fuel
cells, internal combustion engines and combustion turbines. As a
heat pump, the JTEC system could be used as a drop in replacement
for existing HVAC equipment in residential, commercial, or
industrial settings.  
  


---

  
<http://www.popularmechanics.com/science/environment/green-energy/4243793>  
  
Solar energy technology is enjoying its day in the sun with the
advent of innovations from flexible photovoltaic (PV) materials to
thermal power plants that concentrate the sun's heat to drive
turbines. But even the best system converts only about 30 percent
of received solar energy into electricitymaking solar more
expensive than burning coal or oil. That will change if Lonnie
Johnson's invention works. The Atlanta-based independent inventor
of the Super Soaker squirt gun (a true technological milestone)
says he can achieve a conversion efficiency rate that tops 60
percent with a new solid-state heat engine. It represents a
breakthrough new way to turn heat into power.  
  
Johnson, a nuclear engineer who holds more than 100 patents, calls
his invention the Johnson Thermoelectric Energy Conversion System,
or JTEC for short. This is not PV technology, in which
semiconducting silicon converts light into electricity. And unlike
a Stirling engine, in which pistons are powered by the expansion
and compression of a contained gas, there are no moving parts in
the JTEC. It's sort of like a fuel cell: JTEC circulates hydrogen
between two membrane-electrode assemblies (MEA). Unlike a fuel
cell, however, JTEC is a closed system. No external hydrogen
source. No oxygen input. No wastewater output. Other than a jolt
of electricity that acts like the ignition spark in an
internal-combustion engine, the only input is heat.  
  
Here's how it works: One MEA stack is coupled to a high-
temperature heat source (such as solar heat concentrated by
mirrors), and the other to a low-temperature heat sink (ambient
air). The low-temperature stack acts as the compressor stage while
the high-temperature stack functions as the power stage. Once the
cycle is started by the electrical jolt, the resulting pressure
differential produces voltage across each of the MEA stacks. The
higher voltage at the high-temperature stack forces the
low-temperature stack to pump hydrogen from low pressure to high
pressure, maintaining the pressure differential. Meanwhile
hydrogen passing through the high-temperature stack generates
power.  
  
"It's like a conventional heat engine," explains Paul Werbos,
program director at the National Science Foundation, which has
provided funding for JTEC. "It still uses temperature differences
to create pressure gradients. Only instead of using those pressure
gradients to move an axle or wheel, he's using them to force ions
through a membrane. It's a totally new way of generating
electricity from heat."  
  
The bigger the temperature differential, the higher the
efficiency. With the help of Heshmat Aglan, a professor of
mechanical engineering at Alabama's Tuskegee University, Johnson
hopes to have a low-temperature prototype (200-degree centigrade)
completed within a year's time. The pair is experimenting with
high-temperature membranes made of a novel ceramic material of
micron-scale thickness. Johnson envisions a first-generation
system capable of handling temperatures up to 600 degrees.
(Currently, solar concentration using parabolic mirrors tops 800
degrees centigrade.) Based on the theoretical Carnot thermodynamic
cycle, at 600 degrees efficiency rates approach 60 percent, twice
those of today's solar Stirling engines.  
  
This engine, Johnson says, can operate on tiny scales, or generate
megawatts of power. If it proves feasible, drastically reducing
the cost of solar power would only be a start. JTEC could
potentially harvest waste heat from internal combustion engines
and combustion turbines, perhaps even the human body. And no
moving parts means no friction and fewer mechanical failures.  
  
As an engineer, Johnson says he has always been interested in
energy conversion. In fact, it was while working on an idea for an
environmentally friendly heat pump (one that would not require
Freon) that he came up with the Super Soaker, which earned him
millions of dollars in royalties. That money allowed Johnson to
quit NASA's Jet Propulsion Lab (where he worked on the Galileo
Mission, among other projects) and go independent. His toy profits
have funded his research in advanced battery technology,
specifically thin-film lithium-ion conductive membranes. And that
work sparked the idea for JTEC. Besides, he jokes, "All inventors
have to have an engine. It's like a rite of passage."  
  


---

  
<http://www.theatlantic.com/magazine/archive/2010/11/shooting-for-the-sun/8268/1/>  
  

Shooting for the Sun  
  
By Logan Ward

  
From his childhood in segregated Mobile, Alabama, to his run-ins
with a nay-saying scientific establishment, the engineer Lonnie
Johnson has never paid much heed to those who told him what he
could and couldnt accomplish. Best known for creating the
state-of-the-art Super Soaker squirt gun, Johnson believes he now
holds the key to affordable solar power.  
  
In March 2003, the independent inventor Lonnie Johnson faced a
roomful of high-level military scientists at the Office of Naval
Research in Arlington, Virginia. Johnson had traveled there from
his home in Atlanta, seeking research funding for an advanced heat
engine he calls the Johnson Thermoelectric Energy Converter, or
JTEC (pronounced jay-tek). At the time, the JTEC was only a set
of mathematical equations and the beginnings of a prototype, but
Johnson had made the tantalizing claim that his device would be
able to turn solar heat into electricity with twice the efficiency
of a photovoltaic cell, and the Office of Naval Research wanted to
hear more.  
  
Projected onto the wall was a PowerPoint collage summing up some
highlights of Johnsons career: risk assessment hed done for the
space shuttle Atlantis; work on the nuclear power source for
NASAs Galileo spacecraft; engineering help on the tests that led
to the first flight of the B-2 stealth bomber; the development of
an energy-dense ceramic battery; and the invention of a
remarkable, game-changing weapon that had made him millions of
dollarsa weapon that at least one of the men in the room, the
father of two small children, recognized immediately as the Super
Soaker squirt gun.  
  
Mild-mannered and bespectacled, Johnson opened his presentation by
describing the idea behind the JTEC. The device, he explained,
would split hydrogen atoms into protons and electrons, and in so
doing would convert heat into electricity. Most radically, it
would do so without the help of any moving parts. Johnson planned
to tell his audience that the JTEC could produce electricity so
efficiently that it might make solar power competitive with coal,
and perhaps at last fulfill the promise of renewable solar energy.
But before he reached that part of his presentation, Richard
Carlin, then the head of the Office of Naval Researchs mechanics
and energy conversion division, rose from his chair and dismissed
Johnsons brainchild outright. The whole premise for the device
relied on a concept that had proven impractical, Carlin claimed,
citing a 1981 report co-written by his mentor, the highly regarded
electrochemist Robert Osteryoung. Go read the Osteryoung report,
Carlin said, and you will see.  
  
End of meeting.  
  
Concerned about what he might have missed in the literature,
Johnson returned home and read the inch-thick report, concluding
that it addressed an approach quite different from his own.
Carlin, it seems, had rejected the concept before fully
comprehending it. (When I reached Carlin by phone recently, he
said he did not remember the meeting, but he is familiar with the
JTEC concept and now thinks that the principles are fine.) Nor
was Carlin alone at the time. Wherever Johnson pitched the JTEC,
the reaction seemed to be the same: no engine could convert heat
to electricity at such high efficiency rates without the use of
moving parts.  
  
Johnson believed otherwise. He felt that what had doomed his
presentation to the Office of Naval Researchand others as
wellwas a collective failure of imagination. It didnt help that
he was best known as a toy inventor, nor that he was working
outside the usual channels of the scientific establishment.
Johnson was stuck in a Catch-22: to prove his idea would work, he
needed a more robust prototype, one able to withstand the extreme
heat of concentrated sunlight. But he couldnt build such a
prototype without research funding. What he needed was a new
pitch. Instead of presenting the JTEC as an engine, he would frame
it as a high-temperature hydrogen fuel cell, a device that
produces electricity chemically rather than mechanically, by
stripping hydrogen atoms of their electrons. The description was
only partially apt: though both devices use similar components,
fuel cells require a constant supply of hydrogen; the JTEC, by
contrast, contains a fixed amount of hydrogen sealed in a chamber,
and needs only heat to operate. Still, in the fuel-cell context,
the devices lack of moving parts would no longer be a conceptual
stumbling block.  
  
Indeed, Johnson had begun trying out this new pitch two months
before his naval presentation, in a written proposal he submitted
to the Air Force Research Laboratorys peer-review panel. The
reaction, when it came that May, couldnt have been more
different. Funded just like that, he told me, snapping his
fingers, because they understood fuel cellsthe technology, the
references, the literature. The others couldnt get past this new
engine concept. The Air Force gave Johnson $100,000 for membrane
research, and in August 2003 sent a program manager to Johnsons
Atlanta laboratory. We make a presentation about the JTEC, and he
sayshere Johnson, who is black, puts on a
Bill-Cosby-doing-a-white-guy voiceWow, this is exciting! A
year later, after Johnson had proved he could make a ceramic
membrane capable of withstanding temperatures above 400 degrees
Celsius, the Air Force gave him an additional $750,000 in funding.  
  
The key to the JTEC is the second law of thermodynamics. Simply
put, the law says that temperature differences tend to even
outfor instance, when a hot mug of coffee disperses its heat into
the cool air of a room. As the heat levels of the mug and the room
come into balance, there is a transfer of energy.  
  
Work can be extracted from that transfer. The most common way of
doing this is with some form of heat engine. A steam engine, for
example, converts heat into electricity by using steam to spin a
turbine. Steam enginespowered predominantly by coal, but also by
natural gas, nuclear materials, and other fuelsgenerate 90
percent of all U.S. electricity. But though they have been refined
over the centuries, most are still clanking, hissing,
exhaust-spewing machines that rely on moving parts, and so are
relatively inefficient and prone to mechanical breakdown.  
  
Johnsons latest JTEC prototype, which looks like a desktop model
for a next-generation moonshine still, features two fuel-cell-like
stacks, or chambers, filled with hydrogen gas and connected by
steel tubes with round pressure gauges. Where a steam engine uses
the heat generated by burning coal to create steam pressure and
move mechanical elements, the JTEC uses heat (from the sun, for
instance) to expand hydrogen atoms in one stack. The expanding
atoms, each made up of a proton and an electron, split apart, and
the freed electrons travel through an external circuit as electric
current, charging a battery or performing some other useful work.
Meanwhile the positively charged protons, also known as ions,
squeeze through a specially designed proton-exchange membrane (one
of the JTEC elements borrowed from fuel cells) and combine with
the electrons on the other side, reconstituting the hydrogen,
which is compressed and pumped back into the hot stack. As long as
heat is supplied, the cycle continues indefinitely.  
  
Lonnies using temperature differences to create pressure
gradients, says Paul Werbos, an energy expert and program
director of the National Science Foundation. Only instead of
using those pressure gradients to move an axle or a wheel, hes
forcing ions through a membrane. Werbos, who spent months vetting
the JTEC and eventually awarded Johnsons team a $75,000 research
grant in 2006, describes the JTEC as a fundamentally new way, a
fundamentally well-grounded way, to convert heat to electricity.
Regarding its potential to revolutionize energy production on a
global scale, he says, It has a darn good chance of being the
best thing on Earth.  
  
