Alexander Kalina Steam Cycle --- Part 1

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**[rexresearch.com](../index.htm)**

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**Alexander KALINA**

**Steam Cycle ( I )**

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**( I )**

**[Robert Frenay: "Power Surge"](#frenay)**
  
**[Claudia Chandler: "Kalina
Cycle Goes Commercial"](#chandler)**   
**[Alexander Kalina: US Patent # 4,346,561 ~Generation of Energy by Means of a Working
Fluid...](#4346)**   
**[Alexander Kalina: US Patent # 4,489,563 ~
Generation of Energy](#4489)**

**[Alexander Kalina: US Patent #
4,548,043 ~ Method of Generating Energy](#4548)**   
**[Alexander Kalina: US Patent # 4,586,340 ~
Implementing a Thermodynamic Cycle using a Fluid of Changing
Concentration](#4586)**

**( II )**   
**[A. Kalina: USP # 4,604,867 ~
Implementing a Thermodynamic Cycle with Intercooling](kalina2.htm)**
  
**[A. Kalina: USP #
4,732,005 ~ Direct Fired Power Cycle](kalina2.htm)**   
**[A. Kalina: USP # 4,763,480
~
Implementing
a Thermodynamic Cycle with Recuperative Preheating](kalina2.htm)**
  
**[A. Kalina: USP # 4,899,545 ~
Thermodynamic Cycle](kalina2.htm)**   
**[A. Kalina: USP # 4,982,568 ~ Converting
Heat from Geothermal Fluid to Electric Power](kalina2.htm)**   
**[A. Kalina: USP # 5,029,444
~
Converting
Low Temperature Heat to Electric Power](kalina2.htm)**   
**[A. Kalina: USP # 5,095,708 ~ Converting
Thermal Energy into Electric Power](kalina2.htm)**   
**[A. Kalina: USP # 5,440,882 ~ Converting Heat from Geothermal Liquid and
Geothermal Steam to Electric Power](kalina2.htm)**   
**[A. Kalina: USP # 5,450,821 ~ Multi-Stage Combustion System for Externally
Fired Power Plants](kalina2.htm)**   
**[A. Kalina: USP #
5,572,871 ~ Conversion of Thermal Energy into Mechanical
and Electrical Power](kalina2.htm)**   
**[A. Kalina: USP #
5,588,298 ~ Supplying Heat to an Externally Fired Power
System](kalina2.htm)**   
**[A. Kalina & Richard
Pelletier: USP # 5,649,426 ~ Implementing a Thermodynamic Cycle](kalina2.htm)**
  
**[A. Kalina & Lawrence Rhodes:USP # 5,822,990 ~ Converting Heat into Useful
Energy Using Separate Closed Loops](kalina2.htm)**   
**[A. Kalina: USP # 5,950,443
~
Method
and System of Converting Thermal Energy into a Useful Form](kalina2.htm)**
  
**[A. Kalina & R. Pelletier ~ USP # 5,953,918 ~ Method and Apparatus of Converting
Heat to Useful Energy](kalina2.htm)**

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**Power Surge**

**by Robert Frenay**

Seventeen years ago, Russian emigre Alexander Kalina arrived in
Houston, Texas, with $5.36 in his pocket and a plan. That plan
has now borne fruit in a process that will considerably reduce
global fuel consumption by improving the efficiency of
steam-driven power plants, which produce more than two-thirds of
the world's energy. If U.S. plants had the new technology, they
could save $6 billion a year, according to a Department of
Energy (DOE) study.

Kalina's invention has drawn the attention of prominent
investors and is now licensed to such major manufacturers of
power-plant equipment as General Electric, ABB, Europe's Ansaldo
Energia, and Japan's Ebara Corporation.

The steam power plant now used to make electricity was invented
150 years ago by Scottish engineer William Rankine. It uses a
heat source-coal, oil, natural gas, geothermal heat-to produce
high-pressure steam that drives a turbine. The excess steam is
condensed into water, which is then pumped back to a boiler. In
a Rankine cycle only about 35 to 40 percent of the heat energy
released ever becomes electricity. That means that of the $40
billion spent each year in the United States to fuel steam power
plants, nearly $25 billion is lost. And that figure is matched
in excess pollution and excess depletion of resources.

Mixing the water with ammonia --- which evaporates at lower
temperatures --- can raise efficiency at the heat stage of the
cycle. But ammonia also condenses less readily, forcing
engineers to use smaller turbines and lowering efficiency.
Kalinas' invention solves that problem, using sophisticated
thermodynamics to draw off most of the ammonia before the
condensation stage. Engineers traditionally strain for
productivity gains of 1 percent; a Kalina cycle can boost
efficiency by as much as 40 percent.

In 1991 the first Kalina power plan went online at an
experimental site run by the DOE in Canoga Park, California.
Built with funds from Australian scientist and inventor Ronald
Wise, it can supply enough power for more than 1,000 houses.
Stephan Schmidheiny, a principal of the Swatch watch company,
and well-known speculator George Soros have each purchased 20
percent shares in Kalina's Exergy Corporation. In 1994 the DOE
awarded Exergy a $7 million grant for a geothermal plant in
Steamboat, Nevada, on which construction will begin later this
year. Once it's operational, the DOE will compare its
performance with that of two Rankine geothermal plants now in
operation there.

---

**<http://www.energy.ca.gov/releases/1997_releases/97-06-05_kalina.html>**

**Kalina Cycle Goes Commercial; Energy
Commission Accepts First Royalty Payment**

**Claudia Chandler**

The Kalina Cycle, a Russian emigre's dream of making thermal
power plants up to 50 percent more efficient, is on the road to
commercial reality. And the company that developed the
technology, has begun paying back the California Energy
Commission royalties on the state's investment. Exergy Inc. of
Hayward has made the first royalty payment of $250,000 to the
Commission for funding the innovation during its infancy.

"Technologies such as this offer win-win opportunities for
California energy producers, consumers and taxpayers," said
Governor Pete Wilson. "Not only has the state supported advances
in energy efficiency, but California is reaping a share of its
commercial success."

The technology is the creation of Dr. Alexander Kalina, who
left a high position in the Soviet Union 18 years ago to come to
the United States to develop this advanced thermodynamic cycle.
He formed Exergy Inc. to commercialize the technology.

The technology uses a mix of water and ammonia rather than
water alone to supply the heat recovery system for electricity
generation in a power plant. Because ammonia has a much lower
boiling point than water, the Kalina cycle is able to begin
spinning the steam turbine at much lower temperatures than
typically associated with the conventional steam boiler/turbine
systems. Similarly, the lower boiling point of ammonia allows
additional energy to be obtained on the condenser side of the
steam turbine.

Under its Energy Technologies Advancement Program (ETAP) the
Energy Commission awarded the project $2.25 million to co-fund a
pilot plant in Canoga Park. Under the terms of a royalty
agreement, Exergy will pay back total royalties of $6.75 million
over a period of time based on its gross revenues. The Energy
Commission plows back the royalty funds into ETAP to fund future
projects, thus providing a mechanism for a successful project to
fund other ETAP projects.

The Canoga Park plant at the U.S. Department of Energy's
Engineering Center, has a capacity of six megawatts. It has sold
power to the Rocketdyne Division of Rockwell International and
Southern California Edison since 1992.

In 1993, General Electric signed an agreement with Exergy for a
worldwide exclusive licensing rights to use the technology for
combined-cycle systems in the 50 to 150 megawatt range. GE and
Exergy are proposing a 110 megawatt combined-cycle project in
Livingston, California that will operate at 55 percent
efficiency. In addition, GE and Exergy currently have on the
drawing board a combined-cycle plant that will operate on an
overall efficiency above 62 percent.

Exergy has also signed agreements with Ansaldo Energia of
Italy, ABB and Ebara Corporation of Japan for use of the Kalina
cycle technology in geotheral, waste incineration and
direct-fired coal applications.

The Governor, noting the company's successful ventures abroad
said: "Exports of environmentally-friendly energy technology
sharpen California's competitive edge in global markets,
harnessing the international trade and investment that have been
so critical to the California comeback."

The Kalina cycle can be used with any fuel, geotheral source or
excess energy. Exergy predicts that with the Kalina technology,
geotheral plants can post an efficiency gain of up to 50 percent
while coal-fired plants will operate 20 percent more efficiently
with the technology.

Through ETAP, the Energy Commission assists California energy
research and development companies make energy technologies more
efficient or cost-effective, and to help develop alternative
sources of energy.

ETAP leverages funds from private companies toward each
project. Since its establishment by the Rosenthal-Naylor Act in
1984, the program has funded 68 projects totalling more than
$23.4 million, with project sponsors providing more than $175
million in matching funds. The projects provide research,
development and manufacturing jobs and tax revenues to state and
local governments.

The Kalina cycle was one of the first projects funded by ETAP,
the first to sign a royalty agreement and the first to pay
royalties to the Commission.

---

**US Patent  # 4,346,561**   
( August 31, 1982 )

**Generation of Energy by Means of a Working
Fluid, and Regeneration of a Working Fluid**

**Alexander Kalina**

**Abstract ---** A method of optimizing, within
limits imposed by a heating medium from the surface of an ocean
and a cooling medium from an ocean depth, the energy supply
capability of a gaseous working fluid which is expanded from a
charged high pressure level to a spent low pressure level to
provide available energy, the method comprising expanding the
gaseous working fluid to a spent low pressure level where the
condensation temperature of the working fluid is below the minimum
temperature of the cold water, and regenerating the spent working
fluid by, in at least one regeneration stage, absorbing the
working fluid being regenerated in an absorption stage by
dissolving it in a solvent solution while cooling with the cold
water, the solvent solution comprising a solvent having an initial
working fluid concentration which is sufficient to provide a
solution having a boiling point, after dissolving the working
fluid being regenerated, which is above the minimum temperature of
the cold water to permit effective absorption of the working fluid
being regenerated, increasing the pressure and then evaporating
the working fluid being regenerated by heating in an evaporation
stage with the available hot water, feeding the evaporated working
fluid and the solvent solution to a separator stage for separating
the evaporated working fluid and the solvent solution, recovering
the evaporated, separated working fluid, and recycling the balance
of the solvent solution from the separator stage to constitute the
solvent solution for the absorption stage; and an apparatus for
carrying out the method.

Current U.S. Class: 60/673; 95/179; 95/232; 95/237   
Intern'l Class:  F01K 025/10   
Field of Search:  60/641.6,641.7,649,673 55/70,89,93

**References Cited**   
U.S. Patent Documents   
# 427,401 ~ May., 1890 ~ Campbell 60/673.   
# 3,783,613 ~ Jan., 1974 ~ Billings et al. 60/38.   
# 4,009,575 ~ Mar., 1977 ~ Hartman, Jr. 60/673.   
# 4,037,415 ~ Jul., 1977 ~ Christopher 60/673.   
# 4,101,297 ~ Jul., 1978 ~ Uda 55/89.   
# 4,297,332 ~ Oct., 1981 ~ Tatani 55/89.   
Foreign Patent Documents   
# 294,882 ~ Sep., 1929 ~ GB.   
# 352,492 ~ Jul., 1931 ~ GB.   
# 786,011 ~ Nov., 1957 ~ GB.   
# 872,874 ~ Jul., 1961 ~ GB.   
# 1,085,116 ~ Sep., 1967 ~ GB.

**Description**

This invention relates to the generation of energy by
means of a working fluid, and to the regeneration of a working
fluid. More particularly, this invention relates to a method of
and to apparatus for generating energy by means of a working fluid
and for regenerating such a working fluid. In the generation of
energy by expansion of a working fluid, the energy which can be
produced by expansion of the working fluid is limited by the
temperatures at which heating and cooling mediums can economically
be provided for regeneration of the working fluid. The result is,
therefore, that such a working fluid is expanded from a high
pressure charged level to a low pressure spent level, with the
high pressure charged level being governed by the maximum pressure
at which the working fluid can be evaporated with the available
heating medium, and with the spent low pressure level being
governed by the minimum pressure at which the working fluid can be
condensed with the available cooling medium. In practice,
therefore, expansion of the working fluid is controlled to provide
a spent low pressure level at which the condensation temperature
of the working fluid is greater than the temperature of the
cooling medium, to permit condensation of the working fluid. In
addition, in practice, regeneration is based on condensation of
working fluid in a condenser wherein the working fluid is arranged
to flow in heat exchange relationship with an available cooling
medium. Because of the desire to achieve maximum expansion of the
working fluid, regeneration of working fluid is often effected
where the temperature difference between the condensation
temperature of the spent working fluid at the spent level and the
temperature of the available cooling medium is marginal --- often
as low as 1.degree. C. This of necessity imposes a requirement for
a large condenser with an extensive heat exchange surface, and for
a large supply of cooling medium, thereby substantially adding to
the operating costs. This is particularly significant where severe
restraints are imposed by the temperatures of available heating
and cooling mediums as in the case of ocean thermal energy
conversion systems. In accordance with one aspect of this
invention, there is provided a method of generating energy, which
comprises expanding a gaseous working fluid from a charged high
pressure level to a spent low pressure level to release energy,
and regenerating the spent working fluid by, in a plurality of
successive regeneration stages: (a) condensing the working fluid
in an absorption stage by dissolving it in a solvent solution
while cooling with a cooling medium, the solvent solution
comprising a solvent having an initial working fluid concentration
which is sufficient to provide a solvent solution boiling range
suitable for absorption of the working fluid;

(b) increasing the pressure of the solvent solution containing
the dissolved working fluid, and evaporating the working fluid
being regenerated by heating in an evaporation stage;

(c) feeding the evaporated working fluid to a succeeding
regeneration stage;

(d) recycling the balance of the solvent solution remaining
after evaporation of the working fluid, to constitute the
solvent solution for the absorption stage of that regeneration
stage; and

(e) withdrawing regenerated charged working fluid from a final
regeneration stage for re-expansion to release energy;

The working fluid may be expanded to a spent low pressure level
where the condensation temperature of the gaseous working fluid
is below the minimum temperature of the cooling medium in the
absorption stage.

In accordance with another aspect of the invention, there is
provided a method of optimizing, within limits imposed by
available sources of cooling and heating mediums, the energy
supply capability of a gaseous working fluid which is expanded
from a charged high pressure level to a spent low pressure level
to provide available energy, the method comprising expanding the
gaseous working fluid to a spent low pressure level where the
condensation temperature of the working fluid is below the
minimum temperature of the available cooling medium, and
regenerating the spent working fluid by, in a plurality of
successive incremental regeneration stages:

(a) condensing the working fluid being regenerated in an
absorption stage by dissolving it in a solvent solution while
cooling with the cooling medium, the solvent solution comprising
a solvent having an initial working fluid concentration which is
sufficient to provide a solvent solution boiling range suitable
for absorption of the working fluid;

(b) increasing the pressure of the solvent solution containing
the dissolved working fluid, and evaporating the working fluid
being regenerated by heating in an evaporation stage with the
available heating medium;

(c) feeding the evaporated working fluid to a succeeding
regeneration stage for condensation;

(d) recycling the balance of the solvent solution remaining
after evaporation of the working fluid being regenerated, to
constitute the solvent solution for the absorption stage of that
regeneration stage; and

(e) withdrawing regenerated working fluid from a final
regeneration stage.

Further in accordance with the invention, there is provided a
method of optimizing, within limits imposed by available sources
of cooling and heating mediums, the energy supply capability of
a gaseous working fluid which is expanded from a charged high
pressure level to a spent low pressure level to provide
available energy, the method comprising expanding the gaseous
working fluid to a spent low pressure level, and regenerating
the spent working fluid by, in a plurality of successive
regeneration stages, condensing the working fluid and then
evaporating the working fluid at an increased pressure, the
working fluid being condensed in each regeneration stage by
absorbing or dissolving it in a solvent solution while cooling
with the cooling medium, the solvent solution comprising a
solvent having, in each stage, an initial working fluid
concentration which is sufficient to provide a solvent solution
boiling range suitable for absorption of the working fluid, and
the working fluid being evaporated in each stage by increasing
the pressure to a level where the working fluid being
regenerated can be evaporated with the available heating medium,
and then evaporating the working fluid.

The invention further extends to apparatus for generating
energy, the apparatus comprising expansion means for expanding a
gaseous working fluid from a charged high pressure level to a
spent low pressure level to release energy, and a plurality of
successive regeneration stages for regenerating such a spent
working fluid, each regeneration stage comprising:

(a) an absorber for receiving both a spent working fluid and a
solvent solution for dissolving or absorbing the spent working
fluid, the absorber having circulation means for circulating a
cooling medium through it to cool it;

(b) a pump for pumping a resultant solvent solution from the
absorber to increase its pressure;

(c) an evaporator for receiving a resultant solvent solution
from the pump, the evaporator having circulation means for
circulating a heating medium through it to heat it to evaporate
such a working fluid to be regenerated;

(d) a separator for separating such an evaporated working fluid
being regenerated, from such a solvent solution;

(e) feed means to feed such an evaporated working fluid to the
absorber of a succeeding regeneration stage;

(f) recycle means for recycling a solvent solution from the
separator to the condenser;

and a feed conduit for feeding a regenerated working fluid from
the separator of a final regeneration stage to the expansion
means.

Since the solvent solution in each regeneration stage is
recycled, the solvent solution constitutes a closed loop in that
stage, and is separate from the solvent solution in each other
regeneration stage. Furthermore, in each regeneration stage, the
quantity of working fluid being regenerated is dissolved in the
solvent solution of that stage, and the equivalent quantity of
working fluid being regenerated is evaporated from the solvent
solution in the evaporation stage of each regeneration stage.

It will be appreciated that the quantity of solvent solution,
and the initial concentration of working fluid in the solvent
solution in each regeneration stage will be separately adjusted
as may be required for specific operating conditions, and as may
be required for variations in the minimum temperature level of
an available cooling medium.

The solvent of the solvent solution may be any suitable solvent
which is a solvent for the working fluid, which has a boiling
point above the maximum temperature which will be attained in
any evaporation stage, and which will provide a solvent solution
when working fluid is dissolved therein, which has a boiling
point which decreases as the concentration of working fluid
increases.

While the solvent solution is preferably a binary solution, it
will be appreciated that it may be a solution of a plurality of
liquids.

A number of working fluids which would be suitable, are known
to those skilled in the art. Any of such working fluids may be
employed in this invention.

In one embodiment of the invention, the working fluid and
solvent may be in the form of hydrocarbons having appropriate
boiling points. Thus, for example, the solvent may be in the
form of butane or pentane while the working fluid may be in the
form of propane. In an alternative example, the working fluid
may be an appropriate freon compound, with the solvent being an
appropriate solvent for that compound.

In a preferred embodiment of the invention, the working fluid
is in the form of ammonia and the solvent is in the form of
water. In this embodiment of the invention, at a pressure of one
atmosphere the boiling point of water is 100.degree. C. whereas
the boiling point of pure ammonia is -33.degree. C. As the
concentration of ammonia in water increases, the boiling point
of the aqueous ammonia solution will decrease. From binary phase
diagrams of water and ammonia solutions, the appropriate initial
concentration of ammonia in the solvent solution for each
regeneration stage, can readily be determined for this invention
from the pressure and temperature which will prevail in each
condensation stage.

In a preferred embodiment of the invention, the initial
concentration of working fluid in the solvent solution in each
regeneration stage, and the proportion of solvent solution to
working fluid to be regenerated will be selected so that after
complete absorption of the working fluid being regenerated in
the absorption stage of that regeneration stage, the solvent
solution will have a boiling point marginally above the minimum
temperature attained in that absorption stage during use.

In practice, therefore, the minimum quantity of solvent
solution will be employed which will satisfy this requirement
thereby reducing cooling medium requirements to the minimum, and
thereby further reducing heating medium requirements to the
minimum.

It will be appreciated that since the pressure is increased
between the absorption stage and evaporation stage of each
regeneration stage, there will be a step-wise or incremental
increase in pressure between each preceeding regeneration stage
and each succeeding regeneration stage. It follows, therefore,
that the initial concentration of working fluid in the solvent
solution for each successive regeneration stage will be
correspondingly higher to provide a boiling range for the
solvent solution in each stage which is suitable for dissolving
or absorbing the working fluid at the pressure prevailing in
that stage.

In a preferred embodiment of the invention, the pressure is
increased between the absorption and evaporation stages of each
regeneration stage, to the maximum pressure at which the working
fluid being regenerated can be evaporated effectively in the
evaporation stage by the, or by a heating medium, available for
heating the evaporation stage.

The pressure is, therefore, preferably increased in each
regeneration stage to the maximum level where the solvent
solution in each evaporation stage will, after evaporation of
the working fluid in that stage, have a boiling point marginally
below the maximum temperature attainable in that evaporation
stage.

By appropriate control of the pressure, evaporation of the
required quantity of working fluid being regenerated can be
readily effected in each evaporation stage. Control valve means
may, however, be provided to control the quantity of evaporated
working fluid which is fed from each regeneration stage to each
succeeding regeneration stage. Thus, if a greater quantity of
working fluid than that required for regeneration has been
evaporated in an evaporator stage, only the required quantity
will pass to the succeeding regeneration stage. The balance will
be recycled with the solvent solution.

The method of this invention may preferably include the step
of, in each regeneration stage, feeding the solvent solution and
evaporated working fluid from the evaporation stage to a
separation stage for separating the working fluid being
regenerated.

The separator stage may be provided by a separator of any
conventional suitable type known to those skilled in the art.

The solvent solution which is recycled to the absorption stage
in each regeneration stage, is conveniently expanded to reduce
its pressure to a pressure corresponding with or approaching
that of the pressure of the working fluid being regenerated in
that absorption stage.

In a preferred embodiment of the invention, in each
regeneration stage, the solvent solution which is recycled, is
recycled in heat exchange relationship with the evaporation
stage to thereby reduce the heating medium requirements for the
evaporation stage.

The solvent solution which is recycled in each regeneration
stage, may be recycled at least partially in heat exchange
relationship with the absorption stage.

Where the recycled solvent solution is recycled in heat
exchange relationship with an absorption stage, the cooling
medium requirement will decrease because the quantity of heat to
be removed will remain constant, but the capacity of the
absorption stage will have to be increased. Conversely, if the
recycled solvent solution is not recycled in heat exchange
relationship with the absorption stage, the capacity of the
absorption stage will decrease while the requirement of cooling
medium will increase.

In practice, therefore, depending upon the source and
availability of the cooling medium, on the basis of economic
considerations, the reduced cost of supplying lesser quantities
of cooling medium can be balanced against the capital costs of
increasing the capacity of the absorption stages to determine
whether the recycled solvent solution should be recycled in heat
exchange relationship, or at least partially in heat exchange
relationship with the absorption stages, or not at all.

In an embodiment of the invention, all of the absorption stages
of the regeneration stages may be carried out separately in a
single composite absorption stage which is cooled by means of
cooling medium from a common source. Furthermore, all of the
evaporation stages may be carried out separately in a single
composite evaporation stage which is heated by means of a
heating medium from a common source.