Johnson is a member of what seems to be a vanishing breed: the
self-invented inventor. Born the third of six children in Mobile,
Alabama, in 1949, he came into the world a black male in the Deep
South during the days of lawful segregation. His father, David,
who died in 1984, was a World War II veteran and a civilian driver
for nearby Air Force bases. According to his mother, Arline, who
is 86 and still lives in Mobile (in a house remodeled with Super
Soaker profits), the family was poor but happy. All eight lived in
a three-bedroom, one-bathroom house near Mobile Bay, in a
neighborhood then being bisected by the construction of Interstate
10.  
  
As a boy, Johnson was quiet and curious, and early on, he
developed a fascination with how things worked. Lonnie tore up
his sisters baby doll to see what made the eyes close, his
mother recalls. As he grew older, he began making things,
including rockets powered by fuel cooked up in his mothers
saucepans. At 13, he bolted a discarded lawn-mower engine onto a
homemade go-cart and took it atop the I-10 construction siteonly
to have a bemused policeman escort him back down. It was around
then that Johnson learned that engineers were the people who did
the kind of things that I wanted to do.  
  
It was hardly an obvious career path: then, as now, the profession
was dominated by whites. (As recently as 2004, only 1.6 percent of
the engineering doctorates awarded in the United States went to
blacks.) In high school, a standardized test from the Junior
Engineering Technical Society informed Johnson that he had little
aptitude for engineering; but he persevered and, as a senior,
became the first student from his all-black high school ever to
enter the societys regional engineering fair. The fair was held
at the University of Alabama at Tuscaloosa, just five years after
then-Governor George Wallace had tried, in 1963, to physically
block two black students from enrolling there. Johnsons entry in
the competition was a creation he called Linex: a
compressed-air-powered robot assembled from electromagnetic
switches hed salvaged from an old jukebox, and solenoid valves
hed fashioned out of copper tubing and rubber stoppers. The
finished product wowed the judges, who awarded him first prize:
$250 and a plaque. Unsurprisingly, university officials didnt
trumpet the news that a black boy had won top honors. The only
thing anybody from the university said to us during the entire
competition, Johnson remembers, was Goodbye, and yall drive
safe, now.  
  
Johnson went on to win math and Air Force ROTC scholarships to
Tuskegee University, where he received a bachelors degree in
mechanical engineering and a masters in nuclear engineering. He
joined the Air Force in 1975 and subsequently held jobs at the Air
Force Weapons Laboratory, NASAs Jet Propulsion Laboratory, and
the Strategic Air Commandsolid, respectable positions that made
him a part of the scientific establishment. But at each stop, he
felt that his creativity was stifled, and in 1987, at the age of
38, he could take it no longer. He would go into business for
himself, he decided, focusing on his own projects, which included
a thermodynamic heat pump, a centrifugal-force engine, and a
pressure-action water gun. All I needed was one to hit, he says,
and Id be fine.  
  
The idea for the water gun had come to him one weekend afternoon
in 1982, while he was tinkering with an idea for an
environmentally friendly heat pump that would use water instead of
Freon. Hed built a prototype pump, attached some rubber tubing,
and brought it into a bathroom. Aiming the nozzle at the tub, he
turned it on, and produced a blast of water so powerful that the
mere wind from the spray ruffled the curtains. This, he thought,
would make a great water gun. It took Johnson seven uncertain and
stressful years, but he acquired the patents and eventually found
a company interested in manufacturing his Super Soaker: the Larami
Corporation, which licensed the rights to the gun in a deal that
would ultimately make Johnson rich.  
  
Hoping to offer society something more significant than enhanced
squirt-gun firepower, Johnson began plowing his Super Soaker
profits into energy-related R&D. While continuing to work on
mechanical devices such as his heat pump, he also studied battery
technology. When what he taught himself about electrochemistry
collided with his longtime obsession with the second law of
thermodynamics, Johnson had his eureka moment: why not use
temperature differences rather than a chemical reaction to force
the flow of ions through a cell? The JTEC concept was born.  
  
Today, Johnson and his family live in Atlantas upscale Ansley
Park neighborhood. The business he launched more than two decades
ago, Johnson Research and Development Company, now employs two
dozen people, including designers, marketers, and research
scientists. Once again, however, Johnson faces financial worries.
There was a time in my life, he says, when I was independently
wealthy. But that time has passed: Super Soaker profits have
eroded thanks to a host of knockoffs, and now bring in only about
a third of his companys operating budget. For the rest, he relies
on grants and commissionsand in the aftermath of the dot-com bust
and the recent economic crisis, theyve been drying up. Hes begun
borrowing money to keep his research goingand hes betting much
of it, millions of dollars in all, on the JTEC.  
  
In the winter of 2008, Johnson received a promising call from Karl
Littau, a materials scientist with the Palo Alto Research Center
(known as PARC), a subsidiary of Xerox. PARC, which gave the world
the laser printer, Ethernet, and many other groundbreaking
technologies, had expanded into alternative-energy research, and
this had led Littau to the JTEC. Like Paul Werbos, Littau
initially feared that the device sounded too good to be true, but
he and several other PARC scientists set up elaborate
three-dimensional computer models to analyze fluidics and
heat-flow behavior in the JTEC under various conditions, and they
came away from those experiments, he says, really impressed.
Littau, like Werbos, is now a convert. The JTEC, he says, is a
very clever way to extract energy from a heat engine  Its
incredibly elegant.  
  
When I spoke to Littau, he ticked off the potential advantages of
the JTEC over typical heat engines: no moving parts, which means
the engine is more reliable and virtually silent; the safety of
hydrogen, which is essentially benign (unlike, say, Freon); and
the lack of waste produced (the JTEC gives off no carbon orunlike
a fuel celleven water, which, although environmentally harmless,
can corrode equipment). All of these advantages mean
longer-lasting performance and potentially higher
energy-conversion efficiencies.  
  
Commercial photovoltaic solar cells convert approximately 20
percent of received solar energy into electricity. The best
solar-energy systems todaythermal-power plants that concentrate
the suns heat to drive turbinesoperate at a rate of about 30
percent efficiency. The JTEC, Johnson claims, could double that
figure, cutting the cost of producing solar power in half from its
current average of 25 cents per kilowatt-hour, and making it
competitive with coal.  
  
Theres a lot of debate in Washington about carbon emissions and
energy, Paul Werbos saysabout coal, nuclear power, and oil,
what I call the three horsemen of the apocalypse. If we can cut
the cost of solar energy in half, it becomes possible to escape
from the three horsemen. The importance of this is just
unbelievable.  
  
But having wowed PARC, Johnson is now wrestling once again with
the difficulties of working within the confines of the scientific
establishment. PARC wants to publish a paper about the JTEC in a
peer-reviewed scientific journal, both to provide legitimacy and
to encourage members of the scientific community to advance the
technologies involved. But Johnson is unconvinced. Peer review is
fine, he says, as long as youre making incremental improvements
to a technology. But Johnson dreams of advancing by leaps and
bounds.  
  
Adding to Johnsons worries is tension with PARC over
intellectual-property rights. Only recently did Johnson, with much
reluctance, give PARC permission to file for patent protection for
the problems solved in its lab. After more than two decades as his
own boss, Johnson isnt sure how much ownership interestand
potential profithe is willing to give up. All of a sudden, I
have other people inventing stuff that I dont have control over
anymore, Johnson says. They could put patents in place for
things I would need to implement in my engine. Id have to pay
them for my own idea!  
  
Last year, I visited the four-acre commercial property that
Johnson owns on the south side of downtown Atlanta. Wearing
pleated khakis and a long-sleeved polo shirt with a turtleneck
underneath, Johnson took me on a tour of a meticulously
refurbished three-story brick loft space featuring soaring
ceilings and antique wood floors. Johnson intends to transform the
building into a high-tech manufacturing center that will train and
employ workers from the area; however, because of research delays
and the recent economic downturn, those plans are on hold.  
  
Until he can scale up, Johnson is instead leasing his beautiful
loft space to a city agency, while he and his employeesincluding
a handful of scientists with doctorates in chemistry, materials
science, and engineeringhunker down in a low-slung, windowless
warehouse across the parking lot. Its a no-frills space, with
galvanized electrical conduit descending from the ceiling through
gaps where acoustic tiles are missing. On one wall of his office
is a promotional poster created by the retail chain Target that
features Johnsons face amid a pantheon of 19th- and 20th-century
African American inventors. Along another wall is a row of plaques
commemorating a dozen of Johnsons 100-odd patents, including
those for his water-pressure heat pump, his ceramic battery, hair
rollers that dry and set without heat, a diaper that plays a
musical nursery-rhyme alarm when the baby is wet, and the
electrochemical conversion system at the heart of the JTEC. And
hanging crooked above his desk is a cheap black frame that
contains an inspirational quote that has been attributed to Calvin
Coolidge. Under the heading Press On, it reads:  
  
Nothing in the world can take the place of persistence. Talent
will not; nothing is more common than unsuccessful men with
talent. Genius will not; unrewarded genius is almost a proverb.
Education alone will not; the world is full of educated derelicts.
Persistence and determination alone are omnipotent.   
  
After we toured the office cubicles, Johnson swiped a card to
unlock a door, and we entered a cavernous laboratory abuzz with
fluorescent fixtures and thrumming with high-tech equipment. We
stepped across a sticky mat, meant to grab dust from our shoes,
and followed a yellow-paint path across the warehouse floor, past
shelves of chemicals, airtight glove boxes, and banks of machines
bristling with wires, charging and discharging batteries.
Technicians in long blue lab coats and protective goggles milled
about. Some of the equipment stations were housed beneath plastic
clean-room tents topped with large fans and aluminum ductwork that
snaked off toward the ceiling. The lab looked like a disheveled,
family-garage version of a computer-microchip factory, and the
resemblance wasnt coincidental: to develop his proton-exchange
membrane and ceramic batteries, Johnson has borrowed processes
developed by the semiconductor industry for depositing materials,
often atom by atom, onto various substrates. Beaming as he showed
me his latest acquisitiona pricey-looking X-ray photoelectron
spectrometer that lets him analyze a materials atomic
makeupJohnson was clearly in his element.   
  


---

  

JOHNSON
AMBIENT-HEAT ENGINE    
US2012064419

  
RELATED APPLICATIONS  
  
[0001] Not applicable.  
  
STATEMENT REGARDING
FEDERALLY-SPONSORED RESEARCH OR DEVELOPMENT  
  
[0002] Not applicable.  
  
TECHNICAL FIELD  
  
[0003] This invention relates to energy harvesting mechanisms for
generating electrical power, and more particularly, the invention
relates to a thermo-electrochemical device that utilizes hydrogen
to convert heat energy from an environment in which the device is
located into electrical power.  
  
BACKGROUND OF THE INVENTION  
  
[0004] It has long been a goal to develop an engine that operates
on thermal energy that is freely available in the ambient
environment. Consistent with the second law of thermodynamics,
prior attempts at such thermal-energy-harvesting devices required
two distinct sources of thermal energy, namely, a heat source and
a heat sink for supplying and removing heat, respectively, at
different temperatures simultaneously. A heat-source and heat-sink
pair having two distinct, spaced-apart temperatures typically does
not occur naturally and/or plentifully, and thus are generally
difficult to access. Therefore, because ambient heat at a single
atmospheric temperature is more abundant and available than a
simultaneous dual-heat source, a device for harnessing
single-source ambient heat is more desirable than a device that
requires a dual-heat source.  
  
[0005] The present inventor disclosed a device in U.S. Pat. No.
6,899,967. That device relies on cyclic temperature changes in the
environment to produce the needed simultaneous dual-heat source.
The needed temperature difference was provided through the use of
a mass of material that has significant heat capacity. The prior
device is a thermo-electrochemical converter that operates on a
pressure difference between two metal-hydride chambers separated
by a membrane electrode assembly (MEA). In the prior invention,
one metal-hydride chamber is exposed to the ambient environment
while the other is insulated and thermally stabilized. A thermal
mass is coupled to the stabilized chamber to act as a heat
source/sink material. Insulation may be used to thermally isolate
the thermal-mass material from the environment in order to enhance
the temperature difference produced. It absorbs heat and stores it
during periods of elevated ambient temperature and releases that
heat to function as an elevated-temperature heat source during
periods of reduced ambient temperatures. As such, changes in the
temperature of the thermal mass will always lag temperature
changes in its environment. Thus a converter coupled between the
thermal mass and the environment will be subjected to a
simultaneous temperature differential needed for the device to
operate.  
  
[0006] The open-circuit electrical potential due to a hydrogen
pressure differential across a proton-conductive membrane
electrode assembly (MEA) is a linear function of temperature and
proportional to the natural logarithm of the hydrogen pressure
ratio and can be calculated using the Nernst equation (Fuel Cell
Handbook, Fourth Edition, 1999, by J. H. Hirschenhofer, D. B.
Stauffer, R. R. Engleman, and M. G. Klett, at pp. 2-5:  
  
[0000]  
VOC= RT/2F ln(PHi/PLow) Equation 1  
  
[0000] where VOC is open circuit voltage, R is the universal gas
constant, T is the cell absolute temperature in degrees Kelvin, F
is Faraday's constant, PHi is the hydrogen pressure on the
high-pressure side and PLow is the hydrogen pressure on the
low-pressure side.  
  
[0007] The hydrogen pressure produced by a metal-hydride bed
depends on temperature. When the ambient metal-hydride chamber is
at a higher temperature, H2 gas is desorbed from its metal hydride
content and flows through the MEA into the thermally stabilized
chamber, thus generating power. During the next half cycle, when
the temperature of the ambient chamber falls below the temperature
of the insulated chamber, the opposite takes place, hydrogen flows
through the MEA back to the ambient temperature chamber. Hydrogen
thus cycles back and forth under a pressure differential across
the proton-conductive membrane generating power in the process.  
  
[0008] A major limitation encountered with the prior invention is
associated with the need to have a device that is capable of
scavenging power in a relatively efficient manner. A major
limitation in achieving efficient operation is associated with the
difficulty of creating a significant temperature difference
between components. This is particularly true for a small device.
The close proximity of the components in a small device allows
parasitic heat transfer losses between the two metal-hydride beds
that are too high whenever a significant temperature gradient is
present. In larger devices, the need for insulation and heat
sink/source material can result in a large, bulky device that is
difficult to implement. Thus it can be appreciated that a need
remains for a device for producing electrical power using heat
from its ambient environment that overcomes the disadvantages and
shortcomings of previous chemical and thermal converters that need
a simultaneous temperature difference in order to operate.  
  
SUMMARY OF THE INVENTION  
  
[0009] According to an embodiment of the present invention, an
electrochemical conversion system has a thermally-conductive
housing. The interior of the housing is divided into a
high-pressure chamber and a low-pressure chamber by a
substantially gas-impermeable membrane. An ionically-conductive,
electrical-energy-generating mechanism forms at least a portion of
the substantially gas-impermeable membrane. A first
hydrogen-storage medium is disposed within the high-pressure
chamber. A second hydrogen-storage medium is disposed within the
low-pressure chamber. The characteristics of the hydrogen-storage
mediums are such that at any given temperature, the first
hydrogen-storage medium stores hydrogen at a first average storage
pressure that is higher than a second average storage pressure at
which the second hydrogen-storage medium stores hydrogen. The
housing contains an initial quantity of hydrogen. An
electrical-energy storage device connected to the
ionically-conductive, electrical-energy-generating mechanism is
selectively operable between a charge condition and a discharge
condition.  
  
[0010] The Johnson Ambient-Heat Engine (JANE) (an electrochemical
conversion system) uses thermal transients that naturally occur in
its ambient environment to generate electrical power. During
selected periods of high temperature, the electrochemical
conversion system naturally produces a high voltage output for a
given pressure ratio between the high-pressure and low-pressure
chambers. The electrical-energy storage device is charged by
allowing hydrogen to expand from the high-pressure chamber into
the low-pressure chamber during periods of high temperature and
thereby high voltage. Conversely, the electrochemical conversion
system produces low voltage during periods of low temperature. The
electrical-energy storage device is discharged during selected low
voltage periods to compress hydrogen from the low-pressure chamber
back into the high-pressure chamber. Given two electrons per
hydrogen molecule, returning the hydrogen to the high-pressure
chamber requires the same amount of current as that generated when
it transitioned to the low-pressure chamber. However, less energy
is required since the hydrogen is returned during periods when the
voltage of the electrochemical conversion system is low. The
difference in energy produced during high-temperature expansion
versus low temperature-compression is retained within the
electrical-energy storage device and is available for supply to an
external load.  
  
BRIEF DESCRIPTION OF THE DRAWINGS  
  
[0011] FIG. 1 is a schematic
illustration of an electrochemical conversion system in
accordance with an embodiment of the invention.  
  

![](us201-1.jpg)

  
[0012] FIG. 2 is a data plot
showing the voltage potential of a proton-conductive
Membrane-Electrode Assembly (MEA) cell as a function of
temperature for selected ranges of hydrogen pressure ratios
across the MEA.  
  

![](us201-2.jpg)

  
[0013] FIG. 3 is a data plot
showing hydrogen pressure as a function of hydrogen content for
a representative type and brand of metal hydride at selected
temperatures.  
  

![](us201-3.jpg)

  
[0014] FIG. 4 is a data plot
showing midpoint hydrogen pressure as a function of temperature
for selected representative metal hydrides suitable for use in
of an electrochemical conversion system in accordance with an
embodiment of the invention.  
  

![](us201-4.jpg)

  
[0015] FIG. 5 is a data plot of
Nernst voltage change as a function of temperature for three
example metal-hydride pairings wherein the metal-hydride pairs
are selected based upon predicted, advantageous pressure
differentials.  
  

![](us201-5.jpg)

  
[0016] FIG. 6 is a schematic
illustration of an electrochemical conversion system in
accordance with an embodiment of the invention depicting
high/low-temperature operation at high ambient temperature.  
  

![](us201-6.jpg)

  
[0017] FIG. 7 is a schematic
illustration of an electrochemical conversion system in
accordance with an embodiment of the invention depicting
high/low-temperature operation at low ambient temperature.  
  

![](us201-7.jpg)

  
[0018] FIG. 8 is a
Temperature-Entropy diagram representing ideal operation of an
electrochemical conversion system in accordance with embodiments
of the invention, viewed as an Ambient-Heat Engine operating on
a Sterling thermodynamic cycle.  
  

![](us201-8.jpg)

  
[0019] FIG. 9 is a schematic
illustration of an electrochemical conversion system in
accordance with an embodiment of the invention showing
metal-hydride beds, MEA arrays or stacks, battery and controller
system under example operating conditions.  
  

![](us201-9.jpg)

  
[0020] FIG. 10 is a schematic
illustration of an electrochemical conversion system in
accordance with an embodiment of the invention showing
metal-hydride beds, MEA array or stack, battery integrated with
controller system for dynamic operation over a range of mean
temperatures.  
  

![](us201-10.jpg)

  
DETAILED DESCRIPTION  
  
[0021] Embodiments of the present invention are described herein.
The disclosed embodiments are merely exemplary of the invention
that may be embodied in various and alternative forms, and
combinations thereof. As used herein, the word "exemplary" is used
expansively to refer to embodiments that serve as illustrations,
specimens, models, or patterns. The figures are not necessarily to
scale and some features may be exaggerated or minimized to show
details of particular components. In other instances, well-known
components, systems, materials, or methods have not been described
in detail in order to avoid obscuring the present invention.
Therefore, at least some specific structural and functional
details disclosed herein are not to be interpreted as limiting,
but merely as a basis for the claims and as a representative basis
for teaching one skilled in the art to variously employ the
present invention.  
  
Overview  
  
[0022] As an overview, the invention teaches a system and
methodology for generating electrical energy, which electrical
energy can be applied to devices requiring electric power. The
concept and overall embodiments of the invention are referred to
herein generally as the Johnson Ambient-Heat Engine. The Johnson
Ambient-Heat Engine is an apparatus that is powered by thermal
transients in its environment. It utilizes thermodynamic
principles of heat engines and electrochemical-cell principles in
combination to generate electrical energy.  
  
[0023] The apparatus performs through a combination of a
thermodynamic processes and complementary electrochemical
reactions. The phrase electrochemical conversion system will be
used throughout this description and claims to generally refer to
the invention. The invention also may be considered an "energy
harvester," and more particularly may be considered a "thermal
energy harvester." Thus the invention as described and claimed
herein may be referred to alternatively as the Johnson
Ambient-Heat Engine, an electrochemical conversion system and an
energy harvester.  
  
INVENTION DESCRIBED IN DETAIL  
  
[0024] Referring now to the drawings, wherein like numerals
indicate like elements throughout the several views, the drawings
illustrate certain of the various aspects of exemplary
embodiments.  
  
[0025] Referring first to FIG. 1, therein is illustrated a
schematic representation of an electrochemical conversion system
10 in accordance with an embodiment of the invention. A
thermally-conductive housing 20 encloses a high-pressure chamber
22 and a low-pressure chamber 24 that are separated from one
another by a substantially gas-impermeable barrier 26. An
ionically-conductive, electrical-energy-generating mechanism forms
at least a portion of the substantially gas-impermeable barrier
26. In the basic embodiment of FIG. 1, the entire barrier 26 is
formed of an ionically-conductive, electrical-energy-generating
mechanism. The central component of the ionically-conductive,
electrical-energy-generating mechanism is an electrochemical cell
30 formed of electrodes 32, 34 that sandwich an electrolyte medium
36. The electrolyte medium is substantially impermeable. The key
elements of the electrochemical cell, namely, electrodes 32, 34
and an electrolyte medium 36, may be referred to as a
Membrane-Electrode Assembly (MEA) 30. There may be more than one
cell, or MEA, however, in the embodiment illustrated in FIG. 1, a
single cell (or MEA) forms the substantially impermeable barrier.  
  
[0026] When the electrolyte medium 36 is a proton-conductive
membrane, a first hydrogen-storage medium 42 is disposed within
the high-pressure chamber 22. A second hydrogen-storage medium 44
is disposed within the low-pressure chamber 24. In a closed
volume, as in the chambers of the invention, the hydrogen gas will
attain an equilibrium pressure in each chamber which depends on
the temperature and the amount of hydrogen contained within the
metal-hydride of that respective chamber. The equilibrium pressure
of a given metal hydride will vary in accordance with the
temperature to which it is subjected. The equilibrium pressure
will increase with increases in temperature and decrease with
decreases in temperature. Although there is hysteresis, the
equilibrium pressure may be considered a tipping point for
absorption and desorption of hydrogen. At a given equilibrium
pressure, the pressure of hydrogen gas above the equilibrium
pressure will cause hydrogen to be absorbed by the hydride and,
conversely, hydrogen pressure below the given equilibrium pressure
will cause hydrogen to be released (desorbed) by the hydride.  
  