The apparatus of this invention may, therefore, include a
single composite absorption unit and a single composite
evaporation unit, with all the absorbers of the various
regeneration stages being incorporated in the absorption unit,
and all the evaporators of the various regeneration stages being
incorporated in the evaporated unit.

While this invention may have various applications, and while
various types of cooling and heating means known to those
skilled in the art, may be employed, this invention can have
particular application in regard to the utilization of readily
and economically available cooling and heating mediums for the
generation of energy.

The invention can, therefore, have specific application where
low temperature differential heating and cooling mediums are
employed.

A preferred application of the invention would, therefore, be
in the field of thermal energy conversion using cool water
withdrawn from a sufficient depth from a body of water as the
cooling medium, and using, as heating medium, surface water from
a body of water, solar heating, surface water heated
additionally by solar heating means, or water or heating fluid
in the form of waste heat fluids from industrial plants.

A preferred application of the invention would, therefore, be
in the field of ocean thermal energy conversion [OTEC] where
ocean surface water is used as the heating medium and ocean
water withdrawn from a sufficient depth from an ocean is used as
the cooling medium, thereby resulting in a low temperature
differential between the heating and cooling mediums.

Normally, ocean water would be withdrawn from a depth of about
200 feet to provide the most economical cooling medium at the
lowest temperature. The temperature does not tend to decrease
significantly beyond a depth of about 200 feet.

The invention further extends to a method of increasing the
pressure of a gaseous working fluid from an initial low pressure
level to a high pressure level utilizing an available heating
medium and utilizing an available cooling medium, which
comprises incrementally increasing the pressure of the working
fluid by, in a plurality of successive incremental regeneration
stages:

(a) absorbing the working fluid being regenerated in an
absorption stage by dissolving it in a solvent solution while
cooling with such an available cooling medium; the solvent
solution comprising a solvent having an initial working fluid
concentration which is sufficient to provide a solvent solution
boiling range suitable for absorption of the working fluid;

(b) increasing the pressure of the solvent solution containing
the dissolved working fluid, and evaporating the working fluid
being regenerated in an evaporation stage by heating with such
an available heating medium;

(c) feeding the evaporated working fluid which is at an
increased pressure level, to a succeeding regeneration stage for
absorption;

(d) recycling the balance of the solvent solution remaining
after evaporation of the working fluid being regenerated, to
constitute the solvent solution for the absorption stage of that
regeneration stage; and

(e) withdrawing regenerated working fluid from a final
regeneration stage.

In accordance with a further aspect of the invention, there is
provided a method of generating energy, which comprises
expanding a gaseous working fluid from a charged high pressure
level to a spent low pressure level to release energy, and
regenerating the spent working fluid by, in at least one
regeneration stage:

(a) condensing the working fluid in an absorption stage by
dissolving it in a solvent solution while cooling with a cooling
medium, the solvent solution comprising a solvent having an
initial working fluid concentration which is sufficient to
provide a solvent solution boiling range suitable for absorption
of the working fluid;

(b) increasing the pressure of the solvent solution containing
the dissolved working fluid and evaporating the working fluid
being regenerated by heating in an evaporation stage;

(c) withdrawing the evaporated working fluid for re-expansion
to release energy; and

(d) recycling the balance of the solvent solution remaining
after evaporation of the working fluid, to constitute the
solvent solution for the absorption stage of that regeneration
stage.

In accordance with a further aspect of the invention there is
provided a method of optimizing, within limits imposed by
available sources of cooling and heating mediums, the energy
supply capability of a gaseous working fluid which is expanded
from a charged high pressure level to a spent low pressure level
to provide available energy, the method comprising expanding the
gaseous working fluid to a spent low pressure level, and
regenerating the spent working fluid by, in at least one
regeneration stage:

(a) condensing the working fluid being regenerated in an
absorption stage by dissolving it in a solvent solution while
cooling with the cooling medium, the solvent solution comprising
a solvent having an initial working fluid concentration which is
sufficient to provide a solvent solution boiling range suitable
for absorption of the working fluid;

(b) increasing the pressure of the solvent solution containing
the dissolved working fluid, and evaporating the working fluid
being regenerated by heating in an evaporation stage with the
available heating medium;

(c) withdrawing the evaporated working fluid to constitute a
charged working fluid; and

(d) recycling the balance of the solvent solution remaining
after evaporation of the working fluid being regenerated, to
constitute the solvent solution for the absorption stage of that
regeneration stage.

The invention further extends to a method of optimizing, within
limits imposed by available sources of cooling and heating
mediums, the energy supply capability of a gaseous working fluid
which is expanded from a charged high pressure level to a spent
low pressure level to provide available energy, the method
comprising expanding the gaseous working fluid to a spent low
pressure level where the condensation temperature of the working
fluid is below the minimum temperature of the available cooling
medium, and regenerating the spent working fluid by absorbing
the working fluid and then evaporating the working fluid at an
increased pressure, the working fluid being absorbed in an
absorption stage by dissolving it in a solvent solution while
cooling with the cooling medium, the solvent solution comprising
a solvent having an initial working fluid concentration which is
sufficient to provide a solvent solution boiling range suitable
for absorption of the working fluid, and the working fluid being
evaporated in an evaporator stage by increasing the pressure and
then evaporating the working fluid being regenerated with the
available heating medium.

The invention further extends to a method of increasing the
pressure of a gaseous working fluid from an initial low pressure
level to a high pressure level utilizing an available heating
medium and utilizing an available cooling medium having a
temperature which need not be below the condensation temperature
of the low pressure working fluid, which comprises:

(a) condensing the working fluid being regenerated in an
absorption stage by dissolving it in a solvent solution while
cooling with such an available cooling medium; the solvent
solution comprising a solvent having an initial working fluid
concentration which is sufficient to provide a solvent solution
boiling range suitable for absorption of the working fluid;

(b) increasing the pressure of the solvent solution containing
the dissolved working fluid, and evaporating the working fluid
being regenerated in an evaporation stage by heating with such
an available heating medium;

(c) recovering the evaporated working fluid which is at the
increased pressure level; and

(d) recycling the balance of the solvent solution remaining
after evaporation of the working fluid being regenerated, to
constitute the solvent solution for the absorption stage.

The expansion of the working fluid from a charged high pressure
level to a spent low pressure level to release energy may be
effected by any suitable conventional means known to those
skilled in the art, and the energy so released may be stored or
utilized in accordance with any of a number of conventional
methods known to those skilled in the art.

In a preferred embodiment of the invention, the working fluid
may be expanded to drive a turbine of conventional type.

In an embodiment of the invention, where the mass ratio between
the solvent solution being recycled through an absorption stage
and the working fluid being regenerated is sufficient, the
pressure of the solvent solution leaving the evaporation stage
may be utilized to increase the pressure of the working fluid
being regenerated which is introduced into the absorption stage
with the recycled solvent solution.

In this embodiment of the invention, instead of expanding the
solvent solution which is recycled to reduce its pressure to a
pressure corresponding with or approaching that of the pressure
of the working fluid being regenerated in an absorption stage,
the solvent solution may be injected into the absorption stage
in such a manner as to entrain the working fluid and draw the
working fluid into the absorption stage.

Various injection systems are known to those skilled in the art
which could be used for this purpose. As an example, an
injection system such as an injection nozzle having a restricted
zone to create a zone of low pressure may be used. With such an
injection nozzle, the working fluid will be introduced into the
proximity of the restricted zone so that the reduced pressure
created will permit the working fluid to be introduced into the
absorption stage.

It will be appreciated that, depending upon relative flow rates
and pressures, it may still be necessary to control the pressure
of the recycled solvent solution by expanding it to provide an
appropriate pressure.

By utilizing the pressure, or at least part of the pressure, of
the solvent solution which is recycled, this will contribute to
an increase in pressure in the absorption stage. This can
provide the advantage of improving absorption in the absorption
stage, or can be utilized to permit expansion of the working
fluid to an even lower spent level. In this event, the initial
increase in pressure provided by the solvent solution may be
utilized to increase the pressure in the absorption stage, to a
level where absorption can be effectively achieved in accordance
with this invention.

Applicant believes that this application of the pressure of the
solvent solution will tend to be valuable in the first stage,
and probably the first and second stages of a multi-stage
regeneration system while, in a single stage system or a system
employing only two stages it will tend to be less valuable. This
will primarily be due to the fact that the mass ratio between
the recycled solvent solution and the working fluid will not be
sufficient.

Preferred embodiments of the invention are now described by way
of example with reference to the accompany drawings.

In the drawings:

**FIG. 1** shows a schematic representation of one
embodiment of the method and apparatus of this invention;

![](fig1.gif)

**FIG. 2** shows a fragmentary schematic representation of
the method and apparatus of FIG. 1 incorporating a modification
to the expansion stage;

![](fig2.gif)

**FIG. 3** shows a fragmentary schematic representation of a
further embodiment of the invention in which injection means is
utilized to inject the working fluid being regenerated;

![](fig3.gif)

**FIG. 4** shows a schematic representation of a further
embodiment of the method and apparatus of this invention.

![](fig4.gif)

With reference to FIG. 1 of the drawings, numeral 50 refers
generally to apparatus for use in generating energy by the
expansion of a gaseous working fluid from a charged high
pressure level to a spent low pressure level to release energy,
and for regenerating the spent working fluid.

The apparatus 50 includes expansion means in the form of a
turbine 52 in which a gaseous working fluid is expanded from a
charged high pressure level to a spent low pressure level to
released energy to drive the turbine 52. The gaseous working
fluid at the high pressure level is fed to the turbine 52 along
charged line 54 and is discharged from the turbine 52 along
spent line 56.

The apparatus 50 further includes regeneration means for
regenerating the spent gaseous fluid. The regeneration means
comprises four successive incremental regeneration stages.

For ease of reference the components of each regeneration stage
have been identified by a letter followed by a suffix in arabic
numerals indicating the particular regeneration stage. In
addition, the flow lines for each regeneration stage have been
identified by reference numerals having a prefix corresponding
to that of the particular regeneration stage.

The first regeneration stage comprises an absorber A1 for
condensing the gaseous working fluid by dissolving it in a
solvent solution, a pump P1 for pumping the solvent solution
containing the dissolved working fluid to increase the pressure,
evaporator E1 for evaporating the working fluid, and a separator
S1 for separating the evaporated working fluid from the solvent
solution.

The first regeneration stage includes an influent line 1-1 into
which the spent gaseous working fluid from the spent line 56 and
solvent solution from a solvent solution recycle line 1-13 are
fed into the first stage and through the absorber A1.

The resultant solvent solution from the absorber A1 is fed
along line 1-2 to the inlet of the pump P1. The solution is
discharged from the pump P1 at an increased pressure along line
1-3 and through the evaporator E1. The solvent solution and
evaporated working fluid are fed from the evaporator E1 along
line 1-4 to the separator S1. The separated evaporated working
fluid is fed from the separator S1 along line 1-5 to the
influent line 2-1 of the second stage. The solvent solution from
the separator S1 is recycled along solvent solution recycle line
1-13 to the influent line 1-1.

The second, third and fourth regeneration stages correspond
exactly with the first regeneration stage except that the
evaporated, separated working fluid from the separator S4 is
withdrawn along line 4-5 and fed into the charged line 54 to
repeat the cycle.

In the preferred embodiment of the invention, the gaseous
working fluid is ammonia, whereas the solvent is water. In
addition, in the preferred embodiment of the invention, the
apparatus 50 is an apparatus for use in producing energy by
ocean thermal energy conversion.

The apparatus 50 is, therefore, conveniently installed on the
seashore or on a floating platform. In addition, the apparatus
50 includes pump means [not shown] for pumping surface water
from the surface of an ocean to the evaporators of the apparatus
to constitute the heating medium for the apparatus, and includes
pump means [not shown] for pumping cold water from a sufficient
depth of such an ocean for constituting the cooling medium for
cooling the absorbers of the apparatus 50.

Thus, the absorber A1 includes circulation means having an
inlet 1-9 and an outlet 1-10 for circulating deep ocean water
through the absorber A1. Similarly, the evaporator E1 includes
an inlet 1-11 and an outlet 1-12 for circulating ocean surface
water through the evaporator for heating the evaporator E1.

Further, in each regeneration stage, the recycle line 1-13,
2-13, 3-13 and 4-13 has an evaporator heat exchange line 1-15,
2-15, 3-15 and 4-15, respectively, passing in heat exchange
relationship through the evaporator E.

In addition, in each of the regeneration stages, the solvent
solution recycle line -13 may have a condenser heat exchange
line 1-16, 2-16, 3-16 and 4-16, respectively, extending in heat
exchange relationship through the absorber A or, alternatively,
may completely bypass the absorber A as indicated by
chain-dotted lines 1-18, 2-18, 3-18 and 4-18.

Where the recycled solvent solution passes in heat exchange
relationship through the absorber of each regeneration stage, it
will assist in cooling the absorber and will thus reduce the
quantity of cooling water required to effect the required
cooling in that absorber since the quantity of heat to be
transferred will remain constant. It will, however, necessitate
an increase in the absorber capacity and thus, in the absorber
size.

In practice, therefore, the capital cost of an increase in
absorber size can be balanced against the cost of the additional
quantity of cooling medium to decide, on the basis of pure
economics, as to whether the recycle line should pass through
the absorbers, should completely bypass the absorbers, or should
pass partially through the absorbers.

In the preferred embodiment of the invention, the recycle lines
will bypass the absorbers.

In the preferred embodiment of the invention, the gaseous
working fluid is ammonia, whereas the solvent solution is a
solution of ammonia in water.

The use of the apparatus 50, and thus the process of this
invention, is now described with reference to a preferred ocean
thermal energy conversion system typically employing, as heating
medium, surface water at a temperature of 27 deg C., and employing
as cooling medium, deep ocean water [typically at a depth of not
less than about 200 feet] having a temperature of about 4 deg C.

Since the boiling point of pure ammonia is -33 deg C. at a
pressure of one atmosphere, and since the minimum temperature of
the cold water cooling medium is 4 deg C., it would normally not be
possible to regenerate ammonia at a pressure of one atmosphere
by using such a cooling medium. In other words, regeneration
would only be possible if the ammonia working fluid were at a
pressure where the boiling point of ammonia is above 4 deg C.

In other words, regeneration of the gaseous working fluid would
only be possible if the working fluid is expanded across the
turbine 52 to a pressure at which it is capable of regeneration
with the available cooling medium. This imposes a direct and
severe limitation on the energy which can be generated since the
maximum pressure to which the ammonia working fluid can be
regenerated is also limited by the evaporation capacity of the
hot water heating medium at 27 deg C.

In practice, utilizing surface water at a temperature of about
27 deg C., evaporation of ammonia in the final evaporator E4 can
only be achieved in an effective manner at a maximum pressure of
about nine atmospheres.

It will be appreciated, therefore, that if the working fluid
can be expanded from a charged level of nine atmospheres to a
spent level pressure of one atmosphere, as opposed to a spent
level pressure of say only four atmospheres, the quantity of
energy released will be increased substantially.

In the preferred process as illustrated in FIG. 1, the gaseous
ammonia working fluid is indeed allowed to expand across the
turbine 52 from a pressure of about nine atmospheres to a
pressure of about one atmosphere.

A specific quantity of gaseous working fluid to be regenerated,
at a spent pressure level of one atmosphere is, therefore fed to
the first stage along influent line 1-1.

This quantity of gaseous working fluid is condensed in the
absorber A1 by dissolving it in a solvent solution which is fed
along solvent solution recycle line 1-13 into the influent line
1-1 at the same pressure of one atmosphere.

In the preferred embodiment of the invention, the solvent
solutions will not be passed in heat exchange relationship
through the absorbers. Thus, the spent gaseous ammonia, which
may contain about 10% by weight of liquid ammonia, will be at a
temperature of about -33 deg C., whereas the corresponding solvent
solution will be at a temperature of about 8 deg C.

The solvent solution comprises water having an initial ammonia
concentration which is sufficient to provide a binary solution
which at the pressure of one atmosphere, has a boiling point
within the temperature range which will prevail in the absorber
A1. Further, the proportion of solvent solution to the quantity
of working fluid to be regenerated is such that after the
solvent solution has dissolved the quantity of working fluid to
be regenerated in the absorber A1, the resultant binary solution
will have a concentration which will provide, at the pressure of
one atmosphere, a boiling point marginally above the minimum
temperature of the cooling medium. The boiling point of the
solvent solution will thus be in the region of about 6 deg C. where
the minimum temperature of the cold water is about 4 deg C.

In this way it will be insured that the total quantity of
working fluid to be regenerated will dissolve in the solvent
solution, and that the minimum quantity of solvent solution to
dissolve that quantity of gaseous ammonia will be employed
thereby reducing the cold water requirements and the capacity of
the absorber A1 to the practical minimum.

The solvent solution containing the dissolved working fluid
being regenerated, will leave the absorber A1 at a temperature
of about 6 deg C. and at a pressure of one atmosphere, and is
pumped by the pump P1 to the evaporator E1.

The pump P1 is controlled to increase the pressure of the
solvent solution to the maximum pressure at which the dissolved
ammonia working fluid can be effectively evaporated in the
evaporator E1 by means of the surface water heating medium at a
maximum temperature of 27 deg C.

Preferably, the pressure increase is controlled so that after
evaporation of the quantity of working fluid being regenerated,
the solvent solution in the evaporator E1 will have a boiling
point marginally below 27 deg C., such as about 25 deg C.

This pressure can readily be determined from a binary
water/ammonia phase diagram in relation to the prevailing
ammonia concentration and temperature range in the evaporator
E1.

It will naturally be appreciated that the initial concentration
of ammonia in water for the solvent solution, as also the
required quantity of solvent solution; which is fed to the
absorber A1, can also readily be determined from such a phase
diagram on the basis of the known pressure and temperature
range.

The evaporated working fluid and solvent solution are fed along
line 1-4 to the separator S1, where they are allowed to
separate.

From the separator S1, the solvent solution, at a temperature
of about 25 deg C. will be recycled along the solvent solution
recycle line 1-13 to constitute the solvent solution for the
first stage. The separated, evaporated ammonia working fluid at
about 25 deg C. is fed from the separator S1 to the second
regeneration stage along influent line 2-1. As in the case of
the first regeneration stage, the quantity of working fluid
being regenerated, is mixed with a solvent solution recycled
from a separator S2 of the second regeneration stage along the
solvent solution recycle line 2-13 for dissolving the working
fluid in the absorber A2.

Since the pressure in the absorber A2 will be greater than the
pressure in the absorber A1, it follows that the initial
concetration of ammonia in the solvent solution for the second
stage will be correspondingly higher to insure that an
appropriate boiling point is again provided for effectively
dissolving or absorbing the working fluid being regenerated in
the absorber A2.

It will be appreciated that the solvent solution which is
recycled from the separator S to the absorber A in each stage
leaves the separator S at a higher pressure than the pressure of
the influent working fluid. Each solvent solution recycle line
1-13, 2-13, 3-13 and 4-13, therefore, includes a
pressure-reducing valve V1, V2, V3 and V4, respectively, for
reducing the pressure of the recycled solvent solution to the
same pressure as that of the influent working fluid being
regenerated.

For each successive regeneration stage, therefore, the initial
concentration of ammonia in the solvent solution will increase
step-wise in correspondence with the step-wise increase in
pressure provided by the pump means in each stage.

It will be appreciated that the apparatus will include an
appropriate number of regeneration stages until the quantity of
working fluid being regenerated, has been regenerated to the
appropriate charged high pressure level in a final regeneration
stage such as the fourth regeneration stage shown in the
drawing. It will further be appreciated that the spent pressure
level to which the working fluid is expanded, will likewise
determine the number of regeneration stages required. Thus if
the working fluid is expanded to only say 3 atmospheres, only
two or three regeneration stages may be required.

In the embodiment illustrated in the drawing, the pump means P4
will increase the pressure of the solvent solution to about nine
atmospheres thereby yielding a charged regenerated working fluid
at a pressure of about nine atmospheres which is withdrawn from
the separator S4 and fed along the charged line 54 to the
turbine 52.

It will be appreciated that in the preferred embodiment of the
invention, the process will be carried out as a continuous
process in which a constant quantity of working fluid by unit
time is continuously being expanded across the turbine 52 and is
then continuously being regenerated in the regeneration means.

To further illustrate the use of the invention in the preferred
embodiment as illustrated in FIG. 1, typical parameters of the
process are now indicated with reference to specific theoretical
calculations performed on the basis of 1 kilogram of gaseous
ammonia working fluid, and on the basis of deep ocean water at a
minimum temperature of 4 deg C. as cooling medium, and surface
ocean water at a maximum temperature of 27 deg C. as heating
medium.

These parameters as calculated are set out in Tables I, II, III
and IV below for the first, second, third and fourth
regeneration stages, respectively.

In each table, the particular point at which the parameter has
been calculated, is indicated by the appropriate reference
numeral in the drawing. These points are listed in the first
column of each table.

The columns in the tables are as follows:

(a) First column--reference numerals (RN);

(b) Second column--temperature (t) in deg C.;

(c) Third column--pressure (p) in atmospheres;

(d) Fourth column--ratio by weight of total ammonia (dissolved
and undissolved) to water plus total ammonia (RATIO);

(e) Fifth column--weight (w) in kilograms; and

(f) Sixth column--Enthalpy (E) in kcal/g.

                 
TABLE
I   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    RN    
t       
p     RATIO   
w     E   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    1-0    -32.0   
1.0   .9920     1.0000   
                                        
354.45
  
    1-1   
+9.0     1.0  
.4266    22.2556   
                                        
-642
  
    1-2   
+6.0     1.0  
.4266    22.2556   
                                        
-20.0
  
    1-3   
+6       1.8  
.4266    22.2556   
                                        
-20.0
  
    1-4    +25.0   
1.8   .4266    22.2556   
                                        
17.9730
  
    1-5    +25.0   
1.8   .9920     1.0000   
                                        
400.0
  
    1-6    +25.0   
1.8  .4000    21.2556   
                                        
0.0
  
    1-7   
+8.0     1.8  
.4000    21.2556   
                                        
-23.4
  
    1-8   
+8.0     1.0  
.4000    21.2556   
                                        
-23.4
  
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
             
TABLE
II   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    RN  
t         
p     RATIO    
w     E   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    2-1  +10.0     
1.8   .5160     17.2457   
                                         
9.4125
  
    2-2 
+6.0       1.8  
.5160     17.2457   
                                         
-10.80
  
    2-3 
+6.0       3.0  
.5160     17.2457   
                                         
-10.80
  
    2-4  +25.0     
3.0   .5160     17.2457   
                                         
28.6905
  
    2-5  +25.0     
3.0   .9920      1.0000   
                                         
403.0
  
    2-6  +25.0     
3.0   .4867     16.2457   
                                         
5.65
  
    2-7 
+8.0       3.0  
.4867     16.2457   
                                         
-14.63
  
    2-8 
+8.0       1.8  
.4867     16.2457   
                                         
-14.63
  
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
             
TABLE
III   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    RN    
t         
p     RATIO   
w     E   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    3-1   
+10.0      3.0  
.6490    8.0000   
                                          
48.625
  
    3-2   
+6.0       3.0  
.6490    8.0000   
                                          
10.00
  
    3-3   
+6.0       5.0  
.6490    8.0000   
                                          
10.00
  
    3-4   
+25.0      5.0  
.6490    8.0000   
                                          
68.688
  
    3-5   
+25.0      5.0  
.9920    1.0000   
                                          
409.5
  
    3-6   
+25.0      5.0  
.6000    7.0000   
                                          
20.00
  
    3-7   
+8.0       5.0  
.6000    7.0000   
                                          
-2.00
  
    3-8   
+8.0       3.0  
.6000    7.0000   
                                          
-2.00
  
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
             
TABLE
IV   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    RN    
t         
p     RATIO   
w     E   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    4-1   
+10.0      5.0  
0.9000   5.4231   
                                          
124.45
  
    4-2   
+6.0       5.0  
0.9000   5.4231   
                                          
80.0
  
    4-3   
+6.0       9.0  
.9000    5.4231   
                                          
80.0
  
    4-4   
+25.0      9.0  
.9000    5.4321   
                                          
139.59
  
    4-5   
+25.0      9.0  
.9920    1.0000   
                                          
412.0
  
    4-6   
+25.0      9.0  
.8792    4.4231   
                                          
78.0
  
    4-7   
+8.0       9.0  
.8792    4.4231   
                                          
60.0
  
    4-8   
+8.0       9.0  
.8792    4.4231   
                                          
60.0
  
    4-9   
+8.0       5.0  
.8792    4.4231   
                                         
60.0
  
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_

From the above theoretical calculations, the total heat
supplied to the four evaporator stages amounted to 1258.35
kcals, while the total heat removed from the four absorption
stages mounted to 1200.8 kcals.

The difference of 57.55 is the work put in per kilogram of
working fluid regenerated and thus the theoretical amount of
work which is available.

The energy required to operate the pumps was calculated to be
2.08 kcals/kg of working fluid regenerated.

The theoretical amount of work available is therefore 55.47
kcal/kg of working fluid.

If it is assumed that the efficiency of the turbine is 85%, the
theoretical thermal efficiency will be 4.408%.

The theoretical thermal efficiency of an ideal Carnot cycle
system operating with a cooling medium at a constant temperature
of 4 deg C. and with a heating medium at a constant temperature of
27 deg C., would be 7.04%. However, considering that the
temperature of the heating and cooling mediums must change in
such a process, the efficiency of the theoretical ideal
thermodynamical cycle will be only about 4.9%.

Therefore, the ratio of the efficiency of a system in
accordance with this invention on the basis of the theoretical
calculations, would be:

(a) 62.55% in relation to an ideal Carnot cycle system;

(b) about 82% in relation to an ideal thermodynamical cycle
under corresponding conditions.

It is an advantage of the embodiment of the invention as
illustrated with reference to the drawing, that an effective
system can be provided for generating energy by using the
relatively low temperature differential between surface ocean
water as heating medium and deep ocean water as cooling medium.

It is a further advantage of this embodiment that a system can
be provided for regeneration of spent gaseous ammonia at a
relatively low level of about one atmosphere or less.

It is a further advantage of the embodiment of the invention as
illustrated, that because the regeneration range of the gaseous
working fluid has been increased, the gaseous working fluid can
be expanded from a high pressure level of about nine
atmospheres, to a low pressure level of about one atmosphere or
less. Thus, the quantity of energy available for release is
substantially greater than would be the case if the working
fluid were expanded from a pressure of about nine atmospheres to
a pressure of only about four or five atmospheres.

The embodiment of the invention as illustrated in the drawing
can provide a further advantage arising from the fact that the
cold water requirements need only be sufficient to provide a
final temperature in each absorber of about 6 deg C. The
temperature of the cold water cooling medium can thus increase
across each absorber as indicated in the above tables. Thus, the
cooling medium requirements will be substantially less than
would be the case if it were necessary to supply a sufficient
quantity of cooling water at a sufficient rate to approach the
Carnot cycle ideal where the cooling medium would remain at the
constant minimum temperature. The same considerations apply to
the heating medium, where the hot water is allowed to cool from
about 27 deg C. to the temperature indicated in the above tables
across each evaporator stage thereby again providing a
substantially reduced heating water requirement over that
required by the ideal Carnot cycle operation.

It will be appreciated that since, in each absorber, the
cooling range for the solvent solution and working fluid is
substantially the same, and the temperature range for the
cooling medium is substantially the same, the absorbers of the
four regeneration stages can conveniently be combined into a
single composite absorber through which the lines 1-1, 2-1, 3-1
and 4-1 pass separately for cooling by means of a single
circulating supply of cold water. In the same way, all the
evaporators can be combined in a single composite evaporator
heated by means of the circulating hot water from a single
source.

It will further be appreciated that, theoretically, the
quantity of solvent solution in each regeneration stage should
remain constant, and that the initial concentration of ammonia
in water to constitute the solvent solution, should also remain
constant for constant minimum cooling water temperatures and
constant maximum heating water temperatures.

In practice, however, the quantity of solvent solution will
have to be adjusted during use to compensate for varying
conditions and for losses. In addition, the concentration of
ammonia in water in each regeneration stage, will have to be
adjusted periodically in relation to seasonal variations in the
minimum temperature of cold water and maximum temperature of hot
water.

It will also be appreciated that where heating of the hot water
can economically be achieved, such as by solar heating or the
like, the effectiveness of the process of this invention can be
improved. Such supplemental heating will, therefore, be employed
under appropriate conditions if dictated by economic
considerations.

With reference to FIG. 2 of the drawings, numeral 150 refers
generally to an alternative embodiment of the method and
apparatus of this invention to the embodiment illustrated in
FIG. 1.

The apparatus 150 corresponds substantially with the apparatus
50 and corresponding parts are indicated by corresponding
reference numerals.

In the apparatus 150, in place of the single turbine 52 of the
apparatus 50, a two-stage turbine system is employed comprising
a first turbine 152 and a second turbine 153.

The charged working fluid is partially expanded across the
first turbine 152 into a heat exchange vessel 170.

From the heat exchange vessel 170 the partially expanded
working fluid is led along separate conduits 171 and 172 through
the absorber A2 and through the absorber A1 respectively in heat
exchange relationship with the cooling water.

Thereafter the partially spent working fluid is further
expanded across the second turbine 153 to its final spent level.
It is then fed, as before, along the spent line 56 to the
influent line 1-1.

Applicant believes that by utilizing a two-stage turbine system
with heat exchange of the partially expanded working fluid, the
effectiveness of the system can be improved particularly where
the system includes a number of regeneration stages. Applicant
believes that it will tend to be less significant where fewer
stages are employed.

With reference to FIG. 3 of the drawings, the drawing shows, to
an enlarged scale, the apparatus of FIG. 1 which has been
adapted in the first and second regeneration stages for the
pressure of the recycled solvent solution to be utilized in
increasing the pressure of the influent spent working fluid into
the absorption stage A1 and the absorption stage A2
respectively.

As indicated in FIG. 3, the absorption stage A1 incorporates an
injection system for injecting the recycled solvent solution at
a pressure substantially higher than the pressure of the spent
working fluid into the absorber A1.

The injection system is in the form of an injection nozzle 180
having an intermediate restricted zone to generate a zone of low
pressure.

The spent line 56 joins the nozzle 180 at the restricted zone
and, as is known those skilled in the art, in an attitude where
the reduced pressure generated at the restricted zone by the
solvent solution being injected through the nozzle 180 into the
absorber A1, will draw the spent working fluid into the nozzle
180 and thus into the absorber A1.

It will be appreciated that the effectiveness of this system
will depend upon the mass ratio between the solvent solution
being recycled and the working fluid being regenerated.

If the ratio is to low, it will not be possible to introduce
the total quantity of working fluid being regenerated by means
of the flow of the solvent solution being recycled.

In practice therefore, depending upon conditions, it may be
necessary to partially reduce the pressure of the solvent
solution being recycled before entry into the nozzle 180, or it
may be necessary to introduce some of the working fluid being
regenerated through the nozzle 180, and the remainder directly
into the absorber A1.

While the absorber A2 has not been illustrated in FIG. 3, it
will be appreciated that the working fluid being regenerated in
the second regeneration stage will be introduced into the
absorber A2 by means of an injection system corresponding to
that of the absorber A1.

The embodiment of the invention as illustrated in FIG. 3 of the
drawings, can provide the advantage that the pressure of the
solvent solution being recycled in the first and second stages
respectively can be at least partially utilized to introduce the
working fluid being regenerated, and to increase the pressure in
the first and second absorbers A1 and A2.

This affect can be utilized to improve the effectiveness of
absorption in the first and second absorbers A1 and A2.
Alternatively, or in addition, this feature can be utilized to
permit expansion of the charged working fluid to a yet lower
pressure across the turbine 52, with reliance being placed on
the pressure contribution of the solvent solution being recycled
to raise the pressure in the absorber A1 to a level where
effective absorption of the working fluid being regenerated can
be effected. Similarly, if employed in relation to the second
regeneration stage, the same considerations will apply where the
working fluid introduced into the absorber A2 can be at a lower
pressure, and reliance is placed on the pressure of the solvent
solution being recycled into the absorber A2, to increase the
pressure to a level for effective absorption in the absorber A2.

Applicant believes that the injection system can be
advantageous in the apparatus 50 particularly in the first and
second stages, but would tend to have lesser value in subsequent
stages.

With reference to FIG. 4 of the drawings, reference numeral 450
refers generally to yet a further alternative embodiment of the
method and apparatus of this invention.

The system 450 as illustrated in FIG. 4, is designed for use
where the charged working fluid is expanded to a relatively
higher level than the level described with reference to FIGS. 1
to 3, but regeneration of the spent working fluid is effected in
accordance with this invention to provide an economical system
with high efficiency.

The apparatus 450 includes a turbine 452, and absorber A, a
pump P, a regenerator R, an evaporator E and a separator S.

The spent working fluid expanded across the turbine 452 is fed
along spent line 456 to influent line 464. Solvent solution
which is recycled from the separator S along solvent solution
recycle line 465 is fed through a pressure reducing valve V to
reduce the pressure of the solvent solution to that of the spent
working fluid, and then into the absorber A through the influent
line 464.

As described with reference to FIG. 1, cooling medium in the
form of cold deep ocean water is circulated in heat exchange
relationship through the absorber A by means of conduit 461,
while heating surface water is circulated through evaporator E
in heat exchange relationship therewith, along conduit 463.

The spent working fluid is absorbed by the solvent solution in
the absorber A whereafter the solvent solution containing the
absorbed working fluid has its pressure increased by the pump P.

The solvent solution containing the absorbed working fluid is
fed from the pump P along line 466 through the regenerator R and
then to the evaporator E for evaporation of the dissolved
working fluid being regenerated.

The solvent solution being recycled along the line 465, is
passed in heat exchange relationship with the solvent solution
passes through the regenerator R to effect heat exchange.

From the evaporator E, the evaporated fluid being regenerated
and the solvent solution passes to the separator S for
separation, whereafter the separated charged working fluid is
fed along charged line 454 to the turbine 452.

To illustrate this embodiment of the invention, typical
parameters of the process of the system of FIG. 4, are now
indicated with reference to specific theoretical calculations
performed on the basis of 1 kilogram of gaseous ammonia working
fluid, and on the basis of deep ocean water at a minimum
temperature of 4 deg C. as cooling medium, and surface ocean water
at a maximum temperature of 27 deg C. as heating medium.

These parameters as calculated are set out in Table V below.
The particular point at which the parameter has been calculated,
has been indicated by the appropriate reference numeral in FIG.
4. These points are listed in the first column of Table V.

                 
TABLE
V   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
          
TEM-            
CONCEN-
  
          
PER-     PRES-  
TRATION        EN-   
          
ATURE    SURE    Kg NH.sub.4 /Kg   
                                    
MASS 
THALPY   
    POINTS deg C.   
                   
atm.   
Solution Kg    K Cal/Kg   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    0     
+25      5.5    
0.9920   1.00  388.0   
    1     
+12      5.5    
0.9368   1.75  248.78   
    2     
+8      
5.5     0.9368   1.75  75.00
  
    3     
+8      
9.0     0.9368   1.75  75.00
  
    4     
+12      9.0    
0.9368   1.75  80.64   
    5     
+25      9.0    
0.9368   1.75  265.45   
    6     
+25      9.0    
0.9920   1.00  407.30   
    7     
+25      9.0    
0.8632   0.75  76.32   
    8     
+13      9.0    
0.8632   0.75  63.16   
    9     
+10      9.5    
0.8632   0.75  63.16   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_

It will be noted from Table V that the working fluid is
expanded from a charged level of 9 atmospheres to a spent level
of 5.5 atmospheres. It will further be noted that the spent
working fluid and solvent solution enter the absorber A at a
temperature of 12 deg C., and that the solvent solution containing
the absorbed working fluid being regenerated, leaves the
absorber A at a temperature of about 8 deg C.

By using an absorber A for absorbing the spent ammonia working
fluid, and by having an appropriate initial concentration of
ammonia in water for the solvent solution being recycled,
absorption of the ammonia working fluid can commence in the
absorber A at a temperature of 12 deg C. or slightly higher, and
complete absorption will have occurred by the time the
temperature has been reduced to about 8 deg C. by the cooling
medium at 4 deg C.

There is therefore a significant temperature difference between
the temperature of the cooling medium and the minimum
temperatures required for complete absorption of the working
fluid being regenerated.

In contrast with a system employing a conventional condensation
stage for the condensation of a working fluid such as ammonia,
condensation of gaseous ammonia at 5.5 atmospheres would only
commence at a temperature of about 5 deg C. resulting in a marginal
difference of 1 deg C. between the temperature of condensation and
the temperature of the available cooling medium, which is at 4 deg
C.

Thus, before condensation can occur in a condensation stage,
the temperature of the working fluid would have to be reduced to
about 5 deg C. by the cooling medium at 4 deg C. It will be
appreciated that because of the marginal temperature difference,
the requirements of cooling water will be substantial and a
substantial heat transfer surface will be required.

In contrast therewith, by utilizing an absorber in accordance
with this invention, while both the working fluid being
regenerated and the solvent solution being recycled will have to
be cooled, because absorption of working fluid can commence at a
temperature substantially above the temperature of the cooling
medium, and can be completed at a temperature substantially
above the temperature of the cooling medium, the amount of
cooling water required can be reduced substantially and/or the
heat transfer surface requirement can be reduced substantially.

In practice, on the basis of economics, the cooling water
requirements, the heat transfer surface area, and the
temperature difference between the temperature of the cooling
water and the temperature required for complete absorption of
the spent working fluid, can be balanced to achieve the most
economical system in the light of the operating parameters and
capital costs.

Because the solvent solution containing the working fluid being
regenerated would leave the absorber A at a temperature higher
than the temperature of a condensed working fluid leaving a
condenser, evaporation in the evaporator E will be facilitated.
By additionally circulating the solvent solution being recycled
and the solvent solution containing the absorbed working fluid
in heat exchange relationship through the regenerator R, both
absorption in the absorber A and evaporation in the evaporator E
will be improved.

The system 450 therefore provides the advantage of an increased
enthalpy drop across the turbine 452 and provides a system of
increased efficiency and economy.

To illustrate the advantages of the system in accordance with
this invention, calculations have been performed to compare the
system illustrated in FIG. 4 with a conventional OTEC system
utilizing a conventional Rankine cycle under the same operating
parameters imposed by the temperatures of the heating and
cooling mediums. The parameters for the Rankine cycle system
were obtained from the publication entitled "OTEC Pilot Plan
Heat Engine" by D. Richards and L. L. Perini, John Hopkins
University, OTC 3592, 1979.

This comparison is set out in Table VI below.

                 
TABLE
VI   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_

COMPARISON OF OFF-DESIGN OPERATING CHARACTERISTICS OF OTEC
PLANTS WITH AMMONIA CLOSED RANKINE CYCLE-[1] AND WATER-AMMONIA
ABSORBTION CYCLE OF FIG. 4 IN ACCORDANCE WITH THIS INVENTION-[2]
RANKINE- FIG. 4 [1]  CYCLE-[2]   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    Warm water temperature deg C.   
                          
+27.89    
+27.89   
    Cold water temperature deg C.   
                          
+4.00     
+4.00   
    Pressure of evaporation   
                  
atm.   
8.8516     9.00   
    Pressure of condensation   
                  
atm.   
6.2784     5.5   
    Inlet turbine temperature deg C.   
                          
+20.389   
+25.00   
    Outlet turbine temperature deg C.   
                          
+10.00    
+7.00   
    Expansion
ratio       
1.41       1.636   
    Enthalpy drop through   
                  
kcal   
8.524      16.984   
   
turbine        kg   
    Turbine efficiency    
0.88       0.88   
    Turbine-generator power   
                  
MW     
13.76      12.452   
    Sea water pumps power   
                  
MW     
2.856      1.832   
    Ammonia pump power   
                  
MW     
0.408      0.124   
    Aux power     
MW      0.0151    
0.0151   
    Net electrical power   
                  
MW     
10.345     10.345   
    Evaporator water flow   
                  
kg/h   
158.76 .times. 10.sup.6   
                                     
107.87
.times. 10.sup.6   
    Condenser water flow   
                  
kg/h   
158.76 .times. 10.sup.6   
                                     
95.86
.times. 10.sup.6   
    Ammonia flow through   
   
turbine       
kg/h    1.388 .times. 10.sup.6   
                                     
0.6304
.times. 10.sup.6   
    Sea water   
    temperature drop   
    evaporator deg C.   
                          
2.580     
1.89   
    condenser/absorber deg C.   
                          
2.505     
2.0   
    Heat flow through   
    evaporator    
kcal/h  409.583 .times. 10.sup.6   
                                     
203.880
.times. 10.sup.6   
    condenser/absorber   
                  
kcal/h 
397.752 .times. 10.sup.6   
                                     
191.715
.times. 10.sup.6   
    regenerator    kcal/h 
0.0        6.222 .times.
10.sup.6   
    Average   
    temperature difference   
    in evaporator deg C.   
                          
6.12      
4.056   
    in condenser/absorber deg C.   
                          
4.635     
4.933   
    in regenerator deg C.   
                          
--        
9.87   
    Heat   
    exchangers surface area   
    evaporator     m.sup.2
78,272.5   59,136.79   
    condenser/absorber   
                  
m.sup.2
100,953.65 45,722.09   
    regenerator    m.sup.2
0.0        990.87   
   
Total                 
179,681.15
105,849.75   
    Net thermal efficiency   
                  
%      
2.1716     4.3627   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
     Thermal efficiency ratio between [2]
& [1] = 2.009   
     Cold water flow decrese in [2] % =
39.62   
     Heat exchangers area decrase in [2] % =
41.09

The significant advantages of the system of FIG. 4 in relation
to the conventional Rankine cycle system are clearly apparent
from Table VI above. It is clear that the system in accordance
with this invention can provide significant imporvements in
efficiency and economy. This is particularly significant in OTEC
systems and related systems where the severe restraints imposed
by the temperatures of the available heating and cooling mediums
have heretofore presented a serious barrier to commercial
utilization of OTEC systems.

---

**US Patent # 4,489,563**   
( December 25, 1984 )

Generation of Energy

**Alexander Kalina**

**Abstract ~**

A method of generating energy which comprises utilizing
relatively lower temperature available heat to effect partial
distillation of at least portion of a multicomponent working
fluid stream at an intermediate pressure to generate working
fluid fractions of differing compositions. The fractions are
used to produce at least one main rich solution which is
relatively enriched with respect to the lower boiling component,
and to produce at least one lean solution which is relatively
improverished with respect to the lower boiling component. The
pressure of the main rich solution is increased whereafter it is
evaporated to produce a charged gaseous main working fluid. The
main working fluid is expanded to a low pressure level to
release energy. The spent low pressure level working fluid is
condensed in a main absorption stage by dissolving with cooling
in the lean solution to regenerate an initial working fluid for
reuse.

Current U.S. Class: 60/673   
Intern'l Class:  F01K 025/06; F01K 025/10   
Field of Search:  60/673,649

**References Cited**   
U.S. Patent Documents   
427,401 ~ May., 1890 ~ Campbell 60/673.   
3,783,613 ~ Jan., 1974 ~ Billings et al. 60/38.   
4,009,575 ~ Mar., 1977 ~ Hartman, Jr. 60/648.   
4,037,415 ~ Jul., 1977 ~ Christopher 60/673.   
4,101,297 ~ Jul., 1978 ~ Uda 55/43.   
4,183,218 ~ Jan., 1980 ~ Eberly, Jr. 60/673.   
4,195,485 ~ Apr., 1980 ~ Brinkerhoff 60/673.   
4,297,332 ~ Oct., 1981 ~ Tatani 423/240.   
4,333,313 ~ Jun., 1982 ~ Cardone, et al. 60/673.   
4,346,561 ~ Aug., 1982 ~ Kalina 60/673.   
Foreign Patent Documents   
2,481,362 ~ Oct., 1981 ~ FR 60/673.   
48,110 ~ Oct., 1981 ~ JP 60/673.   
294,882 ~ Sep., 1929 ~ GB.   
352,492 ~ Jul., 1931 ~ GB.   
786,011 ~ Nov., 1957 ~ GB.   
872,874 ~ Jul., 1961 ~ GB.   
1,085,116 ~ Sep., 1967 ~ GB.

Other References   
OTEC Pilot Plant Heat Engine--D. Richards and L. L. Perini, John
Hopkins University, 1979.   
OTEC--A Comprehensive Energy Analysis--T. C. Carlson et al.

**Description**

This invention relates to the generation of energy. More
particularly, this invention relates to a method of generating
energy in the form of useful energy from a heat source. The
invention further relates to a method of improving the heat
utilization efficiency in a thermodynamic cycle and thus to a
new thermodynamic cycle utilizing the method.

The most commonly employed thermodynamic cycle for
producing useful energy from a heat source, is the Rankine cycle.
In the Rankine cycle a working fluid such as ammonia or a freon is
evaporated in an evaporator utilizing an available heat source.
The evaporated gaseous working fluid is then expanded across a
turbine to release energy. The spent gaseous working fluid is then
condensed in a condenser using an available cooling medium. The
pressure of the condensed working medium is then increased by
pumping it to an increased pressure whereafter the working liquid
at high pressure is again evaporated, and so on to continue with
the cycle. While the Rankine cycle works effectively, it has a
relatively low efficiency. The efficiency of the typical Rankine
cycle is such that currently the cost of installation is in the
region of about $1,700 to about $2,200 per Kw.