[0027] The characteristics of the hydrogen-storage mediums 42, 44
are such that at any given temperature, the first hydrogen-storage
medium 42 stores hydrogen at a first average storage pressure that
is higher than a second average storage pressure at which the
second hydrogen-storage medium 44 stores hydrogen. Effective
hydrogen-storage mediums 42, 44 are metal-hydrides (also referred
to herein as metal-hydride materials). Thus effective
hydrogen-storage mediums are a high-pressure metal-hydride
material and a low-pressure metal-hydride material, respectively.
The housing 20 contains an initial quantity of hydrogen. A
sufficient quantity will have to be aggregated under pressure in
the high-pressure chamber 22 to begin the process of generating
electrical energy.  
  
[0028] Electrical conductors 46, 48 extend from respective
electrodes 32, 34 of the MEA 30 (or other electrochemical cell
configuration) to complete the electrical circuit that is
necessary for operation of the invention. The circuit may be
completed by components such as a simple electronic load or a
controller system, or a combination of components 50. The
invention teaches connection of the MEA 30 (or other cell) to an
electrical-energy storage device, such as a capacitor or battery.
The electrical-energy storage device is selectively operable
between a charge condition and a discharge condition. More
particularly, the invention teaches connection of conductors 46,
48 to a rechargeable battery. The load 50 may be a combination of
a rechargeable battery and controller system that selectively
places the battery component in a charge condition when certain
parameters are met and in a discharge condition when other
parameters are met.  
  
[0029] The chemical reactions that take place in the high-pressure
chamber 22 and low-pressure chamber 24, respectively, are written
out in the chambers 22, 24 in FIG. 1.  
  
[0030] Ideally, the various components comprising the
thermo-electrochemical converter, particularly the environment,
the housing, high-temperature metal-hydride bed, the MEA and the
low-temperature metal-hydride bed are tightly coupled thermally
such that all of the components are maintained at or near a single
uniform temperature. Ideally, the uniform temperature is the
temperature of the environment existing at the time when an
expansion or compression event occurs. As a given metal-hydride
bed undergoes the endothermic process of releasing hydrogen or
exothermic process of absorbing hydrogen, heat is conducted
between it and other components so as to maintain the relatively
uniform temperature. As hydrogen is compressed or expanded through
the MEA heat is removed or supplied respectively so as to maintain
the uniform temperature. The thermal energy needed or removed to
maintain the temperature of the system (including MEA, cells,
hydrides and hydrogen) as hydrogen expands or undergoes
compression respectively is thermal energy supplied to or from the
environment. It is energy that is conducted through the housing 20
to or from the MEA 36, the high-pressure chamber 22 and
low-pressure chamber 24. This thermal energy from the environment
is considered "ambient" thermal energy. "Ambient" in this context
is considered to mean heat from the environment where the housing
is located. In a "local sense," the ambient environment is any
enclosure wherein the housing 20 is subjected to the temperature
level and temperature transients occurring in the enclosure.
Applicable enclosures include but are not limited to a building, a
room in a building structure, or a compartment or enclosure in
close proximity to a combustion engine. A local ambient
environment also encompasses a combustion engine (or other
heat-producing instrumentality) itself. The housing 20 may be
mounted upon such ambient environment. In a more general sense,
the ambient environment may be the atmosphere of the great
outdoors wherein thermal energy and temperature transients are
provided by the sun.  
  
[0031] The materials of the high-pressure and low-pressure beds
have been selected such that at any given temperature the storage
pressure of the high-pressure storage medium 42 is greater than
that of the low-pressure storage medium 44. And, further, because
hydrogen is aggregated under pressure in the high-pressure chamber
22, a greater hydrogen pressure will be exerted in the
high-pressure chamber 42 than in the low-pressure chamber 24.  
  
[0032] The "Load/Controller system" 50 includes a battery or other
electrical-energy storage device. When the circuit with the MEA 30
(or other electrical-energy-generating mechanism) is closed
electrical power is produced as hydrogen, under pressure and as
ions, migrates from the high-pressure chamber to the low-pressure
chamber. In the case where the electrical-energy-generating
mechanism is a hydrogen conductive MEA, hydrogen undergoes
oxidation at the high-pressure electrode 32-electrolyte membrane
36 interface. Electrons are conducted through the circuit as the
hydrogen ions (protons) are conducted through electrolyte membrane
36. In the MEA electrode 34 in the low-pressure chamber 24, the
hydrogen ions being conducted through the membrane combine with
the electrons conducted through the closed circuit to
"reconstitute" hydrogen molecules. The hydrogen reconstituted in
the low-pressure electrode exits the electrode and becomes
substantially absorbed within the second hydrogen-storage medium
44 that is disposed within the low-pressure chamber 24 as the
second hydrogen storage medium functions to maintain a
low-pressure within the chamber 24.  
  
[0033] Hydrogen is returned to the high-pressure chamber 22 from
the low-pressure chamber 24 by applying a voltage of sufficient
magnitude to reverse the current across the MEA 30 or other
electrical-energy-generating mechanism. In this case, hydrogen is
conducted from the low-pressure chamber 24 to high-pressure
chamber 22. Under the reverse current, electrons are striped from
protons in the low-pressure chamber at the low-pressure electrode
34-electrolyte 36 interface and combined with protons in the
high-pressure chamber at high pressure electrode 32-electrolyte 36
interface as the protons are conducted through membrane 36. The
current and voltage are provided by the capacitor, battery or
other electrical-energy storage device.  
  
[0034] FIG. 2 shows the voltage across a proton conductive
Membrane Electrode Assembly (MEA) as a function of temperature as
calculated using the Nernst equation for selected hydrogen
pressure ratios. For a given pressure ratio, the MEA voltage is
high when the temperature is high and low when the MEA temperature
is low. The controller 50 operates to select charge and discharge
events under temperature conditions such that less electrical
energy is required to return hydrogen to the high-pressure chamber
than is produced to charge the battery. The difference between
voltage generated during high-temperature migration and voltage
required to facilitate low-temperature migration is useable
electrical energy that is retained in the electrical-energy
storage device.  
  
[0035] Referring now to FIG. 3, a data plot shows the pressure and
temperature relationship versus hydrogen content for an example
metal hydride. This particular chart is for a metal hydride
commercially marketed as Hy-Stor(R) 207 that has a chemical
formula LaNi4.7Al0.3. The product is believed to be sold and
distributed by Hera USA Inc., a Delaware Corporation, having a
contact address at C/O Corporation Svc. Company, 2711 Centerville,
Road Suite 400 Wilmington Del. 19808. OMEGA, the quantity along
the x-axis, is the amount of hydrogen in the metal hydride as a
ratio to the maximum amount of hydrogen that the hydride can
absorb. As can be seen from the data plot, metal hydrides exhibit
pressure plateaus that are a function of temperature whereby, at a
given temperature, the majority of the hydrogen is stored with
minimal increase in pressure. The pressure level of the plateau
increases with increasing temperature. The "midpoint pressure" for
a given temperature is defined as the pressure at which the
hydride contains 50% (0.50) of its storage capacity. The midpoint
pressure may be used as a representative value for comparison of
pressures of different hydrogen-ladened metal-hydride materials at
a given temperature.  
  
[0036] Referring now to FIG. 4, therein is shown a plot of the
variation of the midpoint pressure versus temperature for several
selected commercially available metal hydrides. The name
Hydralloy(R)C5 is a trademark for the metal hydride having
chemical formula: Ti0.98Zr0.02V0.43Fe0.09Cr0.05Mn1.5. The product
is believed to be sold and distributed by GfE Gesellschaft fur
Elektrometallurgie mbH Ltd Liab Co, Fed Rep Germany, Hofener
Strasse 45, 8500 Nurnberg 1 Fed Rep Germany, a subsidiary of AMG
Advanced Metallurgical Group N.V., Netherlands. FIG. 3 highlights
the fact that metal hydrides can be selectively paired with each
other based on how their midpoint pressures change with
temperature. The data provided by the metal hydride suppliers
indicate that the midpoint pressures of some of the metal hydrides
converge toward each other with increasing temperature (that is,
increasing temperature transients) whereas others diverge. Thus
selected metal hydrides can be paired together as high-pressure
and low-pressure beds for optimum performance in the ambient-heat
engine application. The power produced as hydrogen passes from the
high-pressure bed to the low-pressure bed through the MEA
increases as the pressure ratios between the two beds increase.
Similarly, the power required to recompress hydrogen from the
low-pressure hydride bed to the high-pressure hydride bed
decreases as the pressure ratio decreases. Therefore, higher
performance is achieved by the ambient-heat engine for the case
where the average pressures of the high- and low-pressure
metal-hydride beds diverge with increasing temperature.  
  
[0037] Referring now to FIG. 5, therein is shown a plot of an
increase in Nernst voltage versus increase in temperature above a
starting temperature of 300 degrees K for three example
metal-hydride pairs at their midpoint pressure ratios. The pairs
include MnNi3Co2 paired with Hy-Stor(R) 207, MnNi3Co2 paired with
Pd0.7Ag0.3, and TiCo paired with Pd0.7Ag0.3. The change in voltage
with change in temperature is greatest for the TiCo and Pd0.7Ag0.3
pair.  
  
[0038] Referring now simultaneously to FIGS. 6, 7 and 8, these
figures illustrate ideal operation of an ambient-heat engine
(electrochemical conversion system) 12 in accordance with an
embodiment of the present invention. The term ambient-heat engine
as used herein refers to that electrochemical conversion system
that has a thermal-heat component as described herein. The
engine/system 12 described operates under the same combined
thermal and electrochemical principles as the system 10
illustrated in FIG. 1 and discussed above. Like elements operate
in the same manner as previously described herein. Referring now
particularly to FIGS. 6 and 7, the engine includes a housing 60,
heat-conductive baffle 66 and MEA array or stack 68. The baffle 66
and MEA array 68 form a substantially gas-impermeable barrier that
separates the housing 60 into a high-pressure chamber 62 and a
low-pressure chamber 64. The MEA array 68 is an
ionically-conductive, electrical-energy-generating mechanism.
Although the ionically-conductive, electrical-energy-generating
mechanism 68 could comprise a single electrochemical cell as
illustrated and described with respect to FIG. 1, the embodiment
of FIGS. 6 and 7 teaches a multiple-cell array or stack in which
each cell 70 is a Membrane Electrode Assembly (MEA) comprised of a
pair of electrodes 72, 74 and a proton-conductive electrolyte
medium 76. The electrodes 72 and 74 are configured on opposite
sides of the proton-conductive electrolyte medium 76 such that the
medium is sandwiched between the two electrodes. The electrolyte
medium 76 may be a single, contiguous, elongated structure or it
may be a series of smaller structures placed end-to-end or
stacked. Each approach effectively forms a set of multiple
membrane electrode assemblies each having an electrolyte layer
sandwiched between a pair of opposing electrodes 72, 74. The
high-pressure chamber 62 contains first hydrogen-storage medium in
the form of a high-pressure metal hydride 82. The electrodes 72,
74 of the multiple cells 70 are connected in series
(anode/negative electrode to cathode/positive electrode) to
respective conductors 92, 94. The low-pressure chamber 64 contains
a second storage medium in the form of low-pressure metal hydride
84. A controller system 90 that includes a combined controller and
electrical-energy storage device is electrically coupled to the
MEA array 68 through conductors 92, 94. Controller system 90
contains an electrical-energy storage device such as a battery or
capacitor.  
  