A thermodynamic cycle with an increased efficiency over
that of the Rankine cycle, would reduce the installation costs per
Kw. At current fuel prices, such an improved cycle would be
commercially viable for utilizing various waste heat sources.
Applicants prior patent application Ser. No. 143,524 filed Apr.
24, 1980 relates to a system for generating energy which utilizes
a binary or multicomponent working fluid. This system, termed the
Exergy system, operates generally on the principle that a binary
working fluid is pumped as a liquid to a high working pressure. It
is heated to partially vaporize the working fluid, it is flashed
to separate high and low boiling working fluids, the low boiling
component is expanded through a turbine to drive the turbine,
while the high boiling component has heat recovered therefrom for
use in heating the binary working fluid prior to evaporation, and
is then mixed with the spent low boiling working fluid to absorb
the spent working fluid in a condenser in the presence of a
cooling medium. Applicant's Exergy cycle is compared theoretically
with the Rankine cycle in applicant's prior patent application to
demonstrate the improved efficiency and advantages of applicant's
Exergy cycle. This theoretical comparison has demonstrated the
improved effectiveness of applicant's Exergy cycle over the
Rankine cycle when an available relatively low temperature heat
source such as surface ocean water, for example, is employed.
Applicant found, however, that applicant's Exergy cycle provided
less theoretical advantages over the conventional Rankine cycle
when higher temperature available heat sources were employed. It
is accordingly an object of this invention to provide an energy
generating system which would provide an improved efficiency not
only when lower temperature available heat sources are utilized,
but also when higher temperature waste or available heat sources
are utilized. In accordance with one aspect of this invention, a
method of generating energy comprises: (a) subjecting at least a
portion of an initial multicomponent working fluid stream having
an initial composition of lower and higher boiling components, to
partial distillation at an intermediate pressure in a distillation
system by means of relatively lower temperature heat to generate
working fluid fractions of differing compositions;

(b) using the generated fractions to produce at least one main
rich solution which is relatively enriched with respect to a
lower temperature boiling component, and to produce at least one
lean solution which is relatively impoverished with respect to a
lower temperature boiling component;

(c) increasing the pressure of the main rich solution to a
charged high pressure level and evaporating the main rich
solution by means of a relatively higher temperature heat to
produce a charged gaseous main working fluid;

(d) expanding the gaseous main working fluid to a spent low
pressure level to release energy; and

(e) condensing the spent gaseous working fluid in a main
absorption stage by dissolving it with cooling in the lean
solution at a pressure lower than the intermediate pressure to
regenerate the initial working fluid.

In an embodiment of the invention, the relatively lower
temperature heat may be selected from one or more members of the
group comprising:

(a) a lower temperature portion of the relatively higher
temperature heat;

(b) a portion of the relatively higher temperature heat which
is not utilized for evaporating the main rich solution;

(c) heat from a relatively lower temperature heat source;

(d) heat recovered from the spent gaseous working fluid; and

(e) heat recovered from the main absorption stage.

The relatively lower temperature heat may conveniently be
distributed between the distillation system and a lower
temperature portion of a main evaporation stage to preheat the
main rich solution prior to evaporation thereof in a main
evaporation stage.

The method may conveniently include the steps of:

(a) increasing the pressure of the initial working fluid stream
to a first intermediate pressure;

(b) dividing the initial working fluid stream into a first
neutral stream and a first distillation stream;

(c) subjecting the first distillation stream to partial
distillation in the distillation system to produce a first lower
boiling fraction and a first higher boiling fraction;

(d) removing the first higher boiling fraction from the
distillation system to constitute the lean solution; and

(e) absorbing the first lower boiling fraction in the first
neutral stream to enrich that stream to produce a first rich
solution.

In one preferred embodiment of the invention, the method may
including the step of withdrawing the first rich solution from
the distillation system to constitute the main rich solution.

This embodiment of the invention would be employed in
appropriate circumstances where the heating and cooling mediums
which are available and are employed, are such that enrichment
of the working fluid can be effected sufficiently in a single
distillation stage to produce a main rich solution which can be
evaporated effectively with the available relatively higher
temperature heat source.

In an alternative embodiment of the invention, where justified
by the heating and cooling mediums utilized in practicing the
invention, the method may include two, three or more
distillation stages in the distillation system with a view to
producing a main rich solution which is enriched to a greater
extent than in a single stage distillation system.

Thus, for example, where the method includes two distillation
steps in the distillation stage, the method may include the step
of subjecting the first rich solution to at least one second
distillation step by:

(a) mixing with the first rich solution a second higher boiling
fraction recycled from a succeeding distillation stage of the
distillation system to produce a second working fluid stream;

(b) increasing the pressure of the second working fluid stream
to a second higher intermediate pressure;

(c) dividing the second working fluid stream into a second
neutral stream and a second distillation stream;

(d) subjecting the second distillation stream to partial
distillation in the distillation system to produce a second
lower boiling fraction, and to produce the second higher boiling
fraction which is recycled and mixed with the first rich
solution; and

(e) absorbing the second lower boiling fraction in the second
neutral stream to produce a second rich solution which has a
greater enrichment than the first rich solution.

It will be appreciated that the distillation system can be
adjusted and altered in various ways to accommodate the heat
sources which are available and to provide the most effective
production of rich and lean solution streams for use in the
method of this invention.

While the main rich solution may be evaporated partially in the
evaporation stage, it is preferred that the main rich solution
be evaporated substantially or preferably completely in the main
evaporation stage. In this way all heat utilized in evaporating
the main rich solution will be effective in providing the
charged high pressure working fluid which is available to be
expanded and thereby release or generate energy.

If the main rich solution is evaporated only partially, some of
the main rich solution which is not evaporated, will have been
heated to a relatively high temperature, but will not be
available to generate energy. This will therefore reduce the
efficiency of the process.

Even if the portion of the main rich solution which is not
evaporated is utilized for heat exchange purposes to supply heat
to the main rich solution prior to evaporation and/or to supply
heat for utilization in the distillation stage, substantial
energy losses will occur in the heat exchange system because of
the relatively high temperature heat which is involved.

By evaporating the main rich solution substantially completely
in a main evaporation state using a relatively high temperature
heat, and utilizing all or substantially all of the evaporated
main rich solution as the charged gaseous working fluid for
releasing energy, applicant believes high temperature energy
utilization will be the most efficient.

By using relatively low temperature heat for partial
distillation in the distillation system heat losses will be
substantially less. Heat losses will naturally still occur in
the heat exchanger systems of the distillation system. However,
because relatively low temperature heat is being utilized, the
quantity of heat loss will be substantially less.

Relatively lower temperature heat for the distillation system
of this invention may be obtained in the form of spent
relatively high temperature heat, in the form of the lower
temperature part of relatively higher temperature heat from a
heat source, in the form of relatively lower temperature waste
or other heat which is available from the or a heat source,
and/or in the form of relatively lower temperature heat which is
generated in the method and cannot be utilized efficiently or
more efficiently or at all for evaporation of the main rich
solution.

In practice, any available heat, particularly lower temperature
heat which cannot be used or cannot be used effectively for
evaporating the main rich solution, may be utilized as the
relatively lower temperature heat for the distillation system.
In the same way such relatively lower temperature heat may be
used for preheating the main rich solution in a preheater or in
a lower temperature part of the main absorption stage.

In one embodiment of the invention, at least part of the lean
solution may be used as a second working fluid by having its
pressure increased, by being evaporated in a second main
evaporator stage, by being expanded to release energy, and by
then being condensed with the other spent main working fluid and
with any remaining part of the lean solution in an absorption
stage.

In this embodiment of the invention, the second working fluid
and the main working fluid may be expanded independently, for
example, through separate turbines or the like, to release
energy.

This embodiment of the invention may be utilized where the
higher temperature heat source which is available for use in
carrying out the process of this invention, is such that the
pressure of the main rich solution could be increased above the
capacity of the main evaporator and the turbine or other
expansion/energy release means, and yet still be capable of
effective evaporation in the main evaporator. In this event the
second working fluid which is relatively impoverished with
regard to the low boiling components, could be heated first by
the high temperature heat source so that it will be evaporated
effectively at a lower pressure which is compatible with the
pressure capacities of the main evaporator and the turbine. The
spent very high temperature heat from such evaporation can then
be used in series for evaporating the main rich solution at a
convenient pressure. Thereafter, the remaining spent lower
temperature heat can be utilized in the distillation system of
the invention.

In a similar embodiment of the invention, the initial working
fluid stream may be treated in the distillation system to
produce in addition to the lean solution, a plurality of rich
solution streams having differing compositions. In this
embodiment, the rich solution streams may be separately treated
to increase their pressures, to evaporate them and to expand
them, with the evaporation of each rich solution stream being
effected with a heat source temperature range appropriate for
the specific composition range of the rich solution stream.

In one preferred application of the method of this invention,
the enrichment of portion of the working fluid stream may, in
each distillation stage of the distillation system, be increased
to the maximum extent possible consistent with effective
distillation of the distillation stream in that stage with the
available lower temperature heat source, and consistent with
effective condensation of the lower boiling fraction in the
neutral stream with an available cooling medium in each
distillation stage to produce a main rich solution which may be
pumped to high pressure prior to effective evaporation.

Various types of heat sources may be used to drive the cycle of
this invention. Thus, for example, applicant anticipates that
heat sources may be used from sources as high as say
1,000.degree. F. or more, down to heat sources such as those
obtained from ocean thermal gradients. Heat sources such as, for
example, low grade primary fuel, waste heat, geothermal heat,
solar heat and ocean thermal energy conversion systems are
believed to all be capable of development for use in applicant's
invention.

The working fluid for use in this invention may be any
multicomponent working fluid which comprises a mixture of two or
more low and high boiling fluids. The fluids may be mixtures of
any of a number of compounds with favorable thermodynamic
characteristics and having a wide range of solubility. Thus, for
example, the working fluid may comprise a binary fluid such as
an ammonia-water mixture, two or more hydrocarbons, two or more
freons, or mixtures of hydrocarbons and freons.

Enthalpy-concentration diagrams for ammonia-water are readily
available and are generally accepted. Ammonia-water provides a
wide range of boiling temperatures and favorable thermodynamic
characteristics. Ammonia-water is therefore a practical and
potentially useful working fluid in most applications of this
invention. Applicant believes, however, that when equipment
economics and turbine design become paramount considerations in
developing commercial embodiments of the invention, mixtures of
freon-22 with toluene and other hydrocarbon or freon
combinations will become more important for consideration.

The invention further extends to a method of improving the heat
utilization efficiency in a thermodynamic cycle using a
multicomponent working fluid having components of lower and
higher boiling point, which method comprises:

(a) utilizing relatively lower temperature heat to effect
partial distillation of at least portion of the working fluid
for producing working fluid fractions which have differing
compositions; and

(b) utilizing relatively higher temperature heat to completely
evaporate at least an enriched portion of the working fluid
which has been enriched with respect to a lower boiling
component, to produce a gaseous working fluid.

The invention furhter extends to a method of generating useful
energy from an available heat source, which comprises:

(a) subjecting a multicomponent working fluid having components
of differing boiling points, to partial distillation in a
distillation stage to produce an enriched working fluid liquid
stream which is enriched with respect to a lower boiling point
component;

(b) evaporating the stream substantially completely to produce
a vaporized charged working fluid; and

(c) expanding the charged working fluid to release energy.

Still further in accordance with the invention there is
provided a method of generating energy, which comprises:

(a) feeding an initial multicomponent working fluid stream to a
partial distillation system;

(b) increasing the pressure of the stream to an intermediate
pressure;

(c) separating the stream into a neutral stream and a
distillation stream;

(d) subjecting the first distillation stream to partial
distillation to produce working fluid fractions of differing
compositions;

(e) withdrawing the fraction comprising a lean liquid solution
which is impoverished with respect to a lower boiling component,
from the distillation stage;

(f) mixing the fraction comprising an enriched vapor which is
enriched with respect to a lower boiling component, with the
neutral stream and condensing it therein by means of a cooling
medium to form an enriched liquid stream;

(g) increasing the pressure of the enriched liquid stream;

(h) substantially evaporating the enriched liquid stream in an
evaporation stage to produce a charged working fluid vapor;

(i) expanding the charged working fluid vapor to release energy
and produce a spent working fluid vapor; and

(j) mixing the spent vapor with the lean liquid solution and
condensing it therein in an absorption stage to regenerate the
initial working fluid stream.

In general, standard equipment may be utilized in carrying out
the method of this invention. Thus, equipment such as heat
exchangers, tanks, pumps, turbines, valves and fittings of the
type used in a typical Rankine cycles, may be employed in
carrying out the method of this invention. Applicant believes
that the constraints upon materials of construction would be the
same for this invention as for conventional Rankine cycle power
or refrigeration systems. Applicant believes, however, that
higher thermodynamic efficiency of this invention will result in
lower capital costs per unit of useful energy recovered,
primarily saving in the cost of heat exchange and boiler
equipment. In applications such as geothermal and solar sources,
where heat conversion equipment would tend to be a small part of
the total investment required to produce or collect heat, the
high efficiency of the invention would produce a greater energy
output. Therefore, it would reduce the total cost per unit of
energy produced.

The expansion of the working fluid from a charged high pressure
level to a spent low pressure level to release energy may be
effected by any suitable conventional means known to those
skilled in the art. The energy so released may be stored or
utilized in accordance with any of a number of conventional
methods known to those skilled in the art.

In a preferred embodiment of the invention, the working fluid
may be expanded to drive a turbine of conventional type.

Preferred embodiments of the invention are now described by way
of example with the reference to the accompanying drawings.

In the drawings:

**FIG. 1** shows a simplified schematic representation of
one system for carry out the method of this invention;

![](2fig1.gif)

**FIG. 2** shows a more detailed schematic representation of
one embodiment in accordance with the system of FIG. 1;

![](2fig2.gif)

**FIG. 3** shows a more detailed schematic representation of
an alternative embodiment in accordance with the system of FIG.
1;

![](2fig3.gif)

**FIG. 4** shows a simplified schematic representation of an
alternative system for carrying out the method of this
invention;

![](2fig4.gif)

**FIG. 5** shows a more complete schematic representation of
one embodiment in accordance with the system of FIG. 4;

![](2fig5.gif)

**FIG. 6** shows a schematic representation of yet a further
alternative system in accordance with this invention for
utilizing heat in the form of geothermal heat.

![](2fig6.gif)

With reference to FIG. 1 of the drawings, reference numeral
10.1 refers generally to one embodiment of a thermodynamic
system or cycle in accordance with this invention.

The system or cycle 10.1 comprises a main evaporation stage
12.1, a turbine 16.1, a main absorption stage 20.1, a
distillation system 24.1, and a main rich solution pump 28.1.

In use, using an ammonia-water working solution as the binary
working fluid, an initial working fluid stream at an initial low
pressure will flow from the main absorption stage 20.1 to the
distillation system 24.1 along line 22.1. In the distillation
system 24.1, the initial working fluid stream would have its
pressure increased to an intermediate pressure and would be
split into a neutral stream and a distillation stream (not shown
in FIG. 1). The distillation stream would be subjected to
partial distillation using a low temperature heat source to
generate working fluid fractions of differing composition. The
fraction which is enriched with respect to the low boiling
component, namely enriched with respect to ammonia, would then
be added to the first neutral stream and would be condensed in a
condenser within the distillation system 24.1 to produce a main
rich solution stream leaving the distillation system along line
26.1 and flowing to the main rich solution pump 28.1.

The main rich solution would then be pumped by means of the
pump 28.1 to a higher pressure, and then flows along the line
30.1 to the main evaporation stage 12.1 where it is evaporated
completely with a relatively higher temperature heat source to
form a charged high pressure gaseous working fluid.

The charged gaseous working fluid is then conveyed along line
14.1 to the turbine 16.1 where it is expanded to release energy.
The spent gaseous working fluid is then discharged from the
turbine 16.1 along the line 18.1 to the main absorption stage
20.1. The working fluid is conveniently expanded to the initial
low pressure level.

The fraction of working fluid which is produced in the
distillation system 24.1 which is impoverished with respect to
the lower boiling component, namely the ammonia, constitutes a
high temperature boiling or lean solution stream which leaves
the distillation system 24.1 along line 32.1. The lean solution
has its pressure reduced across a pressure reducing valve 34.1,
and the reduced pressure lean solution flows along line 36.1 to
the main absorption stage 20.1.

In the main absorption stage 20.1 the spent gaseous working
fluid is condensed by being absorbed into the lean solution
while heat is extracted therefrom in the main absorption stage
20.1 by utilizing a suitable available cooling medium.

The relatively higher temperature heat from the waste or other
heat source utilized in carrying out the system or cycle of this
invention is indicated by reference numeral 40.1. The relatively
higher temperature heat 40.1 is fed to the main evaporation
stage 12.1 for evaporating the main rich solution completely.

The spent relatively higher temperature heat from the main
evaporation stage 12.1 which, because of the conventional pinch
point, cannot be utilized efficiently in the main evaporation
stage 12.1, now becomes relatively lower temperature heat. This
spent heat may therefore be fed along dotted line 42.1 to
constitute relatively lower temperature heat 44.1 which is fed
to the distillation system 24.1 for effecting partial
distillation of the portion of the working fluid in the
distillation system.

In addition to the spent relatively higher temperature heat
which is fed to the distillation system as the relatively lower
temperature heat 44.1, relatively lower temperature heat may
also be obtained from another relatively lower temperature
available heat source and/or from the heat extracted from the
main absorption stage 20.1 as indicated by dotted line 46.1
and/or from heat recovered from the spent gaseous working fluid
between the turbine 16.1 and the main absorption stage 20.1 as
indicated by dotted line 48.1.

The available heat can be used in a large number of
combinations to provide for effective utilization thereof. The
way in which the heat will be utilized both for evaporation of
the working fluid and for partial distillation in the
distillation system 24.1, will therefore vary depending upon the
apparatus employed, the capacity of the turbine 16.1, the
working fluid employed, the type of heat utilized as the heat
source, and the availability of relatively low temperature heat
and relatively high temperature heat.

Thus, for example, in the embodiment of FIG. 1, the main
evaporation stage 12.1 may include a preheater stage or a low
temperature stage 13.1. Relatively lower temperature heat may be
fed to the stage 13.1 to preheat the main rich solution prior to
evaporation.

Such relatively lower temperature heat may be:

(a) at least portion of the relatively low temperature heat
44.1 which is diverted from dotted line 42.1 and fed to the
stage 13.1 along line 43.1;

(b) at least portion of the heat extracted from the higher
temperature portion of the main absorption stage 20.1 and fed to
the stage 13.1 along line 45.1;

(c) at least portion of the heat recovered from the spent
gaseous working fluid downstream of the turbine 16.1 and fed to
the stage 13.1 along line 47.1; and/or

(d) relatively lower temperature heat from an available heat
source and fed to the stage 13.1 along line 49.1.

With reference to FIG. 2 of the drawings, reference number 10.2
refers to a more detailed schematic representation of a first
embodiment of the system of FIG. 1.

The system or cycle 10.2 corresponds essentially with the
system 10.1. Corresponding parts are therefore indicated by
corresponding reference numerals except that the suffix "0.1"
has been replaced by the suffice "0.2."

In the system 10.2, the distillation system 24.2 has been
enclosed in a chain dotted line to identify the portions of the
system forming the distillation system 24.2.

The initial working fluid stream at an initial low pressure
flows along the line 22.2 from the main absorption stage 20.2
into the distillation system 24.2. The initial working fluid
stream flows to an intial pump 50.2 where the pressure of the
stream is increased to an intermediate pressure.

On the downstream side of the initial pump 50.2, the initial
working fluid stream is separated into a first neutral stream
which flows along line 52.2, and a first distillation stream
which flows along line 54.2.

The distillation system 24.2 includes a first distillation
stage D1 which is in the form of a heat exchanger to place the
first distillation stream flowing along the line 54.2 in heat
exchange relationship with spent gaseous working fluid flowing
along the line 18.2.

Relatively lower temperature heat from the spent gaseous
working fluid causes partial distillation of the first
distillation stream in the first distillation stage D1 to
generate working fluid fractions of differing compositions which
flow along the line 56.2 to a first separator stage S1.

The first separator stage S1 may be provided by a separator
stage of any conventional suitable type known to those skilled
in the art.

In the separator stage S1 the working fluid fractions become
separated into a lower boiling fraction and a higher boiling
fraction. The higher boiling fraction which is impoverished with
respect to the ammonia, flows out of the distillation system
24.2 along line 32.2 through the pressure release valve 34.2 and
then through the line 36.2 to the main absorption stage 20.2.

The lower boiling fraction which is enriched with respect to
the ammonia flows along line 58.2 and is mixed with the first
neutral stream flowing along line 52.2 to enrich the first
neutral stream. The lower boiling fraction is therefore absorbed
in the first neutral stream in a first condensation stage C1 to
form a first rich solution stream which leaves the first
condensation stage C1.

In the system 10.2, the distillation system 24.2 comprises only
a single distillation unit. The first rich solution stream which
leaves the first condensation stage C1 therefore constitutes the
main rich solution stream which leaves this distillation system
24.2 along the line 26.2 and flows to the main rich solution
pump 28.2 where its pressure is increased prior to evaporation
in the main evaporation stage 12.2.

In the cycle 10.2, cooling water at ambient temperature is
employed both in the main absorption stage 20.2 and in the first
condensation stage C1 to effect absorption of gaseous fractions
into liquid fractions in these two stages. For the relatively
higher temperature heat to effect evaporation of the main rich
solution in the main evaporation stage 12.2, exhaust gases from
a De Laval diesel engine is utilized to flow along the line
40.2.

A case study was prepared to illustrate the recovery of waste
heat from a De Laval diesel engine. Waste heat is available from
such an engine in the form of exhaust gas, jacket water and
lubrication oil. In the embodiment illustrated in FIG. 2 of the
drawings, only the heat available from the exhaust gas was
utilized as a heat source since the lower temperature heat was
not required.

In the embodiment illustrated in FIG. 3, however, heat
available in the form of exhaust gas as well as heat available
in the form of jacket water was utilized as the heat source.

The De Laval engine was a model DSRV-12-4 of Transamerica De
Laval, Inc. "Enterprise". It had a gross bhp rating of 7,390 and
a net bhp rating of 7,313.

The available heat sources which could be utilized from the
waste heat of the De Laval diesel engine are as follows:

    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    EXHAUST GAS   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
   
T1         
750.degree. F. 319.9.degree. C.   
   
T2         
200.degree.     93.3.degree. C.   
    H (heat in  12,566,600 BTU/hr.   
                              
3,166,472
Kcal/hr.   
    exhaust gas   
    above 200.degree. F.)   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    JACKET WATER   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    T1      
175.degree. F.  79.44.degree. C.   
    T2      
163.degree. F.  72.78.degree. C.   
    H       
8,440,300 BTU/hr.   
                            
2,027,130
Kcal/hr.   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    LUBRICATING OIL   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    T1      
175.degree. F.  79.44.degree. C.   
    T2      
153.degree. F.  67.22.degree. C.   
    H       
2,413,290 BTU/hr.   
                            
608,139
Kcal/hr.   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_

EXERGY IN AVAILABLE HEAT SOURCE

Exergy is defined at the initial cooling water temperature of
85 deg F. and final temperature of 105 deg F. Exergy in heat sources
having an initial temperature less than 160 deg F. is considered de
minimus and has been ignored. The exergy in available heat
sources is:

(a) exhaust gas--1,431.4 Kw or 1,230,607 Kw/hr;

(b) jacket water--277.9 Kw or 238,190 Kcal/hr;

(c) lubrication oil--78.3 Kw or 67,329 Kcal/hr;

(d) total--1,787.5 Kw or 1,536.846 Kcal/hr.

In the case study which was performed, the temperatures,
pressures and concentrations were ascertained from water-ammonia
enthalpy/concentration diagrams which are available in the
literature.

The case study which was calculated on the basis of the system
10.2 as illustrated in FIG. 2, had the parameters as set out
below in Table 1.

                                     
TABLE
1   
   
\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_
  
    Point   
       Temperature   
              
Pressure
  
                      
Enthalpy  
Concentration   
                                         
Weight
  
    No.   
        degF.   
            degC.
  
              
psia
  
                  
kg/cm.sup.2
  
                      
BTU/lb
  
                            
kcal/kg
  
                                 
lb/lb
or kg/kg   
                                         
lb/hr
kg/hr   
   
\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_
  
    1  95.0   
          
35.0   
              
42.67
  
                  
3.0
21.6  12.0 0.262   42,719.8   
                                               
19,377.4
  
    2  95.0   
          
35.0   
              
42.67
  
                  
3.0
21.6  12.0 0.262   35,122.7   
                                               
15,931.4
  
    3  95.0   
          
35.0   
              
42.67
  
                  
3.0
21.6  12.0 0.262    7,597.1   
                                                
3,446.0
  
    4  145.4   
          
63.0   
              
42.67
  
                  
3.0
228.4 126.9   
                                 
0.426  
10,282.4   
                                                
4,664.0
  
    5  167.0   
          
75.0   
              
42.67
  
                  
3.0
158.4 88.0 0.262   35,122.7   
                                               
15,931.4
  
    6  167.0   
          
75.0   
              
42.67
  
                  
3.0
813.6 452.0   
                                 
0.890   
2,685.2   
                                                
1,218.0
  
    7  167.0   
          
75.0   
              
42.67
  
                  
3.0
104.4 58.0 0.210   32,437.5   
                                               
14,713.4
  
    8  95.0   
          
35.0   
              
42.67
  
                  
3.0
19.4  10.8 0.426   10,282.4   
                                                
4,664.0
  
    9  95.0   
          
35.0   
              
711.16
  
                  
50.0
  
                      
19.4 
10.8 0.426   10,282.4   
                                                
4,664.0
  
    10 662.0   
          
350.0   
              
711.16
  
                  
50.0
  
                      
1,212.5
  
                            
673.6
  
                                 
0.426  
10,282.4   
                                                
4,664.0
  
    11 183.2   
          
84.0   
              
14.22
  
                  
1.0
956.9 531.6   
                                 
0.426  
10,282.4   
                                                
4,664.0
  
    12 150.8   
          
66.0   
              
14.22
  
                  
1.0
489.6 272.0   
                                 
0.426  
10,282.4   
                                                
4,664.0
  
    13 136.4   
          
58.0   
              
14.22
  
                  
1.0
197.1 109.5   
                                 
0.262  
42,719.8   
                                               
19,377.4
  
    14 116.6   
          
47.0   
              
14.22
  
                  
1.0
104.4 58.0 0.210   32,437.5   
                                               
14,713.4
  
    15 95.0   
          
35.0   
              
14.22
  
                  
1.0
21.6  12.0 0.262   42,719.8   
                                               
19,377.4
  
    16 750.0   
          
399.0   
              
-- 
--  --    --  
gas     91,386.0   
                                               
41,452.0
  
    17 213.3   
          
100.7   
              
-- 
--  --    --  
gas     91,386.0   
                                               
41,452.0
  
    18 85.0   
          
29.4   
              
-- 
--  --    --   water  
107,936.1   
                                               
48,959.0
  
    19 105.0   
          
40.5   
              
-- 
--  --    --  
"       107,936.1   
                                               
48,959.0
  
    20 85.0   
          
29.4   
              
-- 
--  --    --  
"       376,598.0   
                                               
170,822.0
  
    21 105.0   
          
40.5   
              
-- 
--  --    --  
"       376,598.0   
                                               
170,822.0
  
   
\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_

The parameters identified by point numbers 1 through 21 in the
first column of Table 1 are those specifically identified by the
corresponding numbers in FIG. 2.

This case study generated the following data:

(1) turbine output (at 75% efficiency) --- 774.7 Kw;

(2) total pump work --- 11.3 Kw;

(3) net output --- 763.4 Kw or 656.400 Kcal/hr;

(4) thermal efficiency --- 21.2%;

(5) second law efficiency --- 53.9%;

(6) exergy utilization efficiency --- 42.7%;

(7) internal cycle efficiency 71.9%; and

(8) name plate energy recovery ratio --- 14.6%.

As compared to a conventional Rankine cycle, the second law
efficiency was calculated to be 53.9% for the system 10.2 as
opposed to 42.8% for a conventional Rankine cycle. Similarly,
the exergy utilization efficiency was calculated to be 42.7% for
the system 10.2 of FIG. 2, as opposed to 34.2% for the
conventional Rankine cycle. This improvement in efficiency would
therefore allow for a reduction of installed cost per Kw of
between about 40 and 60%.

In calculating the parameters for the system 10.2 of FIG. 2,
the starting point was taken as point 11, namely the pressure of
the spent gaseous working fluid. This was taken to be one
atmosphere which is the lowest pressure which can conveniently
handled without being concerned about subatmospheric sealing
problems, etc.

Utilizing this pressure as the starting point, the temperature
at point 15 would be 35 deg C. based on the temperature of the
cooling water utilized. The concentration of the initial working
fluid stream at point 15 would therefore be fixed from the
water-ammonia enthalpy/concentration diagrams.

The pressure of the initial working fluid stream would
therefore be increase by the initial pump 50.2 to a high
pressure at which the first distillation stream may be
evaporated effectively in the first distillation stage D1,
thereby insuring that the pressure is high enough for effective
condensation in the first condensation stage C1.

The design studies which were performed, were not optimized
either from the thermodynamic or from an economic point of view.

The parameters would, in practice, be varied to balance the
effective utilization of high temperature and low temperature
heat sources while balancing equipment and installation costs.

The theoretical calculations which were prepared for the case
study, have demonstrated the embodiment of the invention as
illustrated in FIG. 2, can provide substantial advantages over
the conventional Rankine type cycle even where extremely high
temperature waste heat sources are employed as the heating
medium. Without wishing to be bound by theory, applicant
believes that these advantages are provided by the effective
utilization of high temperature heat in the evaporation stage,
and low temperature heat in the distillation system thereby
effectively utilizing the heat and limiting the magnitude of
heat losses.

With reference to FIG. 3 of the drawings, reference numeral
10.3 refers to an alternative embodiment of a cycle or system in
accordance with this invention.

The system 10.3 corresponds substantially with the systems 10.1
and 10.2. Corresponding parts are therefore indicated by
corresponding reference numeral except that the suffix "0.3" has
been employed in place of the suffix "0.2".

The system 10.3 again has a distillation system 24.3 which has
been encircled in chain dotted lines to highlight the portions
which constitute the distillation system 24.3.

The distillation system 24.3 includes two distillation units
with the first distillation unit having a distillation stage D1,
a separation stage S1 and a condensation stage C1, while the
second distillation unit has a distillation stage D2, a
separator stage S2 and a condensation stage C2.

In the system 10.3, cooling jacket water from the De Laval
diesel engine would be utilized as the lower temperature heat
source to cause partial distillation of the first distillation
stream flowing along the line 54.3 into the distillation stage
D1.

The partially distilled distillation stream flowing from the
distillation stage D1, flows along the line 56.3 to the first
separator stage S1. As before, the higher boiling fraction flows
along the line 32.3 through the pressure reducing valve 34.3 and
then through the line 36.3 to the main absorption stage 20.3.
The first lower boiling fraction mixes with the first neutral
stream flowing along the line 52.3 and is absorbed in the first
neutral stream in the condensation stage C1.

A second high boiling fraction from the second distillation
unit flows along line 63.3 through a pressure reducing valve
65.3 to the first condensation stage C1.

The first condensation stage C1 is cooled by means of cooling
water at ambient temperature to ensure absorption of the first
lower boiling fraction which is enriched with ammonia.

A second working fluid stream is therefore produced in the
first condensation stage C1 and flows along the line 67.3 to a
second pump 69.3. The second pump 69.3 increases the pressure of
the second working fluid stream whereafter the stream is
separated into a second neutral stream flowing along the line
71.3, and a second distillation stream flowing along the line
73.3.

The second distillation stream flows through the second
distillation stage D2 in heat exchange relationship with the
spent gaseous working fluid flowing along the line 18.3. Partial
distillation occurs in the stage D2 so that the partially
distilled second distillation stream flows along the line 75.3
to a second separator stage S2. The higher boiling fraction from
the separator stage S2 constitutes the second higher boiling
fraction which flows along line 63.3 to the first condensation
stage C1. The second lower boiling fraction flows along line
77.3 and is absorbed into the second neutral stream in the
second condensation stage C2. The second condensation stage C2
is again cooled with cooling water at ambient temperature.

The resultant main rich solution emerges from the distillation
system 24.3 along line 26.3 and enters the pump 28.3 where it is
pumped to an appropriate pressure for complete or substantially
complete evaporation in the main evaporation stage 12.3 where it
is evaporated with exhaust gases from the DeLeval engine.

As in the case of the system 10.2, a design study was performed
on the system 10.3 utilizing not only the exhaust gases from the
De Laval engine as the high temperature heat source, but also
utilizing the jacket water from the DeLaval engine as the low
temperature heat source for use in the distillation system 24.3.

The parameters for the theoretical calculations which were
performed again utilizing standard ammonia-water
enthalpy/concentration diagrams, are set out in Table 2 below.

In Table 2 below, points 1 through 35 in the first column
correspond with the specifically marked points in FIG. 3.

                                     
TABLE
2   
   
\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_
  
    Point   
       Temperature   
              
Pressure
  
                      
Enthalpy  
Concentration   
                                         
Weight
  
    No  degF.   
            degC.
  
              
psia
  
                  
kg/cm.sup.2
  
                      
BTU/lb
  
                            
kcal/kg
  
                                 
lb/lb
or kg/kg   
                                         
lb/hr
kg/hr   
   
\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_
  
    1  95.0   
          
35.0   
              
995.60
  
                  
70.0
  
                      
34.2 
19.0 0.50    12,015.2   
                                                
5,450.0
  
    2  608.0   
          
320.0   
              
995.60
  
                  
70.0
  
                      
1,080.0
  
                            
600.0
  
                                 
0.50   
12,015.2   
                                                
5,450.0
  
    3  174.2   
          
79.0   
              
14.22
  
                  
1.0
831.4 461.9   
                                 
0.50   
12,015.2   
                                                
5,450.0
  
    4  200.0   
          
93.3   
              
-- 
--  --    --   exhaust gas   
                                         
91,386.0
  
                                               
41,452.0
  
    5  750.0   
          
399.0   
              
-- 
--  --    --   exhaust gas   
                                         
91,386.0
  
                                               
41,452.0
  
    6  138.2   
          
59.0   
              
14.22
  
                  
1.0
492.3 273.8   
                                 
0.50   
12,015.2   
                                                
5,450.0
  
    7  140.0   
          
60.0   
              
14.22
  
                  
1.0
229.5 127.5   
                                 
0.26   
38,228.2   
                                               
17,340.9
  
    8  95.0   
          
35.0   
              
14.22
  
                  
1.0
21.2  11.8 0.26    38,228.2   
                                               
17,340.9
  
    9  95.0   
          
35.0   
              
28.45
  
                  
2.0
21.2  11.8 0.26    38,228.2   
                                               
17,340.9
  
    10 95.0   
          
35.0   
              
28.45
  
                  
2.0
21.2  11.8 0.26     6,676.2   
                                                
3,027.8
  
    11 95.0   
          
35.0   
              
28.45
  
                  
2.0
21.2  11.8 0.26    31,555.0   
                                               
14,313.1
  
    12 167.0   
          
75.0   
              
28.45
  
                  
2.0
234.0 130.0   
                                 
0.26   
31,555.0   
                                               
14,313.1
  
    13 167.0   
          
75.0   
              
28.45
  
                  
2.0
847.8 471.0   
                                 
0.80    
5,340.0   
                                                
2,422.2
  
    14 167.0   
          
75.0   
              
28.45
  
                  
2.0
108.9 60.5 0.15    26,214.9   
                                               
11,890.9
  
    15 140.0   
          
60.0   
              
14.22
  
                  
1.0
108.9 60.5 0.15    26,214.9   
                                               
11,890.9
  
    16 122.0   
          
50.0   
              
28.45
  
                  
2.0
388.6 215.9   
                                 
0.50   
12,015.2   
                                                
5,450.0
  
    17 129.2   
          
54.0   
              
28.45
  
                  
2.0
204.3 113.5   
                                 
0.36   
33,041.8   
                                               
14,987.5
  
    18 95.0   
          
35.0   
              
28.45
  
                  
2.0
16.6  9.2  0.36    33,041.8   
                                               
14,987.5
  
    19 95.0   
          
35.0   
              
64.00
  
                  
4.5
16.6  9.2  0.36    33,041.8   
                                               
14,987.5
  
    20 95.0   
          
35.0   
              
64.00
  
                  
4.5
16.6  9.2  0.36    24,003.7   
                                               
10,887.9
  
    21 95.0   
          
35.0   
              
64.00
  
                  
4.5
16.6  9.2  0.36     9,038.1   
                                                
4,099.6
  
    22 136.4   
          
58.0   
              
64.00
  
                  
4.5
211.0 117.2   
                                 
0.50   
12,015.2   
                                                
5,450.0
  
    23 95.0   
          
35.0   
              
64.00
  
                  
4.5
34.2  19.0 0.50    12,015.2   
                                                
5,450.0
  
    24 167.0   
          
75.0   
              
64.00
  
                  
4.5
186.1 103.4   
                                 
0.36   
24,003.7   
                                               
10,887.9
  
    25 167.0   
          
75.0   
              
64.00
  
                  
4.5
801.0 445.0   
                                 
0.92    
2,977.1   
                                                
1,350.4
  
    26 167.0   
          
75.0   
              
64.00
  
                  
4.5
99.0  55.0 0.28    21,026.6   
                                                
9,537.5
  
    27 132.8   
          
56.0   
              
28.45
  
                  
2.0
99.0  55.0 0.28    21,026.6   
                                                
9,537.5
  
    28 175.0   
          
79.4   
              
-- 
--  --    --   jacket water   
                                         
559,924.0
  
                                               
253,977.3
  
    29 163.0   
          
72.8   
              
-- 
--  --    --   jacket water   
                                         
559,924.0
  
                                               
253,977.3
  
    30 85.0   
          
29.4   
              
-- 
--  --    --   cooling water   
                                         
381,156.0
  
                                               
172,889.5
  
    31 105.0   
          
40.5   
              
-- 
--  --    --  
"       381,156.0   
                                               
172,889.5
  
    32 85.0   
          
29.4   
              
-- 
--  --    --  
"       399,908.0   
                                               
181,395.9
  
    33 105.0   
          
40.5   
              
-- 
--  --    --  
"       399,908.0   
                                               
181,395.9
  
    34 85.0   
          
29.4   
              
-- 
--  --    --  
"       106,775.6   
                                               
48,433.5
  
    35 105.0   
          
40.5   
              
-- 
--  --    --  
"       106,775.6   
                                               
48,433.5
  
   
\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_

In relation to this case study, the following data was
calculated:

1. Turbine output (at 75% efficiency)--875.4 Kw.

2. Total pump work--14.5 Kw.

3. Net output--860.9 Kw or 740,159 Kcal/hr.

4. Thermal efficiency--15.2%.

5. Second law efficiency--51.9%.

6. Exergy utilization efficiency--48.2%.

7. Internal cycle efficiency--69.2%.

8. Name plate energy recovery ratio--16.5%.

In comparing the theoretical calculation for the cycle of
system 10.3 with that of a conventional Rankine cycle, it was
found that the second law efficiency of the cycle 10.3 was 51.9%
as opposed to 42.8% for the conventional Rankine cycle. It was
further calculated that the exergy utilization efficiency for
the cycle 10.3 was 48.2% as opposed to 34.2% for the
conventional Rankine cycle. This improvement over the cycle 10.2
is believed to be as a result of the more effective utilization
of the lower temperature waste heat generated by the DeLaval
diesel engine during use.

The embodiment of the cycle illustrated in FIG. 3 would
therefore again provide the advantage that the cost per
installed kilowatt would be reduced by about 50 to 60% in
relation to a typical conventional Rankine cycle. It must be
appreciated that this is based essentially on theoretical
calculations and that the actual installed cost per kilowatt
will vary depending upon, design, location and size of plant.

The design studies performed on the cycles 10.2 and 10.3,
nevertheless indicate that waste heat from internal combustion
engines could be converted economically to useful energy output
in a quantity ranging from about 15 to 20% of nameplate capacity
of the primary engine using conventionally available component
equipment, but using applicant's improved heat utilization in
applicant's thermodynamic cycles or systems.

With reference to FIG. 4 of the drawings, reference numeral
10.4 refers generally to yet a further alternative embodiment in
accordance with this invention.

The system 10.4 corresponds generally with the system 10.1.
Corresponding parts are therefore indicated by corresponding
reference numerals except that the suffix "0.4" has been
employed in place of the suffix "0.1".

The cycle or system 10.4 would be utilized where the waste heat
source available for use, is available at such a high
temperature that it could evaporate the main rich solution even
where the pressure of that solution has been increased to a
pressure far in excess of that which can conveniently be handled
by the main evaporator 12 or by the turbine 16.

The cycle 10.4 is therefore designed to utilize such heat in an
effective manner without providing pressure which cannot
conveniently be handled by the evaporator and turbine.

In the system 10.4, the distillation system 24.4 produces, as
before, a lean solution which emerges from the distillation
system 24.4 and flows along line 32.4, through pressure reducing
valve 34.4, along line 36.4 and into the main absorption stage
20.4.

In addition, however, the distillation system 24.4 produces two
rich solution streams having differing compositions. The one
rich solution liquid stream which is the least enriched with the
low boiling ammonia, and is therefore a higher boiling solution
than the remaining rich solution, is fed along line 26.4 to the
pump 28.4 and is evaporated in the main evaporation stage 12.4
using the very high temperature available heat source. The
evaporated charged gaseous working medium produced in the main
evaporation stage 12.4 is fed through a first turbine 16.4 to
release energy therein.

The second rich solution liquid stream which is produced in the
distillation system 24.4, and which is more enriched with the
low boiling ammonia and is therefore a lower boiling fluid than
the other rich solution stream, flows along line 27.4 to a pump
29.4 where its pressure is increased. From there it flows along
line 80.4 through a preheater 82.4 where it flows in heat
exchange relationship with the spent working fluid from the
turbine 16.4. Thereafter it flows along line 84.4 into a second
main evaporation stage 13.4 where it is evaporated with slightly
lower temperature high temperature heat which is recovered from
the main evaporation stage 12.4, to evaporate it. Since it is
more enriched with low boiling ammonia than the remaining rich
solution stream, it can be evaporated effectively utilizing a
lower temperature heat source than utilized in the main
evaporation stage 12.4.

The evaporation stage 13.4 therefore produces a second charged
working fluid which is fed to a second turbine 17.4 to release
energy. This spent working fluid flows with the spent working
fluid from the turbine 16.4 to the main absorption stage 20.4
for absorption in the lean solution.

The one rich solution stream which flows along the line 26.4
may, in an embodiment of the invention, have the same
composition as the stream which leaves the absorption stage 20.4
depending upon the available heat source and the operating
conditions.

The system 10.4 is set out in more detail in FIG. 5 and is
identified therein by reference numeral 10.5.

The distillation system 24.5 is again identified by being
encircled with chain dotted lines. The distillation system 24.5
includes a plurality of distillation units comprising main
distillation stages D1 and D2, main condensation stages C1 and
C2, and a plurality of separation stages S1, S2 and S3.

A design calculation was performed upon the system 10.5
utilizing exhaust gas, jacket water and lubricating oil from a
DeLaval diesel engine as available heat sources. This design
calculation provided a calculated second law efficiency of 52.6%
as opposed to a second law efficiency for a conventional rankine
cycle of 42.8%. It further provided a calculated exergy
utilization efficiency of about 51.8% as opposed to a
conventional rankine cycle exergy utilization efficiency of
34.2%.

The embodiment of FIG. 5 illustrates how the parameters of the
system of this invention may be varied to effectively utilize a
large range of available heat sources ranging from very high
temperature available heat to low temperature available heat.

For each application of the invention, available heat sources
will have to be balanced against specific equipment costs, to
arrive at the most appropriate parameters for each application
utilizing appropriate multicomponent diagrams for the particular
working fluid employed.

The embodiments of the invention as illustrated in the
drawings, indicate that the invention can effectively utilize a
plurality of different temperature heat sources to produce
energy thereby providing for effective heat utilization and
reduced heat loss.

Further calculations have been done with the system in
accordance with applicant's invention as compared to a
conventional rankine system. With a typical system in accordance
with this invention, applicant found a second law efficiency of
59.7% as opposed to a second law efficiency of 29.7% for a
typical rankine cycle when utilizing surface ocean water and
deep ocean water as the heating and cooling mediums for a
typical ocean thermal energy conversion system.

In further calculations performed on a heat source in the form
of a solar pond, applicant calculated a second law efficiency
for applicant's invention of about 80% and an exergy utilization
efficiency of about 80% as compared to a second law efficiency
and an exergy utilization efficiency of a typical Rankine cycle
of about 56%.

With reference to FIG. 6 of the drawings, FIG. 6 indicates a
typical cycle in accordance with applicant's invention employed
for utilizing waste heat in the form of geothermal heat.

The embodiment of FIG. 6 corresponds essentially with the
embodiment of FIG. 2. Corresponding parts have therefore been
indicated by corresponding reference numerals except that the
suffix "0.6" has been used in place of the suffix "0.2".