[0039] Referring now also to FIG. 8, the Temperature-Entropy (T-S)
diagram of FIG. 8 represents operation of the AHE device
illustrated in FIGS. 6 and 7. The indicators QHT and QLT denote
the high-temperature and low-temperature heat quantities described
with respect to the engines/systems illustrated in FIGS. 6 and 7.
Beginning at high-temperature, high-pressure State 1, represented
in FIG. 6 as "DAY" operation, hydrogen expands to low-pressure
state 2 under, ideally, constant-temperature conditions as the
engine extracts the needed heat of expansion as heat QHT from the
engine's environment.  
  
[0040] When high-temperature heat, denoted as QHT with direction
arrow 80 in FIG. 6, from the engine environment (ambient thermal
energy or ambient heat) is available to the engine, the controller
system 90 applies a load to the MEA array 68. Electrical current
is produced as hydrogen passes from the high-pressure,
metal-hydride bed 82 and high-pressure chamber 62 (as H2) through
the proton-conductive membrane 76 (as H<+>) to the
low-pressure chamber 64 and low-pressure, metal-hydride bed 84 (as
H2) as illustrated by direction arrows 78. Freed electrons flow
through the conductor 92 to the electrical-energy storage device
(battery) that is part of the controller system 90 in the
direction shown by direction arrow 96. Useful electrical energy
generated by the engine is stored within an
electrical-energy-storage device (battery) that is a part of the
combined battery and controller system 90. Hydrogen released from
the high-pressure metal-hydride bed, after passing through the MEA
by becoming ions H<+> and then being reconstituted as
hydrogen molecules H2, is absorbed by the low-pressure
metal-hydride bed on the low-pressure side of the MEA stack 68.  
  
[0041] Referring again to the temperature entropy diagram shown in
FIG. 8, once high-temperature, low-pressure State 2 is achieved,
operation stops and the engine transitions from State 2 to State 3
(from the elevated temperature conditions depicted in FIG. 6 to
the low-temperature state represented in FIG. 7). This temperature
change takes place over an interval of time and represents a
decrease in ambient temperature. This transition from State 2 to
State 3 is essentially a constant volume process with no movement
of the hydrogen or change in state during the transition. Ideally,
the absorbed hydrogen substantially remains absorbed in the
metal-hydride bed on the low-pressure side of the engine.  
  
[0042] As depicted in FIG. 7, when the environment reaches a
predetermined low temperature as detected and registered by
controller system 90, controller system 90 supplies power by means
of charged battery to MEA array 68 as illustrated by direction
arrow 98 to electronically "pump" hydrogen from the low-pressure
side of the engine back to the high-pressure side as illustrated
by direction arrows 87. The compression process transitions the
engine from State 3 to State 4 of the T-S diagram of FIG. 8. This
is, ideally, a constant-temperature compression process as heat of
compression QLT is dissipated to the engine's environment as
illustrated by direction arrow 89. The transition from state 4
back to state 1 to complete the cycle is a constant-volume process
as the hydrogen remains substantially absorbed in the
high-pressure, metal-hydride bed, thus the cycle continues with
changes in the temperature of the engine's environment.  
  
[0043] As an example, consider a daily thermal environment cycle
of 10[deg.] C., that is, during a 24-hour period the difference
between a high and a low ambient temperature is 10[deg.] C. During
long thermal transitions such as day-night cycles, even a
relatively large engine could have time to come into thermal
equilibrium with its environment. Assume an engine, as taught by
the invention, that uses the Pd0.7Ag0.3 and TiCo metal-hydride
pair. Referring back momentarily to FIG. 5, the voltage change for
this pair over a temperature change of 10[deg.] C. is about 1.6
mV. This value is derived under the condition that the midpoint
pressure ratios represent an average of the pressure ratio
maintained during transition of the hydrogen between hydride beds.
A reasonable hydrogen capacity per unit volume of an average metal
hydride is equivalent to about 1.86 Ah/cc in electrons. Assume
that the high-pressure and low-pressure chambers each contain 1 cc
of metal hydride. Given these conditions, the expansion process
occurs at 1.6 mV higher voltage than the compression process thus
a difference in energy of 2.98 mWh/cc (that is, 1.86 Ah/cc\*1.6
mV). This amount of energy is available for powering an external
load. If averaged over a period of 24 hours, the average level of
continuous available power would be about 0.124 mW per cubic
centimeter (that is, 2.98 mWh/cc/24 h=0.124 mW/cc) of metal
hydride.  
  
[0044] Given practical implementation constraints, assume an
average power output of 0.1 mW/cm<3 >for this system.
Additional thermal cycles result in the generation of additional
power. Multiple daily cycles are possible and the controller
system may be programmed to anticipate and respond to thermal
transients that may be greater than or less than the 10[deg.] C.
example transient disclosed herein. Consider one possible
application wherein a portable electronic device that may be
carried on one's person into and out of buildings or other
situations that change the engine's thermal environment.  
  
[0045] To achieve useful output voltage levels, the MEA may be
configured as an array or stack of MEA cells with electrical
interconnects connecting the cells in series. A single common
membrane for the cells in the array or multiple membranes may be
aligned to achieve a desired number of cells and voltage level.
The amount of hydrogen cycled back and forth across the MEA stack
remains constant on average during operation of the engine.
Therefore, the difference in energy is extracted based on a
difference in cell voltage between the expansion and compression
half cycles of the engine.  
  
[0046] Referring now to FIG. 9, therein is illustrated
schematically an electrochemical conversion system 14 in
accordance with another embodiment of the invention. A
thermally-conductive housing 100 is separated into a high-pressure
chamber 102 and a low-pressure chamber 104 by a substantially
gas-impermeable barrier. Ambient heat of the environment QE and
heat from within the housing 100 are interchanged through the
housing 100, as denoted by the bi-directional arrow 120. As with
the systems 10, 12 illustrated and previously described herein, at
least a portion of the substantially gas-impermeable barrier
comprises an ionically-conductive, electrical-energy-generating
mechanism. A particularly suitable ionically-conductive,
electrical-energy-generating mechanism is at least one
membrane-electrode assembly type of electrochemical cell. The MEA
and constituent elements described previously herein are also
suitable for use in the embodiment of FIG. 9. As before, the
membrane of the MEA provides the substantially gas-impermeable
barrier. Somewhat similar to the embodiment of FIGS. 6 and 7, the
present embodiment uses multiple MEA's connected in series. For
convenience, the illustration of FIG. 9 uses a graphic icon to
represent MEA cells. The icon is denoted by the numeral 112 and
consists of the symbol for a cell (positive and negative
electrode) inscribed within a circle as a symbol for at least one
MEA. The icon is also used to represent one or a grouping of more
than one MEA. Further, the groupings of the graphic MEA icon 112
are used herein to represent an array, or stack, 110 of individual
MEA cells 112. The array, or stack, 110 is comprised of two MEA
sub-arrays or stacks 116, 118 with all the individual cells
connected in series. One sub-array contains more MEA's than the
other. In an example, the array, or stack, 110, comprises 142 MEA
cells all connected in series and segmented into a first sub-array
116 of 138 cells and a second sub-array 118 of 4 cells. A first
hydrogen-storage medium, in the form of a high-pressure,
metal-hydride bed 122 is disposed in the high-pressure chamber
102. A second hydrogen-storage medium, in the form of a
low-pressure, metal-hydride bed 124, is disposed in the
low-pressure chamber 104. Operation of the arrays is such that the
hydrogen passes across the cells uniformly. Since all the cells
are connected in series, the current through each and therefore
the hydrogen flow across each must be the same. Assuming operation
over a 10[deg.] C. temperature swing between 20[deg.] C. and
30[deg.] C. and the Pd0.7Ag0.3 and TiCo metal-hydride pair, the
Nernst voltage at 20[deg.] C. is 0.02762V and at 30[deg.] C. is
0.02926V at the midpoint pressures for these materials.  
  
[0047] The system 14 further includes controller system 130,
battery 132, normally-open charge control switch 140 and
normally-open regeneration control switch 142. Operation of the
system 14 is such that when the temperature is high, say 30[deg.]
C., the 138 cells in group 116 produce a voltage of 4.03V (that
is, 138 cells\*0.02926 V/cell). Output power from MEA array group
116 is supplied at this voltage and controller system 130 closes
switch 140 to charge battery 132. The resulting current flow
allows hydrogen to expand from high-pressure bed 102 to
low-pressure bed 104. Assume that each bed is sized to supply and
absorb an amount of hydrogen equivalent to 1.86 Ah of current
capacity. The geometry of the system (that is, cells, chambers,
etc.) is such that the hydrogen transfer is divided over the
number of MEA cells in the stack or array. This alignment results
in each cell transferring an amount of hydrogen equivalent to an
electrical charge of 13.5 mAh (that is, 1.86 Ah/138 cells).
Therefore, 13.5 mAh of charge is supplied to battery 132 at a
voltage of 4.03 Volts.  
  
[0048] Switch 140 is returned to an open state after charging
stops. For battery-charging condition, electric current is
dissipated from the larger MEA sub-array 116 through a connector
134 and the closed switch 140 in the direction of the direction
arrow 144. When the system is in a discharge-battery
configuration, current flows from the battery 132 through closed
switch 142 and connector 136 into the full MEA array 110 in the
direction shown by direction arrow 146.  
  
[0049] Optimally, battery discharge to "recharge" hydrogen in the
high-pressure chamber will be effected when the temperature is
low, say 20[deg.] C. At that temperature, the voltage of the
individual cells is reduced to 0.02762V, as given by the Nernst
equation. Under this condition, controller system 130 closes
switch 142 and thereby connects rechargeable battery 132 in series
with the four cells that are in group, or sub-array, 118 and the
138 cells of group, or sub-array, 116. At 20[deg.] C., the 142 MEA
cells connected in series produce a voltage of only 3.92V (that
is, 142 cells\*0.02762 V/cell). Conversely, this is the amount of
voltage that is necessary to return (or pump) the same quantity of
hydrogen back across the membrane(s) at the lower temperature and
associated pressure ratio. The battery, having been previously
charged to 4.03 volts, now supplies power to the full MEA array
110 to pump hydrogen back from low-pressure bed 124 to
high-pressure bed 122. Return of the equivalent of 1.86 Ah of
hydrogen to the high-pressure chamber is now divided over 142
cells requiring an application of electrical energy from the
battery of only 10.3 mAh (that is, 1.86 Ah/142 cells). In this
simple example, 3.1 mAh (that is, 13.5 mAh-10.3 mAh) of residual
capacity of electrical energy charge remains available in the
battery 132 after the hydrogen has been pumped back to the
high-pressure side of the engine. This residual, thus harvested,
energy can be used for external applications and the ambient-heat
engine is now ready for the follow-on power half cycle.  
  