The system or cycle 10.6 was designed on a theoretical basis
for utilization of a heat source in the form of geothermal heat
from a site in the United States known as the East Mesa
geothermal site.

The relatively high temperature heat is fed to the main
evaporation stage 12.6 as indicated by reference numeral 40.6 in
the form of a hot geothermal brine solution which cools from
335 deg F. (168.3 deg C.) to 134.8 deg F. (56.0 deg C.).

The cycle 10.6 includes a single distillation unit which
includes two partial distillation stages D1 and D2.

The relatively lower temperature heat for the distillation
system is provided by the spent gaseous working fluid which
flows along line 18.6 and passes through the distillation stage
D2. Thereafter, the higher boiling fraction from the separator
S1 joins this flow where line 36.6 joins the line 18.6. This
combined flow thereafter flows in heat exchange relationship
with the first distillation stream through the partial
distillation heat exchanger D1.

As in the prior systems, the expansion of the charged working
fluid across the turbine 16.6 is controlled to achieve a reduced
pressure corresponding to the pressure to which the pressure of
the lean solution is reduced by the pressure reducing valve
34.6.

As in the case of the other systems, a design study was
performed on the system or cycle 10.6 utilizing geothermal heat
as the relatively high temperature heat source and utilizing
ambient air as the cooling medium in the main absorption stage
20.6 and in the condensation stage C1.

The parameters for the theoretical calculations which were
performed again utilizing standard ammonia-water
enthalpy/concentration diagrams are set out in Table 3 below.

                                     
TABLE
3   
   
\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_
  
    Point   
       Temperature   
              
Pressure
  
                      
Enthalpy 
Concentration   
                                        
Weight
  
    No.   
        degF.   
            degC.
  
              
psia
  
                  
kg/cm.sup.2
  
                      
BTU/lb
  
                           
kcal/kg
  
                                
lb/lb
or kg/kg   
                                        
lb/hr
  
                                             
kg/hr
  
   
\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_
  
    1  81.0   
          
27.2   
              
113.8
  
                  
8.0
16.6 9.2  0.521   90,358.1   
                                             
40,985.6
  
    2  81.0   
          
27.2   
              
113.8
  
                  
8.0
16.6 9.2  0.521   78,491.2   
                                             
35,602.9
  
    3  81.0   
          
27.2   
              
113.8
  
                  
8.0
16.6 9.2  0.521   11,866.9   
                                              
5,382.7
  
    4  95.0   
          
35.0   
              
113.8
  
                  
8.0
379.6   
                           
210.9
  
                                
0.750  
23,592.2   
                                             
10,701.2
  
    5  149.0   
          
65.0   
              
113.8
  
                  
8.0
174.6   
                           
97.0
0.521   78,491.2   
                                             
35,602.9
  
     5a   
       107.6   
          
42.0   
              
113.8
  
                  
8.0
64.1 35.6 0.521   78,491.2   
                                             
35,602.9
  
    6  149.0   
          
65.0   
              
113.8
  
                  
8.0
747.0   
                           
415.0
  
                                
0.982  
11,725.3   
                                              
5,318.5
  
    7  149.0   
          
65.0   
              
113.8
  
                  
8.0
75.24   
                           
41.8
0.440   66,765.9   
                                             
30,284.4
  
    8  81.0   
          
27.2   
              
113.8
  
                  
8.0
97.2 54.0 0.750   23,582.2   
                                             
10,701.2
  
    9  81.0   
          
27.2   
              
284.5
  
                  
20.0
  
                      
97.2
54.0 0.750   23,592.2   
                                             
10,701.2
  
    10 307.4   
          
153.0   
              
284.5
  
                  
20.0
  
                      
928.8
  
                           
516.0
  
                                
0.750  
23,592.2   
                                             
10,701.2
  
    11 201.2   
          
94.0   
             
49.8
  
                  
3.5
837.7   
                           
465.4
  
                                
0.750  
23,592.2   
                                             
10,701.2
  
    12 116.6   
          
47.0   
              
49.8
  
                  
3.5
469.8   
                           
261.0
  
                                
0.750  
23,592.2   
                                             
10,701.2
  
    13 116.6   
          
47.0   
              
49.8
  
                  
3.5
178.2   
                           
99.0
0.521   90,358.1   
                                             
40,985.6
  
    13a   
       104.0   
          
40.0   
              
49.8
  
                  
3.5
138.1   
                           
76.7
0.521   90,358.1   
                                             
40,985.6
  
    14 116.6   
          
47.0   
              
49.8
  
                  
3.5
75.2 41.8 0.440   66,765.9   
                                             
30,284.4
  
    15 81.0   
          
27.2   
              
49.8
  
                  
3.5
16.6 9.2  0.521   90,358.1   
                                             
40,985.6
  
    16 335.0   
          
168.3   
              
118.0
  
                  
8.3
--   --   Brine   97,200.0   
                                             
44,089.0
  
    17 134.8   
          
56.0   
              
-- 
--  --   --   Brine  
97,200.0   
                                             
44,089.0
  
   
\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_

The points 1 through 17 in the first column of Table 3
correspond with the specifically marked points in FIG. 6.

In relation to this case study, the following data was
calculated:

    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
                        
Rankine
  
                               
Cycle
  
                        
Cycle 
10.6   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_   
    1   turbine output (at 72%
efficiency)   
                              
530Kw   
630Kw   
    2   total pump
work        
75Kw     15Kw   
    3   net
output            
455Kw   
615Kw   
    4   thermal
efficiency      8.6%   
10.7%   
    5   second law efficiency 
35.5%    46.1%   
    6   exergy utilization efficiency   
                              
33.3%   
44.5%   
    7   internal cycle efficiency   
                              
49.2%   
64.0%   
    8   ratio of net output (Rankine
Cycle = 1)   
                              
1.0     
1.35   
    \_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_\_

This embodiment indicates a substantial theoretical improvement
over the conventional Rankine cycle. It further illustrates the
effective utilization of geothermal heat as a relatively higher
temperature heat source for effecting complete evaporation of a
high pressure liquid working fluid which has been enriched, and
utilizing relatively lower temperature heat from spent gaseous
working fluid as the low temperature heat source for causing
partial distillation of portion of the initial working fluid
stream to achieve effective enrichment thereof.

Applicant believes that by having working fluids of markedly
different composition in the evaporation stage and in the main
absorption stage, effective evaporation and heat utilization can
be achieved in the evaporation stage for effective and complete
evaporation of an enriched portion of a working fluid.
Thereafter by utilizing a substantially impoverished fluid in
the main absorption stage, the spent working fluid can be
effectively condensed and thus regenerated for reuse.

It will be appreciated that heat sources can be obtained from
various points in the system and from various heat and waste
heat sources to provide for effective evaporation utilizing
relatively higher temperature heat, and then utilizing spare
relatively higher temperature heat and relatively lower
temperature heat from other sources to effect partial
distillation and thus enrichment of portion of the working fluid
for effective evaporation.

---



**US Patent # 4,548,043**   
( October 22, 1985 )

**Method of Generating Energy**

**Alexander Kalina**

**Abstract ---** A method of generating energy in which
working fluid fractions of differing compositions are generated,
are subjected to heating in a first evaporator stage, are
combined, the combined stream is then evaporated and is expanded
to convert its energy into usable form. Thereafter the combined
stream is processed to regenerate the differing working fluid
fractions for reuse.

US Cl 60/673   

Intl. Cl. F01K 025/06

**References Cited**   
U.S. Patent Documents   
4,346,561 ~ Aug., 1982 ~ Kalina ~ 60/673<>   
4,489,563 ~ Dec., 1984 ~ Kalina ~ 60/673

***Description***

This invention relates to the generation of energy. More
particularly, this invention relates to a method of transforming
the energy of a heat source into usable form by using a working
fluid which is expanded and regenerated. The invention further
relates to a method of improving the heat utilization efficiency
in a thermodynamic cycle and thus to a new thermodynamic cycle
utilizing the method.

The most commonly employed thermodynamic cycle for producing
useful energy from a heat source, is the Rankine cycle. In the
Rankine cycle a working fluid such as water, ammonia or a freon
is evaporated in an evaporator utilizing an available heat
source. The evaporated gaseous working fluid is then expanded
across a turbine to transform its energy into usable form. The
spent gaseous working fluid is then condensed in a condenser
using an available cooling medium. The pressure of the condensed
working medium is then increased by pumping it to an increased
pressure whereafter the working liquid at high pressure is again
evaporated, and so on to continue with the cycle. While the
Rankine cycle works effectively, it has a relatively low
efficiency.

A thermdynamic cycle with an increased efficiency over that of
the Rankine cycle, would reduce the installation costs per Kw.
At current fuel prices, such an improved cycle would be
commercially viable for utilizing various waste heat sources.

Applicants prior U.S. Pat. No. 4,346,561 filed Apr. 24, 1980
relates to a system for generating energy which utilizes a
binary or multicomponent working fluid. This system, termed the
Exergy system, operates generally on the principle that a binary
working fluid is pumped as a liquid to a high working pressure.
It is heated to partially vaporize the working fluid, it is
flashed to separate high and low boiling working fluids, the low
boiling component is expanded through a turbine to drive the
turbine, while the high boiling component has heat recovered
therefrom for use in heating the binary working fluid prior to
evaporation, and is then mixed with the spent low boiling
working fluid to absorb the spent working fluid in a condenser
in the presence of a cooling medium. Applicant's Exergy cycle is
compared theoretically with the Rankine cycle in Applicant's
prior patent to demonstrate the improved efficiency and
advantages of Applicant's Exergy cycle. This theoretical
comparison has demonstrated the improved effectiveness of
Applicant's Exergy cycle over the Rankine cycle when an
available relatively low temperature heat source such as surface
ocean water, for example, is employed. Applicant found, however,
that Applicant's Exergy cycle provided less theoretical
advantages over the conventional Rankine cycle when higher
temperature available heat sources were employed. Applicant then
devised a further invention to provide an improved thermodynamic
cycle for such applications. This invention utilizes a
distillation system in which part of a working fluid is
distilled to thereby assist in regeneration of the working fluid
component. This invention is the subject matter of Applicant's
prior patent application Ser. No. 405,942 which was filed on
Aug. 6, 1982, now U.S. Pat. No. 4,489,563. Applicant believes
that a thermodynamic cycle can be improved if effective steps
can be taken to reduce the effect of the pinch point problem
when a working fluid is evaporated with a heating source. It is
accordingly one of the objects of this invention to provide a
thermodynamic cycle in which the effect of the pinch point
problem can be reduced.

In accordance with one aspect of this invention, a method of
generating energy comprises:

(a) subjecting at least a portion of an initial composite
stream having an initial composition of higher and lower boiling
components, to distillation at an intermediate pressure in a
distillation system to distill or evaporate part of the stream
and thus generate an enriched vapor fraction which is enriched
with a lower boiling component relatively to both a rich working
fluid fraction and a lean working fluid fraction;

(b) mixing the enriched vaor fraction with part of the
composite stream and absorbing it therein to produce at least
one rich working fluid fraction which is enriched relatively to
a composite working fluid with a lower boiling component;

(c) generating at least one lean working fluid fraction from
part of the composite stream, the lean working fluid fraction
being impoverished relatively to such a composite working fluid
with a lower boiling component;

(d) using a remaining part of the initial composite stream as a
condensation stream;

(e) condensing vapor contained in the rich and lean working
fluid fractions to the extent that it is present in either;

(f) increasing the pressures of the rich and lean working fluid
fractions in liquid form to a charged high pressure level;

(g) feeding the rich working fluid fraction and the lean
working fluid fraction separately to a first evaporator stage to
heat the lean working fluid fraction towards its boiling point,
and to evaporate at least part of the rich working fluid
fraction;

(h) mixing the lean and rich working fluid fractions to
generate a composite working fluid;

(i) evaporating the composite working fluid in a second
evaporator stage to produce a charged composite working fluid;

(j) expanding the charged composite working fluid to a spent
low pressure level to transform its energy into usable form; and

(k) condensing the spent composite working fluid in an
absorption stage by cooling and absorbing it in the condensation
stream at a pressure lower than the intermediate pressure to
regenerate the initial composite stream.

The lean and rich working fluid fractions, to the extent that
they are not generated in liquid form, are cooled to condense
them, preferably completely or substantially completely, into
liquid form before their pressures are increased to the charged
high pressure level.

The rich and lean working fluid fractions will usually both
require condensation to generate them in liquid form before they
are pumped to the charged high pressure level.

In one embodiment of the invention the entire initial composite
stream may be subjected to distillation in the distillation
system to produce the enriched vapor fraction, and to produce a
stripped liquid fraction from which the enriched vapor fraction
has been stripped.

In one example of this embodiment of the invention the enriched
vapor fraction may be divided into first and second enriched
vapor fraction streams, and the stripped liquid fraction may be
divided into first, second and third stripped liquid fraction
streams. The first enriched vapor fraction stream may then be
mixed with the first stripped liquid fraction stream to produce
the rich working fluid fraction, the second enriched vapor
fraction stream may be mixed with the second stripped liquid
fraction stream to generate the lean working fluid fraction, and
the third stripped liquid fraction stream may comprise the
remaining part of the initial composite stream which is used as
the condensation stream.

In an alternative example of this embodiment of the invention,
the stripped liquid fraction may be divided into first, second
and third stripped liquid fraction streams, the enriched vapor
fraction may be mixed with the first stripped liquid fraction
stream to produce the rich working fluid fraction, the second
stripped liquid fraction stream may be used as the part of the
initial composite stream comprising the lean working fluid
fraction, and the third stripped liquid fraction stream may be
used as the remaining part of the initial composite stream to
constitute the condensation stream.

In an alternative embodiment of the invention, only portion of
the initial composite stream may be subjected to distillation in
the distillation system to produce the enriched vapor fraction,
and to produce a stripped liquid fraction from which the
enriched vapor fraction has been stripped.

In this embodiment of the invention the enriched vapor fraction
may, for example, be divided into first and second enriched
vapor fraction streams and the stripped liquid fraction may be
used to constitute or comprise the condensation stream. In this
example of the invention, the remaining part of the initial
composite stream which is not subjected to distillation may be
divided, for example, into first and second composite streams.
The first and second enriched vapor fraction streams may be
mixed with the first and second composite streams respectively
to produce the rich working fluid fraction and the lean working
fluid fraction.

It will readily be appreciated that depending upon conditions
and circumstances including available heating and cooling
sources, the rich and lean working fluid fractions may be
generated by mixing varying proportions of the enriched vapor
fraction with varying proportions of one or more stripped liquid
fractions, one or more initial composite stream fractions which
are not subjected to distillation, or by making any combination
which will achieve the desired rich and lean working fluid
fractions for reducing the pinch point problem in accordance
with this invention.

It will further be appreciated that by making appropriate
selections from the enriched vapor fraction, from the stripped
liquid fraction and from the initial composite stream two, three
or more working fluid fractions may be produced which have a
range of low boiling component concentrations and which are of
appropriate quantities to allow effective separate heating in a
first evaporator stage, followed by combining two or more of the
streams, followed by separate heating in a subsequent evaporator
stage, again followed by mixing of the fluid streams to reduce
the number of streams, again followed by evaporation in a
subsequent evaporator stage, and so on until a single composite
working fluid has been produced which can then be evaporated and
expanded to convert its energy into usable form.

In a preferred embodiment of the invention, the condensation
stream will be throttled down to the pressure of the spent
composite working fluid for absorbing the spent composite
working fluid therein in the absorption stage.

The condensation stream and the spent composite working fluid
may be cooled in the absorption stage utilizing any appropriate
and available cooling medium.   
The initial composite stream generated in the absorption stage,
or the portion thereof which is to be subjected to distillation,
may be subjected to distillation by heating in one or more heat
exchangers using any suitable and available heating medium.

Applicant's presently preferred method of subjecting the
initial composite stream, or portion thereof, to distillation is
by means of relatively low temperature heat. This provides the
advantage that the quantity of heat loss in the heat exchanger
system will be substantially less, and that low temperature heat
may be used for this purpose which cannot conveniently be
utilized in other aspects of the cycle.

In a presently preferred embodiment of the invention,
distillation may be effected by passing the initial composite
stream, or portion thereof, in heat exchange relationship with
one or more of the following heating sources:

(a) the spent composite working fluid;

(b) the condensation stream;

(c) the lean working fluid fraction;

(d) the rich working fluid fraction; and

(e) an auxiliary heating source.

Applicant believes that in many applications of the cycle of
this invention, no auxiliary heating source will be required.
Applicant thus believes that sufficient heat can be extracted
from the spent composite working fluid, from the condensation
stream, and from the lean and rich working fluid fractions to
provide for effective distillation or evaporation of part of the
initial composite stream to produce the enriched vapor fraction
which is enriched with respect to the lower boiling component or
components of the composite stream.

When the initial composite stream is subjected to such
distillation, the lower boiling component or components will
naturally evaporate or distill first thereby producing the
enriched vapor fraction.

The compositions of the rich working fluid and lean working
fluid fractions are preferably selected so that they can be
heated most effectively in the first evaporator stage with the
available heating medium. The first evaporator stage will
generally be the low temperature stage of the evaporator.

Thus, for example, the composition should be selected, and the
relative quantities should be selected, such that the lean
working fluid fraction will be heated towards its boiling point
in the first evaporator stage, while the rich working fluid
fraction will be heated towards its saturated vapor stage.

Preferably the rich working fluid fraction should be enriched
as much as possible with the lower boiling component or
components, consistent with the use of a lean working fluid
fraction which can have a boiling point at the dew point of the
rich working fluid fraction.

In a presently preferred embodiment, the compositions and
quantities will be selected so that the lean working fluid will
be heated to its boiling point or to substantially its boiling
point in the first evaporator stage, while the rich working
fluid fraction will be evaporated substantially or completely to
be in the form of a saturated vapor in the first evaporator
stage.

While both the lean working fluid fraction and the rich working
fluid fraction may be heated to a higher temperature in the
first evaporator stage, Applicant believes that this will not
provide any real thermodynamic advantage in the cycle of this
invention.

The rich and lean working fluid fractions are thus selected so
that after they have passed through the first evaporator stage,
they are substantially or at least generally in equilibrium both
in temperature and pressure to reduce any thermodynamic losses
which may occur during mixing.

When lean and rich working fluid fractions are first generated
in accordance with this invention, they will usually both
contain vapor and must therefore be cooled to condense them
completely. They are then pumped separately to the charged high
pressure level before being fed to the first evaporator stage.
While the lean working fluid fraction may sometimes contain no
vapor and will therefore not have to be cooled, the rich working
fluid fraction will usually contain vapor and will have to be
cooled to condense the vapor and provide the fraction in liquid
form for effective pressure increase.

They may be cooled utilizing any available cooling medium. In
accordance with Applicant's presently preferred embodiment of
the invention, the lean working fluid fraction will be cooled by
passing it in heat exchange relationship with the initial
composite stream which is being subjected to distillation.

Similarly, in accordance with Applicant's presently preferred
embodiment, the rich working fluid fraction will be cooled by
passing it in heat exchange relationship with an auxiliary
cooling source. A preheater system may also be employed between
the cooled rich working fluid fraction and the rich working
fluid fraction which has not yet been cooled with the cooling
medium of the auxiliary cooling source.

In the preferred application of the invention, the rich and
lean working fluid fractions will be cooled so that their
temperatures will be generally equal or close before they are
fed to the first evaporator stage.

After the lean and rich working fluid fractions have passed
through the first evaporator stage, and have been mixed to
constitute the composite working fluid, they may be heated in
the second evaporator stage to evaporate the composite working
fluid completely or at least substantially completely.

Applicant believes that the best thermodynamical advantages
will be provided if the composite working fluid is evaporated
completely in the second evaporator stage. Applicant believes
that it will be less advantageous if the composite working fluid
is not evaporated completely.

If the composite working fluid is evaporated only partially,
some of that fluid, which will have been heated to a relatively
high temperature, will not be available to generate energy. This
will therefore reduce the efficiency of the process. By
evaporating the composite working fluid completely in the second
evaporation stage using a relatively high temperature heat, and
utilizing all or substantially all of the evaporated composite
working fluid as the charged composite working fluid, Applicant
believes that high temperature energy utilization will be the
most efficient and effective.

In a presently preferred embodiment of the invention, the
composite working fluid from the second evaporator stage, will
be superheated in a superheater stage.

The charged composite working fluid may be expanded to a spent
low pressure level to transform its energy into usable form,
utilizing any suitable and available device for this purpose.
Devices of this nature are generally in the form of turbines and
will generically be referred to in the specification as
turbines.

Various single and multi-stage turbines are available and can
be selected to provide the appropriate pressure and temperature
ranges for effective utilization of this invention.

In an embodiment of the invention a multi-stage turbine system
may be used, and at least part of the composite working fluid
may be recycled to the superheater stage after passing through a
high pressure stage of the turbine, and before entering a low
pressure stage of the turbine.

It will readily be appreciated by those skilled in the art that
relatively low temperature heat for the distillation system of
this invention may be obtained from various sources depending
upon circumstances. It may be obtained in the form of spent
relatively high temperature heat, in the form of the lower
temperature part of relatively higher temperature heat from a
heat source, in the form of relatively lower temperature waste
or other heat which is available from the or from a heat source,
and/or in the form of relatively lower temperature heat which is
generated in the method of this invention and cannot be utilized
efficiently or more effectively or at all for evaporation of the
composite working fluid.

Various types of heat sources may be used in the evaporator
stage of the cycle of this invention to evaporate the composite
working fluid. In each instance, depending upon available heat
sources, the cycle can be adjusted to utilize such heat sources
in the most effective manner. For example, Applicant anticipates
that heat sources may be used from sources as high as 1,000 deg F.
or more, down to heat sources such as those obtained from ocean
thermal gradients. Heat sources such as, for example, low grade
primary fuel, waste heat, geothermal heat, solar heat and ocean
thermal energy conversion systems are believed all to be capable
of development for use in this invention.

The working fluid for use in this invention may be any
multi-component working fluid which comprises a mixture of two
or more low and high boiling fluids. The fluids may be mixtures
of any of a number of compounds with favorable thermodynamic
characteristics and having an appropriate or wide range of
solubility. Thus, for example, the working fluid may comprise a
binary fluid such as an ammonia-water mixture, two or more
hydrocarbons, two or more freons, mixtures of hydrocarbons and
freons, or the like.

Applicant's presently preferred working fluid is a
water-ammonia mixture.

Enthalpy-concentration diagrams for ammonia-water are readily
available and are generally accepted. The National Bureau of
Standards will supply upon request an article published in the
National Bureau of Standards list as Project 758-80. This paper
was prepared by Wiltec Research Company, Inc., 488 South 500
West, Provo, Utah, 84601 in 1983 and deals with the experimental
study of water-ammonia mixtures and their properties in a wide
range of temperatures and pressures. A copy of this paper is
attached to this specification and is incorporated herein by
reference.

Ammonia-water provides a wide range of boiling temperatures and
favorable thermodynamic characteristics. Ammonia-water is
therefore a practical and potentially useful working fluid in
many applications of this invention. Applicant believes,
however, that when equipment economics and turbine design become
paramount considerations in developing commercial embodiments of
the invention, mixtures of freon-22 with toluene or other
hydrocarbon or freon combinations will become more important for
consideration.

In general, standard equipment may be utilized in carrying out
the method of this invention. Thus, equipment such as heat
exchangers, tanks, pumps, turbines, valves and fittings of the
type used in typical thermodynamic cycles such as, for example,
Rankine cycles, may be employed in carrying out the method of
this invention. Applicant believes that the constraints upon
materials of construction would be the same for this invention
as for conventional Rankine cycle power or refrigeration
systems. Applicant believes, however, that higher thermodynamic
efficiency of this invention will result in lower capital cost
per unit of useful energy recovered, primarily saving in the
cost of heat exchanger and boiler equipment. Applicant believes
that this invention will provide a reduction in the total cost
per unit of energy produced.

The invention is now described in detail with reference to
certain preferred embodiments invention and with reference to
the accompanying drawings.

In the drawings:

**FIG. 1** shows a schematic representation of one system
for carrying out the method of this invention;   
    
 

![](3fig1.gif)

**FIG. 2** shows a schematic representation of the system of
FIG. 1, but with the superheating stage omitted;
![](3fig2.gif)

**FIG. 3** shows a schematic representation of an
alternative embodiment of this invention;

**FIG. 4** shows a schematic representation of yet a further
alternative embodiment in accordance with this invention; and

![](3fig4.gif)

**FIG. 5** is a graphic representation of a
temperature/enthalpy diagram to demonstrate how application of
this invention can reduce the pinch point problem.

![](3fig5.gif)

With reference to FIG. 1 of the drawings, reference numeral
50.1 refers generally to one embodiment of a thermodynamic
system or cycle in accordance with this invention.

The system of cycle 50.1 comprises an absorption stage 52, a
heat exchanger 54, a recuperator 56, a main heat exchanger 58, a
separator stage 60, a preheater 62, pumps 64 and 66, a first
evaporator stage 68, a second evaporator stage 70, a superheater
section 72, and a multi-stage turbine comprising a high pressure
stage 74 and a low pressure stage 76.

The system or cycle of this invention will now be described by
way of example by reference to the use of an ammonia-water
working solution as the initial composite stream.

This is a continuous system where a charged composite working
fluid is expanded to convert its energy into usable form, and is
then continually regenerated. A substantially constant and
consistent quantity of composite working fluid will therefore be
maintained in the system for long term use of the system.

In analyzing the system it is useful to commence with the point
in the system identified by reference numeral 1 comprising the
initial composite stream having an initial composition of higher
and lower boiling components in the form of ammonia and water.
At point 1 the initial composite stream is at a spent low
pressure level. It is pumped by means of a pump 51 to an
intermediate pressure level where its pressure parameters will
be as at point 2 following the pump 51.

From point 2 of the flow line, the initial composite stream at
an intermediate pressure is heated consecutively in the heat
exchanger 54, in the recuperator 56 and in the main heat
exchanger 58.

The initial composite stream is heated in the heat exchanger
54, in the recuperator 56 and in the main heat exchanger 58 by
heat exchange with the spent composite working fluid from the
turbine sections 74 and 76. In addition, in the heat exchanger
54 the initial composite stream is heated by the condensation
stream as will be hereinafter described. In the recuperator 56
the initial composite stream is further heated by the
condensation stream and by heat exchange with lean and rich
working fluid fractions as will be hereinafter described.

The heating in the main heat exchanger 58 is performed only by
the heat of the flow from the turbine outlet and, as such, is
essentially compensation for under recuperation.

At point 5 between the main heat exchanger 58 and the separator
stage 60 the initial composite stream has been subjected to
distillation at the intermediate pressure in the distillation
system comprising the heat exchangers 54 and 58 and the
recuperator 56. If desired, auxiliary heating means from any
suitable or available heat source may be employed in any one of
the heat exchangers 54 or 58 or in the recuperator 56. This is
shown, for example, by dotted line 59 in the heat exchanger 54.

At point 5 the initial composite stream has been partially
evaporated in the distillation system and is sent to the gravity
separator stage 60. In this stage 60 the enriched vapor fraction
which has been generated in the distillation system, and which
is enriched with the low boiling component, namely ammonia, is
separated from the remainder of the initial composite stream to
produce an enriched vapor fraction at point 6 and a stripped
liquid fraction at point 7 from which the enriched vapor
fraction has been stripped.

In the embodiment illustrated in FIG. 1, the enriched vapor
fraction from point 6, is divided into first and second enriched
vapor fraction streams as at points 9 and 8 respectively.

Further, in the FIG. 1 embodiment, the stripped liquid fraction
from point 7 is divided into first, second and third stripped
liquid fraction streams having parameters as at points 11, 10
and 14 respectively.

The enriched vapor fraction at point 6 is enriched with the
lower boiling component, namely ammonia, relatively to both a
rich working fluid fraction and a lean working fluid fraction as
discussed below.

The first enriched vapor fraction stream from point 9 is mixed
with the first stripped liquid fraction stream at point 11 to
provide a rich working fluid fraction at point 13.

The second enriched vapor fraction stream at point 8 is mixed
with the second stripped liquid fraction stream at point 10 to
produce a lean working fluid fraction at point 12.

The rich working fluid fraction is enriched relatively to the
composite working fluid (as hereinafter discussed) with the
lower boiling component comprising ammonia. The lean working
fluid fraction, on the other hand, is impoverished relatively to
the composite working fluid (as hereinafter discussed) with
respect to the lower boiling component.

The third stripped liquid fraction at point 14 comprises the
remaining part of the initial composite stream and is used to
constitute the condensation stream.   
The difference in composition of the lean and rich working fluid
fractions at points 12 and 13 is achieved by using difference
proportions of vapor to liquid in forming these two fractions.

The lean working fluid fraction is cooled between points 12 and
15 in the recuperator 56 to condense it completely and provide a
condensed lean working fluid fraction at point 15.

The rich working fluid fraction at point 13 is partially
condensed in the recuperator 56 to point 16. Thereafter the rich
working fluid fraction is further cooled and condensed in the
preheater 62 (from point 16 to 18), and is finally condensed in
the absorption stage 52 by means of heat exchange with a cooling
water supply through points 47 to 48.

The lean working fluid fraction at point 15 is then pumped to a
charged high pressure level by means of the pump 64 to provide
it with parameters as at point 24. Likewise the rich working
fluid fraction is pumped to the same or substantially the same
charged high pressure level by means of the pump 66. Thereafter
it passes through the preheater 62 to arrive at point 25 where
it is substantially at the same pressure and temperature as the
lean working fluid fraction which is at point 24.

In practice the temperatures at points 24 and 25 should be
sufficiently high to prevent water precipitation on the surface
of the tubes in the evaporator stage 68.   
The flows at points 24 and 25 are then fed separately to the
first evaporator stage 68. This is the low temperature stage of
the evaporator system where the rich and lean working fluid
fractions are heated with the lower temperature portion of a
heating source supplied originally from point 43 at high
temperature, and leaving the system at point 46.

In the first evaporator stage 68 the rich working fluid
fraction is preferably heated from point 25 to point 27 so that
it is evaporated entirely and is preferably, at point 27, in the
form of a saturated vapor at its dew point. Applicant believes
that this will be the most effective heat utilization in the
first evaporator stage 68 and that while the rich working fluid
fraction could be heated to a lower or higher temperature in
this stage, this will provide no advantage and may lead to
losses.

The lean working fluid fraction is likewise heated in the first
evaporator stage 68 from point 24 to point 26. This is
preferably heated such that the lean working fluid fraction is
heated to or substantially to its boiling point by the time it
reaches point 26. Again Applicant believes that this will be the
most effective utilization of heat in relation to the lean
working fluid fraction in the first evaporator stage 68, and
that heating to a lower or higher temperature will reduce the
efficiency of the cycle.

The lean and rich working fluid fractions 26 and 27 are then
mixed to form, at point 28, a composite working fluid. When they
are mixed they are in thermodynamical equilibrium both in regard
to temperature and pressure. Thermodynamical losses on mixing
should therefore be very low.   
The charged composite working fluid from point 28 is then fed
through the second evaporator stage 70 where it is preferably
evaporated completely to produce the charged composite working
fluid in gaseous form. This is at point 29. From point 29 to
point 30 the charged composite working fluid is superheated in
the superheater stage 72.

The composite working fluid, with parameters at point 30 is
then sent through the high pressure stage 74 of the turbine to
transform its energy into usable form.   
Both the high pressure stage 74 and the low pressure stage 76 of
the turbine are shown to comprise four separate stages. Any
appropriate turbine system may, however, be used instead.

After passing through the high pressure stage 74 of the turbine
the composite working fluid has parameters as at point 34, with
a lower pressure and lower temperature than it had at point 30.
From point 34 the composite working fluid is sent back into the
superheater section 72 of the evaporator stage, where it is
reheated from point 34 to point 35 and is then fed into the low
pressure stage 76 of the turbine, where it is fully expanded
until it reaches the spent low pressure level at point 39. At
point 39 the composite working fluid preferably has such a low
pressure that it cannot be condensed at this pressure and at the
available ambient temperature. From point 39 the spent composite
working fluid flows through the main heat exchanger 58, through
the recuperator 56 and through the heat exchanger 54. Here it is
partially condensed and the released heat is used to preheat the
incoming flow as previously discussed.

The spent composite working fluid at point 42 is then mixed
with the condensation stream at point 20. At point 20 the
condensation stream has been throttled from point 19 to reduce
its pressure to the low pressure level of the spent composite
working fluid at point 42. The resultant mixture is then fed
from point 21 through the absorption stage 52 where the spent
composite working fluid is absorbed in the condensation stream
to regenerate the initial composite stream at point 1.

With reference to FIG. 2 of the drawings, reference numeral
50.2 refers generally to an alternative embodiment of an energy
system or cycle in accordance with this invention.

The system 50.2 corresponds in all respects with the system
50.1, except that the superheater stage 72 of FIG. 1 has been
omitted, and that there is no recycle of the partially expanded
composite working fluid through such a superheater stage.

With reference to FIG. 3 of the drawings, reference numeral
50.3 refers to yet a further alternative embodiment of a system
or cycle in accordance with this invention.

The system 50.3 corresponds substantially with the system 50.1
of FIG. 1, and corresponding parts are identified with
corresponding reference numerals.

In the system 50.3 the stripped liquid fraction at point 7 is
divided into first, second and third stripped liquid fractions
at points 11, 15 and 10 respectively. Further, in this
embodiment, only one enriched vapor fraction is produced at
point 6. It is not split into two vapor fraction streams as in
the case of the cycles 50.1 and 50.2.

The enriched vapor fraction at point 9 is mixed with the first
stripped liquid fraction stream from point 11 to produce the
rich working fluid fraction at point 13.

The rich working fluid fraction at point 13 is condensed and
cooled in the same way as discussed with reference to FIG. 1
through the recuperator 56, the preheater 62 and the absorption
stage 52. It is then pumped to the charged high pressure level
by means of the pump 66, passes through the preheater 62 and
arrives at point 25.

The second stripped liquid fraction stream is obtained at point
15 after passing, together with the third stripped liquid
fraction stream, through the recuperator 56. After point 17, the
second and third stripped liquid fraction streams are split with
the one being conveyed to point 15 to constitute the lean
working fluid fraction. The third stripped liquid fraction
stream from point 10 passes through the heat exchanger 54, is
throttled from point 19 to point 20 to reach the spent low
pressure level, and thus constitutes the condensation stream for
absorbing the spent composite working fluid from point 42 in the
absorption stage 52.

The lean working fluid fraction at point 15 is pumped to the
charged high pressure level by means of the pump 64 and arrives
at point 24 where it has substantially the same pressure and
temperature parameters as the rich working fluid fraction at
point 25.

The remainder of the process is then exactly the same as
described with reference to FIG. 1.

With reference to FIG. 4 of the drawings, reference numeral
50.4 refers to yet a further alternative embodiment of a
thermodynamic system or cycle in accordance with this invention.

The cycle 50.4 corresponds generally with the cycle 50.2 and
thus with the cycle 50.1 as illustrated in FIGS. 2 and 1 of the
drawings. Corresponding parts are therefore indicated by
corresponding reference numerals.

In the system 50.4, unlike the embodiments of the previous
figures, only portion of the initial composite stream which is
at the intermediate pressure at point 2 is subjected to
distillation in the distillation stage.

In the system 50.4 the enriched vapor fraction at point 6 is
again, as in the case of the system 50.1, divided into first and
second enriched vapor fraction streams at points 9 and 8
respectively. These streams flow through the recuperator 56
where they are cooled for partial condensation.

The stripped liquid fraction from point 7, comprises the
condensation stream. It flows from point 14 through the
recuperator 56 to point 17, through the heat exchanger 54 to
point 19, and then through the throttle valve to point 20 to
absorb therein, in the absorption stage 52, the spent composite
working fluid to regenerate the initial composite stream at
point 1 as described with reference to FIG. 1.

After point 2 the remaining part of the initial composite
stream which is not subjected to distillation in the
distillation system, is extracted and divided into first and
second composite streams 11 and 10 respectively.

The second enriched vapor fraction stream from point 8, after
passing through the recuperator 56, is mixed with the second
composite stream from point 10, to constitute the lean working
fluid fraction at point 15. This is then again pumped by means
of the pump 64 to the charged high pressure level to yield the
lean working fluid fraction at point 24.

The first enriched vapor fraction stream from point 9 is fed
through the recuperator 56 and through the preheater 62.
Thereafter, from point 18, it is mixed with the first composite
stream from point 11. This then yields the rich working fluid
fraction at point 13 which passes through the absorption stage
52, through the pump 66, and through the preheater 62 to arrive
at point 25 with the appropriate temperature and pressure
parameters.

As in the case of the embodiment of FIG. 1, these two streams
then pass through the first absorption stage, are then mixed at
point 28, and are then evaporated in the second absorption stage
70.

The embodiment illustrated in FIG. 4 corresponds with the cycle
50.2. It may also, of course, include a superheater stage 72 and
a recycle loop 34 to 35 as illustrated in FIG. 1.

Persons of ordinary skill in this art will appreciate that for
appropriate circumstances and conditions, a plurality of lean
working fluid fractions or rich working fluid fractions can be
generated by selecting quantities of enriched vapor fractions
from zero up, and by selecting stripped liquid fractions and/or
initial composite stream fractions in appropriate quantities as
may be desired.

Applicant will now, without wishing to bound by theory, try to
explain the theoretical basis for this invention with reference
to the graph of FIG. 5. In this graph temperature is plotted
against enthalpy for what Applicant believes would be a typical
water-ammonia system in accordance with this invention. The
points given in this graph correspond with the points used for
the various parameters in the cycle 50.1 of FIG. 1.

The first evaporator stage 68 or the low temperature evaporator
stage 68 can be considered as being divided into two portions.
In the first portion the rich working fluid fraction and the
lean working fluid fraction are heated from points 25 and 24
respectively up to the point designated t.sub.br. Both the rich
and the lean working fluid fractions are below their boiling
points. In the second part of the first evaporator stage 68,
beyond the point t.sub.br the temperatures of both the rich and
lean working fluid fractions are above their bubble point
temperatures.

If one were to introduce into the first separation stage only
the rich working fluid fraction at its given pressure, such a
fluid would begin to boil at point t.sub.br. This is a
relatively low temperature and will permit the use of the
available heat source in full. However, the whole boiling
process will take place at a relatively low temperature which
would result in increased temperature differences in most parts
of the evaporator stage and consequently would result in
relatively high thermodynamic losses. This theoretical process
is shown in FIG. 5 by the line between point 25 and t.sub.br, by
the dotted line from point t.sub.br to point 29a and by the
dotted line from point 29a to point 29.

The cooling of the heat source is designated with a chain
dotted line from point 43 through to point 46.

If a person were now trying to introduce the composite working
fluid, comprising the mixture of the rich working fluid fraction
at point 25 and the lean working fluid fraction at point 24, at
the same given pressure, while trying to use the available heat
source in full, this fluid would only begin to boil at a
temperature t.sub.b. This is a temperature which is higher than
the temperature of the heat source in the corresponding part of
the evaporator stage 68. This would consequently make the
process impossible. This impossible process is demonstrated in
FIG. 5 by the line 24-t.sub.br -t.sub.b -28-29. Such a process
would only be possible if incomplete use is made of the
available heat source and the corresponding thermodynamic losses
are incurred.

When, however, the rich working fluid fraction and lean working
fluid fraction are introduced separately into the first
evaporation stage 68 in accordance with this invention, the rich
working fluid fraction will start to boil at the relatively low
temperature t.sub.br, thereby reducing the "pinch point"
problem. At the same time, because the rich working fluid
fraction and lean working fluid fraction have been combined at
point 28, when they are in thermodynamical equilibrium, the
boiling process will take place at a relatively high
temperature. The thermodynamic losses are therefore reduced.
This, in turn, permits the system to accommodate an increased
pressure in the evaporator stage and consequently at the turbine
inlet. This combined process is shown in FIG. 5 by the solid
line 24-29.

This resultant summary of the enthalpy of the two systems,
demonstrates that the curve followed by the system of this
invention through the first evaporator stage 68, is further away
from the heating medium line in the pinch point zone to thereby
reduce the pinch point problem, while it approaches the heating
medium line more closely after point 28 to reduce the
thermodynamic losses.

Applicant believes that by using more than two working fluid
fractions of varying composition which are combined in
successive stages as they pass through successive evaporator
stages, and by using superheating in an effective number of
stages, the heating curve of the working fluid fraction can be
smoothened to approach that of the heating fluid more closely
and thereby lead to a reduction in thermodynamic losses.

In certain embodiments of the invention where the composite
working fluid has been expanded from a very high pressure to a
spent low pressure level, the working fluid may, at point 39,
have a temperature which is too low. It may also have a
significant content of condensed liquid. As a result it can have
an adverse effect on the performance of the last stages of the
turbine 76. In addition, the quantity and quality of heat
remaining in this stream after point 39 may not be sufficient to
provide for distillation of the initial composite stream and
thus for regeneration of the working fluid fraction. Applicant
believes that this potential disadvantage may overcome by the
superheater stage 72 and by the recycle loop as employed between
points 34 and 35 in FIGS. 1 and 3.

---

**US Patent # 4,586,340**   
( May 6, 1986 )

**Method and Apparatus for Implementing
a Thermodynamic Cycle using a Fluid of Changing
Concentration**

**Alexander Kalina**

Abstract ---
A method and apparatus for implementing a thermodynamic cycle
involves utilizing partial distillation of a multi-component
working fluid stream. At least one main enriched solution is
produced which is relatively enriched with respect to the
lower boiling temperature component, together with at least
one lean solution which is relatively impoverished with the
respect of lower boiling temperature component. The main
working fluid is expanded to a low pressure level to convert
energy to a usable form. This spent low pressure level working
fluid is condensed by dissolving with cooling in the lean
solution to regenerate an initial working fluid for reuse. A
portion of the impoverished fraction may be injected into the
charged gaseous main working fluid in order to obtain added
work and to increase system efficiency by decreasing the
temperature of the output fluid flow when the fluid flow would
otherwise have been superheated. A low pressure, low
temperature expanded spent fluid may be distilled using low
quality heat to create an enriched solution which has a
significantly higher concentration of the lower boiling
component. For this enriched solution, a reduced temperature
and pressure is sufficient to enable distillation. The
efficiency of the cycle may be enhanced by charging the spent
fluid with the lower boiling temperature component prior to
distillation. This may be accomplished by lowering the
pressure of the impoverished fraction to separate an
additional lower boiling temperature fraction.

Current U.S.
Class: 60/673; 60/649; 60/677   
Intern'l Class:  F01K 025/06   
Field of Search:  60/649,673,677

References
Cited

U.S. Patent
Documents   
USP # 4,534,175 ~ Aug., 1985 ~ Kogan, et al. ~ 60/649.

Description

BACKGROUND OF
THE INVENTION

1. Field of
the Invention

This invention
relates generally to methods and apparatus for transforming
energy from a heat source into usable form using a working
fluid that is expanded and regenerated. This invention further
relates to a method and apparatus for improving the heat
utilization efficiency of a thermodynamic cycle.

2. Brief
Description of the Background Art

In the Rankine
cycle, the working fluid such as water, ammonia or a freon is
evaporated in an evaporator utilizing an available heat
source. The evaporated gaseous working fluid is expanded
across a turbine to transform its energy into usable form. The
spent gaseous working fluid is then condensed in a condenser
using an available cooling medium. The pressure of the
condensed working medium is increased by pumping, followed by
evaporation, and so on to continue the cycle.

The basic
Kalina cycle, described in U.S. Pat. No. 4,346,561, utilizes a
binary or multi-component working fluid. This cycle operates
generally on the principle that a binary working fluid is
pumped as a liquid to a high working pressure and is heated to
partially vaporize the working fluid. The fluid is then
flashed to separate high and low boiling working fluids and
the low boiling component is expanded through a turbine to
drive the turbine, while the high boiling component has heat
recovered for use in heating the binary working fluid prior to
evaporation. The high boiling component is then mixed with the
spent low boiling working fluid to absorb the spent working
fluid in a condenser in the presence of a cooling medium.

A theoretical
comparison of the conventional Rankine cycle and the Kalina
cycle demonstrates the improved efficiency of the new cycle
over the Rankine cycle when an available, relatively low
temperature heat source such as ocean water, geothermal energy
or the like is employed.

In applicant's
further invention, referred to as the Exergy cycle, the
subject of U.S. patent application Ser. No. 405,942, filed
Aug. 6, 1982, now U.S. Pat. No. 4,489,563 relatively lower
temperature avilable heat is utilized to effect partial
distillation of at least a portion of a multicomponent working
fluid stream at an intermediate pressure to generate working
fluid fractions of differing compositions. The fractions are
used to produce at least one main rich solution which is
relatively enriched with respect to the lower boiling
component, and to produce at least one lean solution which is
relatively impoverished with respect to the lower boiling
component. The pressure of the main rich solution is
increased; thereafter, it is evaporated to produce a charged
gaseous main working fluid. The main working fluid is expanded
to a low pressure level to convert energy to usable form. The
spent low pressure level working fluid is condensed in a main
absorption stage by dissolving with cooling in the lean
solution to regenerate an initial working fluid for reuse.