[0050] Charging is initiated after an increasing temperature
transient has occurred in the ambient environment. Such charge
initiation can be facilitated through use of a sensing system and
detector that work in conjunction with the controller system 130
to recognize when charging may be conducted effectively. For
example, a temperature sensor may detect the ending, stabilization
or leveling off of an increasing temperature transient. If the
controller 130 determines that the configuration of the engine and
the magnitude of the temperature change are suitable for a charge
or discharge event, then it will initiate such an event.
Similarly, the event may be initiated upon the detection of a
temperature change at the housing or in the ambient environment of
a predetermined magnitude over a predetermined period of time. As
another example, a pressure sensor may detect that a predetermined
pressure in the high-pressure chamber 102 has been reached or that
a predetermined pressure differential between the high-pressure
chamber 102 and the low-pressure chamber 104 has been reached.
Charging may be stopped when the battery 132 has been charged to a
predetermined level. For example, a voltage sensor and detecting
system may be used in conjunction with the controller system 130.  
  
[0051] The battery 132 may be placed in a discharge condition for
at least two purposes. One purpose is to provide electrical energy
to an external load. The battery 132 may also be placed in a
discharge condition for the purpose of providing current through
and a voltage potential across the MEA so as to cause hydrogen to
migrate from the low-pressure chamber 104 to the high-pressure
chamber 102. This is in effect a "recharging" of the high-pressure
chamber 102 with hydrogen. Discharge of battery 132 to recharge
the hydrogen may be facilitated through use of sensor and
detection systems in conjunction with the controller system 130.
Battery discharge is terminated when a sufficient amount of
hydrogen has been placed in or returned to the high-pressure
chamber 102 and hydride bed 122. The "recharged" hydrogen
condition in the high-pressure chamber 102 and associated hydride
bed may be detected by a sensing mechanism that works in
conjunction with the controller system 130 to recognize that
sufficient hydrogen is now in the high-pressure chamber. For
example, and not by way of limitation, a pressure sensor may
detect that a predetermined hydrogen pressure has been achieved.
As a further example, and also not by way of limitation, a charge
sensor to integrate current during the charge period as a part of
the controller system may detect and determine that that at least
as many hydrogen ions as migrated from the high-pressure chamber
to the low-pressure chamber during the battery 132 charging have
been returned to the high-pressure chamber.  
  
[0052] Referring now to FIG. 10, an electrochemical conversion
system 16 has several elements similar to the systems 10, 12, 14
previously illustrated and described herein. A
thermally-conductive housing 160 defines an interior that is
divided into a high-pressure chamber 162 and a low-pressure
chamber 164 by a substantially gas-impermeable barrier that is
formed at least in-part by an ionically-conductive,
electrical-energy-generating mechanism. Ambient heat of the
environment QE and heat from within the housing 160 are
interchangeable through the housing 160, as denoted by the
bi-directional arrow 180. A particularly suitable
ionically-conductive, electrical-energy-generating mechanism is at
least one membrane-electrode assembly (MEA) type of
electrochemical cell. The MEA and constituent elements described
previously herein are also suitable for use in the embodiment of
FIG. 10. As before, the membrane of the MEA provides the
substantially gas-impermeable barrier. The ionically-conductive,
electrical-energy-generating mechanism comprises an MEA array, or
stack 170. The array/stack 170 comprises individual MEA's
electrically connected in series. As in the case of the embodiment
of FIG. 14, for convenience, the illustration of FIG. 10 uses a
graphic icon to represent MEA cells. The icon is denoted by the
numeral 172 and consists of the symbol for a cell (positive and
negative electrode) inscribed within a circle as a symbol for at
least one MEA. The icon is used to represent one or a grouping of
more than one MEA. Further, the grouping of the graphic MEA icons
172 is used herein to represent an array, or stack, 170 of
individual MEA cells 172. A first hydrogen-storage medium, in the
form of a high-pressure, metal-hydride bed 182 is disposed in the
high-pressure chamber 162. A second hydrogen-storage medium, in
the form of a low-pressure, metal-hydride bed 184, is disposed in
the low-pressure chamber 164. Operation of the array, or stack,
170 is such that the hydrogen passes across all of the cells
uniformly.  
  
[0053] A charge controller system 190 includes a rechargeable
battery, electrical circuit components, sensing components,
switching components, battery and discharge charge circuitry, and
software components including but not limited to pattern
recognition software. Internal logic of the charge controller
system 190 enables it to selectively extract power from the MEA
array/stack 170 to charge the battery and/or to direct electrical
power elsewhere or to supply power to the MEA array/stack 170 to
regenerate the metal-hydride beds 182, 184. The pattern
recognition software allows the charge controller system 190 to
recognize patterns in temperature transients and hydrogen pressure
transients and thereby anticipate peaks and ebbs in temperature so
as to identify optimum times at which to initiate a battery charge
or metal-hydride regeneration event. The battery charge circuitry
allows the charge controller system 190 to operate efficiently
over a wide range of MEA array open circuit voltages. As such it
can perform a battery charge or hydride-bed regeneration event
independent of the mean environmental temperature or associated
mean operating voltage of the MEA array. This feature gives the
engine the versatility to operate about a mean environmental
temperature of 10[deg.] C., 40[deg.] C. or other mean that the
environmental temperature may dictate.  
  
Metal Hydrides' Role in Operation
of Ambient-Heat Engine  
  
[0054] Metal hydrides are metallic substances that are capable of
absorbing hydrogen gas when exposed to the hydrogen gas at certain
pressures and temperatures. The terminology used in discussing
metal hydrides is sometimes confusing. A primary reason for the
confusion is that the term metal hydride can be used to refer to
the hydrogen-absorptive material both before and after it has
absorbed hydrogen. Therefore, for purposes of explanation herein,
the pre-absorption material generally will be referred to as
"metal hydride" or "metal-hydride material," or, simply,
"hydride." After the metal hydride, or metal-hydride material, has
absorbed hydrogen gas, for clarity, the resulting product
sometimes is referred to herein as a hydrogen-ladened
metal-hydride." The "hydrogen-ladened" adjective is not used where
from the context the state or condition of hydrogen absorption is
clear. In the hydrogen-ladened metal hydride, hydrogen is
distributed throughout the metal-lattice structure of the metal
hydride. The metal-hydride material is typically provided in a
crushed or other configuration that maximizes the surface area to
be contacted by hydrogen gas.  
  
[0055] Ideally, if the pressure of the hydrogen gas rises above
the equilibrium pressure, then hydrogen will be absorbed into the
metal hydride. Absorption is exothermic since heat will be
released during the process. If sufficient heat is not transferred
away from the metal hydride to support continued hydrogen
absorption at a stable temperature, then the temperature will
increase to a point where a new, higher equilibrium pressure state
is attained. On the other hand, if the pressure of hydrogen gas
drops below the equilibrium pressure, hydrogen gas will be
released from the hydrogen-ladened metal-hydride material. The
hydrogen-release process is endothermic since heat input is
required to maintain the desorption process. If sufficient heat is
not available to support continued hydrogen evolution at a stable
temperature, then the temperature will drop to a point where a new
lower equilibrium pressure is attained. In practice, for a given
material, the equilibrium pressures and temperatures for
absorption are different from the equilibrium pressures and
temperatures for desorption by finite amounts. This difference is
generally referred to as the hysteresis property of the material
and must be accounted for by appropriately selecting metal
hydrides for use in the JAHE.  
  
[0056] The ambient-heat engine 10, 12, 14, 16 operates cyclically
and, as such, any point or region in the cycle that is illustrated
in the temperature-entropy diagram of FIG. 8 can be chosen as a
starting point. Certain conditions will exist in the engine at any
one of the four points of the diagram. For example, consider the
condition of an increasing environment temperature when the
hydrogen gas that is used in the engine is predominantly contained
in the high-pressure chamber. The temperature transient of the
high-pressure hydrogen terminates at point "1" on the diagram. As
previously discussed herein, the metal-hydride materials are
chosen such that at any given temperature, the midpoint
equilibrium pressure in the high-pressure chamber 22, 62, 102, 162
will be greater than the midpoint equilibrium pressure in the
low-pressure chamber 24, 64, 104, 164. As the ambient temperature
increases, the equilibrium pressures of both metal-hydride beds
42/44, 82/84, 122/124, 182/184 of each engine 10, 12, 14, 16
respectively increase.  
  
[0057] Phase 1-2: The portion of the cycle of FIG. 8 from point 1
to point 2 represents, the expansion of hydrogen from the
high-pressure chamber 22, 62, 102, 162 and passage of the hydrogen
from the high-pressure chamber to the low-pressure chamber 44, 64,
104, 164. Electrical energy is generated during this portion of
the cycle. Several things occur simultaneously, in Phase 1-2. Heat
is absorbed in the high-pressure chamber as hydrogen is released
and heat is released by the low-pressure chamber as the metal
hydride contained therein absorbs hydrogen. The engine may be
configured to facilitate heat transfer between the two chambers so
as to minimize the amount of heat that must be extracted from or
transferred to the environment. However, the overall effect of
expansion of hydrogen from the high-pressure bed to the
low-pressure bed is endothermic due to the net decrease in energy
state of the hydrogen and heat is absorbed by the engine from the
elevated temperature ambient environment. The transition of the
hydrogen from state 1 to state 2 is associated with the closing of
a circuit that includes the ionically-conductive membrane and the
electrical-energy storage device. With closing of the circuit
hydrogen ions H<+> are conducted across the membrane and
electrons freed from the hydrogen flow through the circuit into
the electrical-energy storage device. During Phase 1-2, hydrogen
(that has been reconstituted from migrated hydrogen ions H+ and
received electrons) is received in the opposing low-pressure
chamber 24, 64, 104, 164 where it is ready to be absorbed into the
associated metal-hydride beds 44, 84, 124, 184.  
  
[0058] Phase 2-3: With the hydrogen now substantially contained by
the low-pressure metal-hydride chamber 24, 64, 104, 164, the
portion of the cycle of FIG. 8 from point 2 to point 3 represents
a decreasing temperature transient (which may be a succession of
decreasing temperature transients) associated with the engine's
environment. Note that at point 2, the temperature of each
metal-hydride bed has been substantially stabilized to the high
temperature (THT) of the ambient environment. Between points 2 and
3, as ambient environment temperature decreases, heat is
transferred through the housing 20, 60, 100, 160 of the engine 10,
12, 14, 16 to what is now a low-temperature ambient environment
(QLT, QE) causing both the temperature and the equilibrium
pressures of the metal-hydride beds 42/44, 82/84, 122/124, 182/184
of each engine 10, 12, 14, 16 respectively to decrease. Phase 2-3
may be considered to be carried out under the constant volume of
the low-pressure chamber 24, 64, 104, 164.  
  
[0059] At point 3, the predominance of hydrogen in the engine
system is in the low-pressure chamber 24, 64, 104, 164 and in
equilibrium with the low-temperature point of the ambient
environment, TLT.  
  
[0060] Phase 3-4: During this phase of the cycle of FIG. 8
represented by point 3 to point 4, the high-pressure chamber 22,
62, 102, 162 of the engine system is "recharged" with hydrogen.
The electrical-energy storage device is energized to complete a
circuit (that includes the MEA 30, 70, 116, 170) and thereby cause
hydrogen (H2) to be conducted through the MEA as hydrogen ions
(H<+>) from low-pressure chambers 24, 64, 104, 164 to
high-pressure chambers 22, 62, 102, 162 respectively. The MEA
performs a pumping process to recompress the hydrogen. At point 4
of the diagram of FIG. 8, hydrogen predominantly has been
aggregated in the high-pressure chamber under some pressure.
Electrical energy is consumed during this portion of the cycle.
Heat is absorbed in the low-pressure chamber as hydrogen is
released and heat is released by the high-pressure chamber as the
metal hydride contained therein absorbs hydrogen. The overall
effect of compression of hydrogen from the low-pressure bed to the
high-pressure bed is exothermic due to the net increase in energy
state of the hydrogen and heat is released by the engine to the
now lower temperature ambient environment.  
  
[0061] Phase 4-1: The portion of the cycle of FIG. 8 from point 4
to point 1 represents an increasing temperature transient (which
may include a succession of lesser increasing temperature
transients). Note that at point 4 hydrogen has been aggregated in
the high-pressure chamber 22, 62, 102, 162. As ambient environment
temperature increases, heat is transferred through the housing 20,
60, 100, 160 of the engine 10, 12, 14, 16 causing both the
temperature and equilibrium pressures of the metal-hydride beds to
increase, with the high-pressure bed maintaining a higher
equilibrium pressure than that of the low pressure bed.  
  
Additional Features of the
Invention  
  
[0062] In a broad embodiment, the invention is practiced without
first and second hydrogen-storage mediums, and more particularly,
without metal-hydride materials. In this embodiment, at least a
first portion of the hydrogen that is placed in the housing is
initially placed in the high-pressure chamber at a higher pressure
than a second quantity of hydrogen that is initially placed in the
low-pressure chamber. The invention still operates by the
previously-described mechanism of selecting between a charge
condition and a discharge condition. The addition of
hydrogen-storage mediums such as metal hydrides increases the
amount of hydrogen that can be stored at a given pressure in a
given volume and therefore the amount of electronic charge that
can be produced.  
  
[0063] A capacitor may be used instead of a battery as an
electrical-energy-storage device that can be successively charged
and discharged.  
  
[0064] Each electrode may include a porous current collector to
help facilitate the flow of hydrogen and hydrogen ions while still
conducting a flow of electrons.  
  
[0065] Each electrode may include a catalyst such as platinum to
help facilitate the hydrogen reaction at each respective
electrode.  
  
[0066] Many variations and modifications may be made to the
above-described embodiments without departing from the scope of
the claims. All such modifications, combinations, and variations
are included herein by the scope of this disclosure and the
following claims.  
  


---

  

Electrochemical conversion system for energy
management    
US7943250

  
REFERENCE TO RELATED APPLICATION  
  
This is a continuation-in-part of U.S. Patent Application Ser. No.
60/569,890 filed May 11, 2004. This is also a continuation-in-part
of U.S. patent application Ser. No. 10/425,067, filed Apr. 28,
2003, now U.S. Pat. No. 7,160,639 which is a continuation-in-part
of U.S. patent application Ser. No. 09/627,721, filed Jul. 28,
2000 now abandoned.  
  
TECHNICAL FIELD  
  
This invention relates to the conversion of heat energy to
electrical energy or electrical energy to heat energy utilizing
multiple electrochemical cells.  
  
BACKGROUND OF THE INVENTION  
  
The conversion of heat energy or chemical energy to electrical
energy, or visa-versa, may be accomplished in a variety of ways.
It is known that electrochemical cells or batteries rely on redox
reactions wherein electrons from a reactant being oxidized are
transferred to a reactant being reduced. With the separation of
the reactants from each other, it is possible to cause the
electrons to flow through an external circuit where they can be
used to perform work.  
  
Electrochemical cells however have had a problem of exhausting the
reactants. Although cells can be designed to be recharged by
applying a reverse polarity voltage across the electrodes, such
recharging requires a separate electrical source. During the
recharging of the cell the cell typically is not usable.  
Fuel cells have been developed in an effort to overcome problems
associated with electrochemical cells. Typically, fuel cells
operate by passing an ionized species across a selective
electrolyte which blocks the passage of the non-ionized species.
By placing porous electrodes on either side of the electrolyte, a
current may be induced in an external circuit connecting the
electrodes. The most common type of fuel cell is a hydrogen-oxygen
fuel cell which passes hydrogen through one of the electrodes
while oxygen is passed through the other electrode. The hydrogen
and oxygen combine at the electrolyte-electrode interface to
produce water. By continuously removing the water, a concentration
gradient is maintained to induce the flow of hydrogen and oxygen
to the cell.  
These types of fuel cells however suffer from a number of
disadvantages. These cells must be continuously supplied with a
reactant in order to produce electricity continuously.
Additionally, these cells produce a continuous product stream
which must be removed, the removal of which may pose a problem.
The porous electrodes of these fuel cells must allow the passage
of the reactant entering the cell. However, over time these porous
electrodes can become fouled or plugged so as to slow or even
prevent the passage of the reactant. Such slowing of the reactant
flow reduces the production of electricity. Lastly, the selection
of an appropriate electrolyte is not always easy. The electrolyte
must rapidly transport the ionized species in order to increase
the current production. Frequently, the limited migration of the
ionized species through the electrolyte is a limiting factor on
the amount of current produced.  
  
In an effort to avoid the problems inherent with the previously
described fuel cells, thermoelectric conversion cells have been
designed. These thermoelectric conversion cells utilize heat to
produce a pressure gradient to induce the flow of a reactant, such
as molten sodium, across a solid electrolyte. A current is
generated as sodium atoms lose electrons upon entering the
electrolyte and gain electrons upon leaving the electrolyte. These
cells however also suffer from the plugging of the porous
electrodes required to pass the sodium ions. Furthermore, the
diffusion of the sodium ions through the solid electrolytes has
proven to be slow, thereby limiting the amount of current produced
by the cell. These cells also utilize alkali metals which is
difficult to use in these types of applications because of they
are highly corrosive. Lastly, these types of fuel cells operate at
extremely high temperatures, typically in a range between
1,200-1,500 degrees Kelvin, thus making them impractical for many
uses.  
  
Accordingly, it is seen that a need remains for an electrochemical
conversion system that does not require a continuous source of
reactant, which does not require an electrolyte which may be
plugged over time and which may be operated at relatively low
temperatures. It is the provision of such therefore that the
present invention is primarily directed.  
  
SUMMARY OF THE INVENTION  
  
In a preferred form of the invention an electrochemical conversion
system for managing energy comprises a first electrochemical cell
having a first ion conductive material, a first electrode mounted
upon one side of the first ion conductive material, and a second
electrode mounted upon one side of the first ion conductive
material opposite the first electrode, a second electrochemical
cell having a second ion conductive material, a third electrode
mounted upon one side of the second ion conductive material, and a
fourth electrode mounted upon one side of the second ion
conductive material opposite the third electrode, and a third
electrochemical cell having a third ion conductive material, a
fifth electrode mounted upon one side of the third ion conductive
material, and a sixth electrode mounted upon one side of the third
ion conductive material opposite the fifth electrode. The system
also includes a conduit system having a first conduit, second
conduit and third conduit. The first conduit is in fluid
communication with the first electrochemical cell second electrode
and the second electrochemical cell third electrode. The second
conduit is in fluid communication with the second electrochemical
cell fourth electrode and the third electrochemical cell fifth
electrode. The third conduit is in fluid communication with the
third electrochemical cell sixth electrode and the first
electrochemical cell first electrode. The system also includes a
first heat exchanger for exchanging heat between the first conduit
adjacent the first electrochemical cell and the third conduit
adjacent the first electrochemical cell, and a second heat
exchanger for exchanging heat between the first conduit adjacent
the second electrochemical cell and the second conduit adjacent
the second electrochemical cell. A supply of ionizable gas is
contained within the conduit system and an electrical circuit
coupled to the first electrode, the second electrode, the third
electrode, the fourth electrode, the fifth electrode and the sixth
electrode. The electrical circuit includes an electrical energy
storage device.  
  
BRIEF DESCRIPTION OF THE DRAWING  
  
FIG. 1 is a schematic view of a
reversible heat engine in a preferred form of the invention,
shown in a heat engine configuration.  
  

![](us794-1.jpg)

  
FIG. 2 is a theoretical,
temperature entropy diagram of the reversible heat engine of
FIG. 1.  
  

![](us794-2.jpg)

  
FIG. 3 is a schematic view of a
reversible heat engine in a preferred form of the invention,
shown in a heat pump configuration.  
  
FIG. 4 is a temperature entropy
diagram of the reversible heat engine of FIG. 3.  
  
FIG. 5 is a schematic view of an
electrochemical conversion system for energy management in a
preferred form of the invention.  
  

![](us794-3.jpg)

  
FIG. 6 is a temperature entropy
diagram of the reversible heat engine of FIG. 5.  
  
  
  
FIG. 7 is a schematic view of
another electrochemical conversion system for energy management
in a preferred form of the invention.  
  

![](us794-4.jpg)

  
DETAILED DESCRIPTION  
  
With reference next to the drawings, there is shown in FIG. 1 a
reversible engine 10 in a preferred form of the invention of a
heat engine. The engine 10 has a conduit system 11, a first
electrochemical cells 12, and a second electrochemical cell 13.
The conduit system 11 is made of a non-reactive material such as
stainless steel. The conduit system 11 includes a first conduit 15
extending from the first electrochemical cell 12 to the second
electrochemical cell 13, and a second conduit 16 extending from
the second electrochemical cell 13 to the first electrochemical
cell 12.  
  
The heat engine 10 also includes a heater 18 mounted in thermal
communication with the conduit system 11 adjacent the second
electrochemical cell 13, a cooler 19 mounted in thermal
communication with the conduit system 11 adjacent the first
electrochemical cell 12, and a heat regenerator or exchanger 20
thermally coupled to the first and second conduits 15 and 16 for
the transfer of heat therebetween.  
  
The first electrochemical cell 12 has a first gas diffusion
electrode 22, a second gas diffusion electrode 23 and a first
proton conductive membrane 24, such as Nafion made by E.I. du Pont
de Nemours, mounted between the first and second gas diffusion
electrodes 22 and 23. This type of electrochemical cell is
available from E-Tek, Inc. of Somerset, N.J. The electrochemical
cell electrodes 22 and 23 are electrically coupled to an external
power supply 25.  
Similarly, the second electrochemical cell 13 has a third gas
diffusion electrode 28, a fourth gas diffusion electrode 29 and a
second proton conductive membrane 30 mounted between the third and
fourth gas diffusion electrodes 28 and 29. The electrochemical
cell electrodes 28 and 29 are electrically coupled to an external
load 31.  
  