The inventor
of the present invention has appreciated that it would be
highly desirable to enable the efficient use of a very low
pressure and temperature fluid at the turbine outlet, in the
Exergy cycle. Regardless of the temperature of the cooling
water in the condenser, the higher the pressure of
condensation in the Exergy cycle, the higher is the
concentration of the lower boiling component in the basic
solution. However, the higher the pressure of condensation,
the higher the pressure at the turbine outlet and the higher
the concentration of the lower boiling component at the
turbine outlet. This higher concentration basic solution
requires for distillation, heat of a lower temperature. Thus,
by reducing the pressure, and consequently the temperature at
the turbine outlet, the concentration of the lower boiling
component of the basic solution may be lowered and a higher
temperature may be required at the turbine outlet to provide
for distillation.

This
contradiction might be addressed by balancing the pressure at
the turbine outlet with the cooling water temperature.
However, to achieve the maximum power output, the turbine
outlet pressure must be as low as possible. When the turbine
outlet pressure and temperature are reduced, as described
above, the concentration of the lower boiling component of the
basic solution decreases. This results in a cycle requiring
exactly the opposite action to increase the turbine outlet
pressure and temperature. The situation worsens with higher
available cooling water temperature.

The inventor
of the present invention has also appreciated the desirability
of controlling the outlet temperature of the fluid exiting the
turbine in the Exergy cycle. The efficiency of a thermodynamic
cycle such as the Exergy cycle may be improved by heating the
fluid in the boiler to the highest possible temperature with
the available heat source. However, it is still desirable that
the fluid exiting from the turbine be at a temperature and
pressure close to that of a saturated vapor. To the extent
that the exiting vapor is superheated, exergy is wasted.

It is
particularly desirable in the Exergy cycle to obtain only
slightly superheated vapor or saturated vapor from the turbine
while inputting fluid at the highest possible temperature to
the turbine. This is because in the Exergy cycle the output
from the turbine is not simply condensed, but instead is used
for distillation. The superheating of the fluid outletted from
the turbine may cause unnecessary exergy losses in the cycle
as a whole. For example, since the spent fluid from the
turbine may be used to pre-heat the condensed fluid in a heat
exchanger prior to regeneration, as described in the
aforementioned patent application, an inefficiently high
temperature difference may exist in the heat exchanger.

If one
attempts to overcome this problem by further fluid expansion
in the turbine, one obtains a lower temperature at the turbine
outlet but a lower pressure as well. This lower pressure fluid
is more troublesome to distill because more heat is required
and this lower pressure fluid requires a larger quantity of
lean solution to absorb it. Thus, this approach to the
solution of the problem of exergy losses arising from the high
temperature of the fluid exiting the turbine is not desirable.

SUMMARY OF THE
INVENTION

It is a
primary object of one aspect of the present invention to
provide a method and apparatus for increasing the efficiency
of the Exergy cycle by enabling the selection of a low
pressure and temperature basic solution at the turbine outlet
through enrichment of the basic solution from the turbine
prior to its regeneration by partial distillation.

It is a
further object of the present invention to provide such a
method and apparatus that lessens the heat loading on the
condenser.

It is a
primary object of another aspect of the present invention, to
decrease the exergy losses arising from the superheating of
the fluid exiting from the turbine without unduly lowering the
pressure of the fluid.

It is another
object of the present invention to provide a method and
apparatus that efficiently regulates the temperature of the
fluid exiting from a turbine in the Exergy cycle and uses any
extra heat to obtain extra energy in the turbine.

These and
other objects of the present invention may be achieved by a
method of generating usable energy including the step of
vaporizing at an upper intermediate pressure, only part of an
initial multi-component working fluid stream having lower and
higher temperature boiling components to form a first vapor
fraction. The first vapor fraction is therefore enriched with
the lower boiling temperature component. The vapor fraction is
mixed with part of the initial working fluid stream and
absorbed therein to produce a rich solution, enriched
relatively to the initial working fluid stream with respect to
the lower temperature boiling component. The remaining part of
the initial working fluid stream is used as a lean solution
which is impoverished relatively to the main solution with
respect to the lower temperature boiling component. The
pressure of the rich solution is increased to a charged high
pressure level. The rich solution is evaporated to produce a
charged gaseous main working fluid that is expanded to a spent
low pressure level to transform its energy into usable form.
The spent main working fluid is cooled and condensed by
absorbing it in a part of the lean solution. An enriched
fraction is separated from a part of the lean solution. The
enriched fraction is enriched relatively to the lean solution
with respect to the lower boiling temperature component. The
enriched fraction is mixed with the condensed main working
fluid to form an initial multi-component working fluid stream.

In accordance
with another preferred embodiment of the present invention a
method of generating usable energy includes the step of
generating a vapor fraction by vaporizing only part of an
initial multi-component working fluid stream having lower and
higher temperature boiling components. The vapor fraction is
enriched with the lower boiling temperature component. The
vapor fraction is mixed with part of the initial working fluid
stream and absorbed therein to produce a rich solution
enriched relatively to the working fluid stream with respect
to the lower temperature component. The remaining part of the
initial working fluid stream is used as a lean solution
impoverished relatively to the rich solution with respect to
lower temperature boiling component. The pressure of the rich
solution is increased to a charged high pressure level. The
rich solution is evaporated to produce a charged, superheated
gaseous main working fluid and expanded to a spent low
pressure level to convert energy into a usable form. The spent
main working fluid is cooled and condensed by dissolving it in
a portion of the lean solution. A portion of the lean solution
is also injected into the charged gaseous working fluid to
lower the temperature of the gaseous working fluid. This
injection may be made into the charged gaseous working fluid
while the main working fluid is continuing to expand or it may
be made into the gaseous main working fluid after the fluid
has been completely expanded.

In accordance
with still another preferred embodiment of the present
invention an apparatus for generating usable energy with a
multi-component working fluid includes a turbine with a gas
inlet and a gas outlet. A distilling device is in fluid
communication with the turbine gas outlet. This device is
adapted to separate a lower boiling temperature component from
a higher boiling temperature component of the multi-component
working fluid using the heat of the outlet gas from the
turbine. The distilling device includes a mixing section
arranged to mix separated lower boiling temperature fraction
with the working fluid to form a rich solution. A condenser is
arranged to condense the rich solution and an evaporator
communicates with the condenser and the inlet to the turbine.
The injector is arranged to inject lean solution from the
distilling device into the superheated fluid near the outlet
of the turbine.

In accordance
with yet another preferred embodiment of the present
invention, an apparatus for generating usable energy with a
multi-component working fluid includes a turbine having a gas
inlet and a gas outlet and a condenser connected to condense
the spent fluid from the turbine. A first distilling device is
in fluid communication with the turbine gas outlet. This
device is adapted to separate a lower boiling temperature
component from a higher boiling temperature component and the
multi-component working fluid. The distilling device includes
a mixing section arranged to mix a separated lower boiling
temperature fraction with the working fluid to form a rich
solution. The second distilling device is arranged to separate
a lower boiling temperature fraction from the fluid remaining
after the lower boiling temperature component has been
separated in the first distilling device. The second
distilling device includes a mixer section adapted to mix a
lower boiling temperature fraction separated by the second
distilling device into the spent fluid from the condenser. An
evaporator communicates with the condenser and the inlet to
the turbine.

In accordance
with another preferred embodiment of the present invention a
regenerator for spent multi-component working fluid having a
temperature and pressure too low for condensation by
conventional means with an available cooling medium includes a
first pump for increasing the pressure of the spent fluid. A
concentrator increases the concentration of the lower boiling
temperature component of the working fluid. A second pump
increases the pressure of the concentrated fluid. A heat
exchanger, communicating with the concentrator, is arranged to
transfer heat from the unconcentrated spent fluid and to
transfer heat to the concentrated spent fluid. A first
separator communicates with the heat exchanger for separating
a portion of the lower boiling temperature component from the
concentrated fluid and for recombining the separated portion
of the lower boiling temperature component with a portion of
the remainder of the concentrated fluid so as to form a
regenerated working fluid that may be condensed by the
available cooling system. A second separator for extracting a
lower boiling temperature component from a portion of the
remainder of the concentrated fluid is arranged to supply
lower boiling temperature component to the concentrator. The
second separator may include a fluid pressure lowering device
for extracting the lower boiling temperature component.

BRIEF
DESCRIPTION OF THE DRAWING

FIG. 1 is a
schematic representation of one system for carrying out one
embodiment of the method and apparatus of the present
invention.

![](4586-1.gif)

DESCRIPTION OF
A PREFERRED EMBODIMENT

Referring to
the drawing wherein like reference characters are utilized for
like parts throughout the several views, a system 10, shown in
FIG. 1, implements a thermodynamic cycle, in accordance with
one embodiment of the present invention, using a boiler 102, a
turbine 104, a condenser 106, a pump 108, and a distilling
subsystem 126. The subsystem 126 includes a recuperator 110, a
distilling gravity separator 112, a heater 114, a preheater
116, a deconcentrating separator 118, and a concentrator 120.

Various types
of heat sources may be used to drive the cycle of this
invention. Thus, for example, heat sources with temperatures
as high as, say 500 deg C. or more, down to low heat sources such
as those obtained from ocean thermal gradients may be
utilized. Heat sources such as, for example, low grade primary
fuel, waste heat, geothermal heat, solar heat or ocean thermal
energy conversion systems may be implemented with the present
invention.

A variety of
working fluids may be used in conjunction with this system
including any multi-component working fluid that comprises a
lower boiling point fluid and a relatively higher boiling
point fluid. Thus, for example, the working fluid may be an
ammonia-water mixture, two or more hydrocarbons, two or more
freons, mixtures of hydrocarbons and freons or the like. In
general the fluid may be mixtures of any number of compounds
with favorable thermodynamic characteristics and solubility.
The system or cycle of this invention may be described by way
of example by reference to the use of an ammonia-water working
solution.

In an
ammonia/water working solution, the ammonia constitutes the
lower boiling component with a boiling point of -33 deg C., while
water is the higher boiling component with a boiling point of
100 deg C. Then the higher the concentration of ammonia, the
lower the boiling point of the water/ammonia composite.

The charged
composite working fluid implements a continuous system wherein
the fluid is expanded to convert energy into an usable form
followed by continuous regeneration. A substantially constant
and consistent quantity of the composite working fluid may
therefore by maintained in the system for long term use.

The Exergy
cycle utilized herein is generally described in pending U.S.
patent application Ser. No. 405,942, filed on Aug. 6, 1982 in
the name of the inventor of the present invention, and in ASME
paper 84-GT-173 entitled "Combined Cycle System With Novel
Bottoming Cycle" by A. I. Kalina. The pending application and
ASME paper are hereby expressly incorporated herein by
reference.

The basic
spent working fluid in a condensed state, termed the
distillation fluid herein, at point 1 has its pressure
increased by the pump 122 to point 2 where the fluid exists as
a subcooled liquid at a lower intermediate pressure, which is
intermediate which respect to the pressure at the turbine
inlet 30 and outlet 38. From point 2 the subcooled liquid is
directed through the top of the concentrator 120 where it is
mixed, for example by spraying, with the flow of saturated
vapor having a higher concentration of the lower boiling point
component arriving from point 28. The pressure at point 28 is
made essentially the same as the pressure at point 2. Because
of the increase in the pressure provided by the pump 122 the
distillation fluid more easily absorbs the saturated vapor
arriving from the point 28.

As a result of
mixing in the concentrator 120, a saturated liquid passes
outwardly from the concentrator 120 through the point 41. This
saturated liquid has a higher concentration of the lower
boiling component than the liquid existing at the point 2 so
that the liquid at point 41 may be termed an "enriched"
liquid. This enriched liquid is pumped by the pump 124 to an
upper intermediate pressure at point 42. The liquid is then
successively heated in preheater 116, heater 114, and
recuperator 110. The heating processes in the preheater 116
and heater 114 are performed by recuperation of the heat of
counterflowing outlet fluid from the turbine 104 as well as
the heat from other fluids utilized in the system. However,
the heating in the recuperator 110 is performed only by the
heat of the flow from the turbine 104 outlet 38 and, as such,
is compensation for under recuperation.

The enriched
flow at point 5, for example, is partially evaporated and
passes into the distilling gravity separator 112. Vapor,
strongly enriched by the lower boiling point component is
separated and passes through point 6. A lean stripped liquid,
impoverished with respect to the lower boiling component which
is substantially removed, exits from the separator 112 through
point 7.

The lean
liquid flow from the separator 112 is divided into three flow
paths, identified by the points 8, 10, and 40. The flow of
liquid passing through point 8 is proportionately mixed with
the vapor from point 6. As a result, the generated mixture,
passing point 9, has the necessary concentration of lower
boiling and higher boiling components, to be used as the
working fluid for the remainder of the cycle. The proportion
of lower and higher boiling components forming the working
fluid is selected to minimize the energy losses during
operation. Generally, the fluid at point 9 is enriched with
the lower boiling component with respect to the fluid at point
5.

In order to
achieve the greatest possible efficiency it is also
advantageous to choose the working composition concentration
to get the minimum exergy losses in the boiler 102. As a
practical matter, the applicable optimal range lies between 50
to 70 percent by weight of the low boiling component in most,
but not necessarily all cases. Generally, it is advantageous
to include at least 20 to 25% by weight of the higher boiling
component.

This enriched
working fluid is cooled in the heater 114, thereby providing
the heat for the heating of the fluid passing from the point 3
to the point 4, as described above. In the boiler preheater
130, the flow is further cooled so that the fluid is
completely condensed in the condenser 106, by cooling water
flowing along the line 24 to 23.

The condensed
working fluid is pumped by the pump 108 from the point 14 to
the point 21 so that it moves counterflow through the
preheater 116. The working fluid then flows through the boiler
102 where it is heated and preferably substantially
evaporated. Most preferably the working fluid is completely
evaporated, and superheated at point 30. The flow of boiler
heating fluid is indicated by the line 25 to 26.

The
superheated vapor is then expanded in the turbine 104
outputting the desired mechanical power. If the working fluid
at point 38 is still superheated vapor, lean liquid from the
distilling gravity separator 112 may be injected into the
expanding working fluid in the turbine 104. This injection is
most practical into the inlet to the last or the next to the
last turbine stage. However, this result may also be
accomplished by injection into fluid stream following exit
from the turbine 104, for example at the point 38, as
indicated in a dashed line in FIG. 1. As a result of this
injection near the turbine outlet, the working fluid from the
previous stage of the turbine 104 has its concentration
changed in travelling from the point 36 to the point 39.

When the
saturated liquid injection is accomplished before the last
turbine stage it must be done in such proportions that the
state of the working fluid in the following stage of the
turbine 104 is still a superheated vapor. However, the
temperature of the mixed gas at the point 39 is lower than the
temperature of the gas in the turbine preceeding injection.
Also, the concentration of the lower boiling point component
at the point 39 is lower than the concentration at the point
preceeding injection. The enthalpy at the point 39 is also
lower than the enthalpy at the point preceding injection.
Similarly the enthalpy, temperature and lower boiling
component concentration at the outlet of the turbine 104 are
lower than they would have been without injection. In
addition, the weight flow rate at the turbine outlet is higher
than at the point preceeding injection, since this flow rate
is equal to the sum of the flow rates into the juncture 132.

The injection
is most advantageously proportioned so that the outlet of the
last stage of the turbine 104 has the characteristics of a
saturated or wet vapor instead of superheated vapor.
Alternatively, where injection is performed into the gas that
has already exited from the turbine, the gas becomes a
saturated vapor upon mixing with the injected fluid.

The pressure
of the inlet fluid in the line 136 is made substantially equal
to the pressure in the line 137 preceeding injection. To
achieve this result, a pressure equalizing device 138 is
utilized. The pressure equalizing device 138 may take the form
of a throttle valve, when it is necessary to decrease the
pressure of the incoming fluid to match that of the turbine.
The device 138 may be totally omitted when the pressure of the
inlet flow happens to equal that of the flow within the
turbine 104. The pressure equalizing device 138 may take the
form of a pump when it is necessary to increase the pressure
in the line 136 to equal that in the line 137.

The turbine
outlet flow passes from the point 38 consecutively through the
recuperator 110, heater 114, and preheater 116 so that the
flow is cooled and partially condensed. However, the pressure
at the turbine outlet and consequently, at the recuperator 110
outlet, the heater 114 outlet, and the preheater 116 outlet
may be so low that it may not be possible to condense the
fluid at that pressure with the available cooling water
temperature. While this result may appear to be unfortunate at
first glance, in fact, this means that the energy of the fluid
has been fully utilized in the turbine 104.

To overcome
this problem, a portion of the stripped liquid flow removed
from the distilling separator 112 is cooled in the heater 114
as it flows from the point 10 to the point 12. This process
provides the heat necessary for the heating process of the
fluid moving from point 3 to point 4. The stripped liquid flow
is throttled by the throttle valve 140 to the lower
intermediate pressure, at the point 27 (so that pressure at
point 27 equals pressure at point 2). This fluid, at the lower
intermediate pressure, is directed into the de-concentrating
separator 118 where it is separated into two streams due to
the lowering of the fluid pressure by the valve 140. The first
stream is a saturated vapor which extends through the point
28, and is relatively enriched with respect to the lower
boiling component. The second stream is an absorbing, lean
solution passing through point 29, that is relatively
impoverished with respect to the lower boiling component and
therefore tends to readily absorb the low boiling component.
The vapor passing through the point 28 is directed into the
concentrator 120 where it is mixed with subcooled liquid flow
from point 2 to increase the lower boiling component
concentration of the fluid.

The absorbing
lean solution passes the point 29 with the same pressure as
the enriched flow at point 42 (upper intermediate pressure),
but the lean solution has a much lower concentration of the
lower boiling component than the flow at point 42. As a
result, the temperature at the point 29 is always higher than
the temperature at the point 42. Therefore the absorbing, lean
flow at point 29 is sent through the preheater 116 where it is
cooled, providing part of the heat necessary for heating the
fluid flowing from the concentrator 120 through the preheater
116.

The cooled,
absorbing, lean solution is throttled by the throttle valve
142 to a low pressure substantially equal to the pressure at
the turbine outlet with parameters similar to those at the
point 17. The turbine outlet flow at point 17 and the
absorbing, lean solution flow at point 19 are mixed,
generating a flow of a basic solution at point 18. The
concentration of the higher boiling component in the flow at
the point 18 is such that the fluid can be completely
condensed at the available cooling water temperature.
Therefore, this flow is fully condensed in the condenser 106
to reach the parameters of the fluid at point 1, after which
the above-described process is repeated.

Those skilled
in the art will appreciate that it is desirable in terms of
thermal efficiency to have the highest possible fluid
temperature at the inlet to the turbine. This is because it
always beneficial to have the working fluid and the heating
fluid at relatively close temperatures. By maximizing the
temperature at the inlet to the turbine 104, a greater power
output may be obtained from the turbine 104 with a
consequently greater enthalpy drop than would be obtained if a
lower temperature were utilized.

Nevertheless,
the temperature at the turbine outlet must increase
corresponding to the increased temperature at the turbine
inlet. This may mean that the working fluid flow leaving the
turbine 104 may still be in a superheated vapor state.
However, this extra energy existing in the form of superheated
vapor is essentially useless in the distillation process and
is generally useless in the cycle as a whole. This means that
there is an incomplete use of the energy potential of the
working fluid.

To achieve the
highest possible cycle efficiency, a relatively high
concentration of the lower boiling point component in the
working fluid passing through the boiler 102 and the turbine
104 is desirable. However, at the same time, it is preferable
to have a lower concentration of the lower boiling component
in the turbine output flow passing through the distillation
subsystem 126.

Thus the
injection of liquid into the turbine 104 through the injector
139, immediately reduces the lower boiling component
concentration of the flow passing through the last stages of
the turbine 104, causing thermodynamic losses. Those losses
are compensated for by the higher weight flow rate of the flow
through the last stages of the turbine 104. Absent this
accommodation, the potential energy in the fluid flow through
the turbine would be unused and would be essentially wasted in
the heat exchange processes of the distillation subsystem 126.

It should be
understood that the present cycle may be operable without the
use of injection of liquids from the separator 112 into the
turbine 104. Specifically if the fluid exiting from the outlet
of the turbine 104 is not superheated, injection may be
wasteful and is generally unnecessary.

When injection
of liquid into the turbine 104 is appropriate, the point of
injection is determined by the point where the smallest
possible exergy losses result in the cycle. One of ordinary
skill in the art will be capable of determining this point. It
generally will lie somewhere in the latter stages of the
turbine or after exit from the turbine.

Through the
use of the liquid injection system, additional power may be
gained from the turbine 104. This arises primarily from the
higher flow rate through the turbine 104. However, it can be
appreciated that the available energy is utilized in a more
efficient manner to increase the output from the turbine 104.

The
concentrator 120 and related components enable the
concentration of the basic solution to be chosen to
accommodate a relatively low pressure and temperature at the
turbine outlet. Thus, even where the pressure and temperature
at the turbine outlet are seemingly insufficient to enable
distillation of the basic solution, the operation of the
system is not adversely affected. This is because an enriched
solution, having a significantly higher concentration of the
lower boiling component, is the one that is subjected to the
distillation process. For this enriched solution a lower
turbine outlet temperature is sufficient to enable
distillation to proceed on an efficient basis.

However, it
should also be appreciated that this result is achieved while
decreasing the heat loading on the condenser 106. This is
because part of the hot liquid from the separator 112 is
diverted to other processes, without condensation, and
therefore less condensation is necessary. In other words, the
fluid outletted from the turbine 104 is mixed, before
condensation, with absorbing, lean flow which is even leaner
than the liquid flow coming from the distilling separator 112.
Therefore, after absorption, the leaner portion of the flow
which is coming into the condenser 106 is in the form of
liquid, and thus a lower quantity of heat has to be removed to
produce condensation. This presumably lowers condenser surface
requirements and increases the efficiency of the system.

Overall, with
present invention using the injector 139, the average
temperature of the fluid flow from the point 38 to the point
17 is effectively increased. At the same time the average
temperature of the required heat from the point 42 to the
point 5 is decreased by injecting the enriched vapor in the
concentrator 120. Thus, separately and in combination, these
effects serve to increase overall system efficiency.

Relatively
lower
temperature heat for the distillation subsystem 126 of this
invention may be obtained in the form of spent relatively
high temperature heat, the lower temperature part of
relatively higher temperature heat from a heat source, the
relatively lower temperature waste or other heat which is
available from a heat source, and/or the relatively lower
temperature heat that cannot be utilized efficiently for
evaporation in the boiler. In practice, any available heat,
particularly lower temperature heat which cannot be used
effectively for evaporation, may be utilized as the
relatively lower temperature heat for the distillation
subsystem 126. In the same way such relatively lower
temperature heat may be used for preheating.

While the
present invention has been described with respect to a single
preferred embodiment, those skilled in the art will appreciate
a number of variations and modifications therefrom and it is
intended within the appended claims to cover all such
variations and modifications as come within the true spirit
and scope of the present invention.

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