In use, the conduit system 11 is filled with an ionizable gas,
such as hydrogen, oxygen or sodium hereinafter referred to simply
as hydrogen H. With the operation of the heater 18 (QH) to
transfer heat energy to the second electrochemical cell 13, or
adjacent thereto, to maintain a constant temperature of the
hydrogen gas ionized and passed therethrough, the operation of
cooler 19 (QL) to transfer heat energy from, or from adjacent
thereto, the first electrochemical cell 12, and the operation of
the heat exchanger 20 to transfer heat energy from the hydrogen
gas within the second conduit 16 to the hydrogen gas within the
first conduit 15, and the passage of an electric current from the
external power supply 25 to the first electrochemical cell 12,
hydrogen gas H passes through the first electrochemical cell 12.
The hydrogen gas H passes through the first electrochemical cell
12 as a result of the electric potential from the external power
supply 25 between the first electrode 22 and the second electrode
23. The electric potential causes the hydrogen gas at the first
electrode 22 to oxidize into hydrogen protons. The oxidation of
the hydrogen gas causes the release of electrons which are passed
to the second electrode 23. The hydrogen protons are drawn through
the first proton conductive membrane 24 to the second electrode 23
by the negative charge at the second electrode 23. At the second
electrode 23 the hydrogen protons are reduced into hydrogen gas.
As such, the electric current through the first electrochemical
cell 12 forces the passage of hydrogen gas from the second conduit
16 to the first conduit 15, thereby increasing the hydrogen gas
pressure within the first conduit 15 while decreasing the hydrogen
gas pressure within the second conduit 16, i.e., creating a
hydrogen gas pressure differential between the second conduit 16
and the first conduit 15.  
  
The passage of hydrogen gas H from the second conduit 16 to the
first conduit 15 causes a pressure differential across the second
electrochemical cell 13. As the hydrogen pressure differential
between the first and second conduits 15 and 16 increases an
electrical potential across the second electrochemical cell 13 is
created and progressively increased. Hydrogen gas H at the higher
pressure first conduit 15 adjacent the second electrochemical cell
third electrode 28 is oxidized into hydrogen protons. These
hydrogen protons are forced by the hydrogen pressure differential
through the second proton conductive membrane 30 to the fourth
electrode 29 at the lower pressure second conduit 16. At the
fourth electrode 29 the hydrogen protons are reduced into hydrogen
gas. As such, the oxidation of the hydrogen gas causes the release
of electrons which are passed to the third electrode 28 while the
reduction of protons into hydrogen gas causes the acceptance or
receiving of electrons from the fourth electrode 29, thereby
inducing an electric current through load 31 coupled to the second
electrochemical cell 13.  
  
The passage of hydrogen gas through the first and second
electrochemical cells 12 and 13 creates a fluid stream or flow
through the conduit system 11 as illustrated by the direction
arrows in the drawings. The flow of hydrogen gas through the first
conduit 15 from adjacent the first electrochemical cell 12 to
adjacent the second electrochemical cell 13 is done so under
constant pressure while the temperature of the gas increases.
Similarly, the flow of hydrogen gas through the second conduit 16
from adjacent the second electrochemical cell 13 to adjacent the
first electrochemical cell 12 is done so under constant pressure
while the temperature decreases.  
  
It should be understood that it takes less work to transfer the
hydrogen gas across the first electrochemical cell from the low
pressure region to the high pressure region at a low temperature
than the work required to transfer the hydrogen gas across the
second electrochemical cell from the high pressure region to the
low pressure region at a high temperature. As such, the work input
at the first electrochemical cell is less than the work output at
the second electrochemical cell, with the additional work output
energy being obtained from the conversion of the heat energy input
(QH). The transfer of heat through the heat exchanger 20 aids in
maintaining a temperature differential between the regions of the
conduit system surrounding the two electrochemical cells 12 and 13
and thereby aid in maintaining a constant pressure during the
process, and in improving the efficiency by conserving the heat
energy within the system by transferring it from the high
temperature gas leaving the high temperature region adjacent the
second electrochemical cell to the lower temperature gas flowing
to the first electrochemical cell.  
  
The entropy diagram shown in FIG. 2 illustrates the theoretical
change in entropy of the just described system during its
operation in an ideal or perfect situation wherein the heat
exchange is ideal or 100 percent efficient, i.e., wherein outside
influences on the system are not considered. Obviously, the true
entropy diagram of the system will be different once these outside
influences are taken into consideration.  
  
The system may also be operated in a reverse cycle as a heat pump,
as shown in FIGS. 3 and 4. Here, the second electrochemical cell
13 is coupled to an external power supply 25 while the first
electrochemical cell 12 is coupled to an external load 31. Also,
the region adjacent the first electrochemical cell 12 is provided
with heat energy (QL) by while heat energy is extracted (QH) from
the region adjacent the second electrochemical cell 13. The
operation of the device in this configuration is the extraction of
heat energy (QL) from a low temperature source and supply it as
heat energy (QH) to a higher temperature source, as illustrated in
FIG. 3. The principles of the invention however remain the same as
those previously described, with the system here providing a
change in the heat energy.  
  
The system may be operated at relatively small temperatures
differences. As such, this system is both safe and manageable.
Furthermore, this system converts energy without any mechanically
moving parts, and as such is practically free of mechanical
failure.  
  
It should be understood that the previously described systems may
utilize any form of heat source such as electric heaters, gas
burning heaters, heated air, radiation heat sources, radiant
heaters or other conventionally known means of producing heat. The
system may also utilize any form of cooling means such as cooling
water jackets, heat sinks, cooling radiators, heat dissipaters or
another other conventionally known means of removing heat.  
  
With reference next to FIG. 5, there is shown an electrochemical
conversion system 40 for energy management which includes
multi-node (three or more stacks) or electrochemical cells. The
three-node system 40 (a thermally driven heat pump) is described
in detail to provide a stepping-stone for multi-node (>3 nodes)
operation. Principles for the thermally driven heat pump apply
equally to all multi-node electrochemical conversion systems.  
  
The system 40 is an innovative, solid-state heat engine which can
operate on any thermal source, such as combustible fuels,
concentrated solar energy, waste heat, or geothermal. In addition
to power generation, the electrochemical conversion systems can be
configured as a heat pump or as a combination heat pump/heat
engine to provide thermal management for heating, cooling and
electrical energy. Operating on the Ericsson cycle and using
hydrogen as a working fluid, the electrochemical conversion system
can efficiently transport heat to or from a desired location to
effectively maintain a desired elevated or reduced temperature.
The Ericsson cycle is Carnot equivalent, and therefore, offers the
maximum theoretical efficiency available from an engine operating
between two temperatures. The electrochemical conversion system
uses electrochemical cells, also referred to as Membrane Electrode
Assemblies (MEA), similar to those used in fuel cells; however, it
does not require oxygen or a fuel supply, only heat.  
  
The three-node system 40 is a thermally driven heat pump and is
shown in FIG. 5 along with a Temperature-entropy (T-s) diagram of
the cycle shown in FIG. 6. The thermodynamic states on the T-s
diagram correspond to the same locations in the thermally driven
heat pump schematic.  
  
The system 40 includes a conduit system 41, an electrical system
42, first electrochemical cell 43, a second electrochemical cell
44, a third electrochemical cell 45, a first recuperative heat
exchanger (RHX) 46, and a second recuperative heat exchanger 47.
The conduit system 41, electrical system 42, heat exchangers, and
electrochemical cells are all constructed and function in the same
manner as previously described.  
  
This version of the system 40 includes an additional, second
recuperative heat exchanger 47 (RHX) (the two node system of FIGS.
1 and 3 include a single RHX) to thermally isolate the third
electrochemical cell 45 or node from the other two, and an
interface with the ambient environment for heat exchange (labeled
as QC at temperature TA), a high temperature interface for heat
exchange (labeled as Qs, at temperature TH>TA), and an
interface to the refrigerated space for heat exchange (labeled as
QR at TR<TA). As shown, the electrochemical cells 43, 44 and 45
are electrically and pneumatically connected in series so that the
electrical current flow and the proton flow through the
electrochemical cells are balanced.  
  
Beginning at high temperature intermediate pressure state 1,
electrical energy EO is generated at the high temperature MEA as
hydrogen expands from state 1 to high temperature low-pressure
state 2. The temperature of the hydrogen is maintained nearly
constant by supplying heat QS from the source during the expansion
process. The thin membrane (less than 10 [mu]m thick) within the
electrochemical cell will not support a significant temperature
gradient, so the near isothermal assumption for the process is
valid, provided adequate heat is transferred from the membrane
through its substrate. From state 2 to state 3, the hydrogen
passes through the first recuperative heat exchanger (RHX) 46
under approximately constant pressure and is cooled by
transferring heat to hydrogen flowing in the opposite direction to
ambient temperature. From ambient temperature, low-pressure state
3, electrical energy (labeled as EC) is consumed as hydrogen is
compressed nearly isothermally across the ambient temperature,
third electrochemical cell 45 to high pressure, ambient
temperature state 4. Heat QC generated during the compression
process is rejected to the ambient environment to maintain the
isothermal process. From ambient temperature, high-pressure state
4 the hydrogen passes through the second recuperative heat
exchanger to low temperature, high-pressure state 5. The hydrogen
flowing from state 4 to 5 is cooled by transferring heat to the
hydrogen flowing in the opposite direction through the second
recuperative heat exchanger flowing from the low temperature,
first electrochemical cell 43 (state 6 to 7). Refrigeration is
accomplished at the low temperature, first electrochemical cell 43
by extracting heat QR from the low temperature environment as
hydrogen expands from low temperature, high-pressure state 5 to
low temperature, low-pressure state 6 thereby generating energy
ER. From state 6 to state 7, hydrogen flows through the second
recuperative heat exchanger 47 wherein its temperature is
increased by heat transfer from the hydrogen passing from state 4
to 5. The hydrogen continues through the first recuperative heat
exchanger 46, where it is heated by hydrogen leaving the high
temperature, second electrochemical cell 44 to return to high
temperature, high-pressure state 1 completing the cycle.  
  
With reference next to FIG. 7, there is shown a four-node
electrochemical conversion system 60 in another preferred form of
the invention. It should be noted that the electrochemical
convention system of the present invention can be configured with
N total nodes, where M (which must be less than N) of the nodes
are connected to sources or sinks at non-ambient temperatures and
at least one node interfaces with the ambient environment to
satisfy thermodynamic requirements for a heat engine. The
multi-node system can be designed for nearly any thermal
management issues, and overall operation will of course depend on
the number of nodes and the amount of heat available.  
  
The four node system 60, is similar to the three-node system of
FIGS. 5 and 6 except for the addition of a fourth electrochemical
cell, the details of which will follow, and a third recuperative
heat exchanger 63. Here, the system 60 includes a high temperature
power generation electrochemical cell 64, a waste heat power
generation electrochemical cell 65, a heat pump electrochemical
cell 66, and an ambient interface electrochemical cell 67.
Electrochemical cell 64 may operate on combustion or some other
high quality heat source (concentrated solar, high quality waste
heat, etc.), while electrochemical cell 65 may operate on a lower
quality waste heat source, e.g. electronics. Electrochemical cell
66 can be used to provide space heating, while the electrochemical
cell 67 rejects heat to the ambient as required for a heat engine
or heat pump. All nodes or electrochemical cells do not need to
operate simultaneously or at the same voltage and current, which
is why the schematic shows a control processor and load leveling
battery. The control processor ensures that proper voltages and
currents are maintained at proper values, while the load leveling
battery is used (as the name implies) to level the system loads
for any combination of operating electrochemical cells.  
  
It thus is seen that an electrochemical conversion system for heat
management is now provided which is efficient. It should of course
be understood that many modifications, in addition to those
specifically recited herein, may be made to the specific
embodiments described herein without departure from the spirit and
scope of the invention as set forth in the following claims.  
  


---